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Materials Analysis Using a THz Imaging System Based on Atomic Vapour

Nourah F. A. Almuhawish

Published Jan 1, 2022• 0 citations
OpenAlex

Abstract

This thesis studies the response of the interaction between Rydberg atomic vapour and a THz frequency field. When Caesium atoms at room temperature are excited to a Rydberg state using three infrared lasers and a 0.55 THz field resonant with the 14P3/2 → 13D5/2 transition is applied, the atoms respond by emitting a green optical fluorescence corresponding to the 13D5/2 → 6P3/2 decay. This response is exploited to investigate the absorption coefficient for different polymer materials that transmit well in the THz frequency range using the Beer–Lambert law. We calibrate the system to obtain a measure of THz intensity. As the THz imaging system is highly sensitive to environmental changes, and to show that our results are consistent, we provide a comparison of results between our atomic detection method and a commercial thermal power meter. Additionally, we measure the absorption coefficient of the same materials at a frequency of 1.1 THz, and the results are compared with those measured at 0.55 THz. The THz imaging system is also used to perform some experiments in order to demonstrate its effectiveness in real-world applications. The system provides an interesting image contrast in the case of a sample containing two different polymer materials measured at two THz frequencies. The result is a proof-of-concept that multispectral THz imaging can provide additional information and is motivation to improve our THz imaging system by introducing a dual-species THz imager. We also investigate the polarisation spectroscopy of an excited-state transition of rubidium vapour at room temperature as a step towards a rubidium THz imaging system. The narrow dispersive signal produced by this spectroscopy technique is ideal for laser frequency stabilisation of excited-state transitions.

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APL Photonics•Apr 1, 2026•0 citations
This thesis studies the response of the interaction between Rydberg atomic vapour and a THz frequency field. When Caesium atoms at room temperature are excited to a Rydberg state using three infrared lasers and a 0.55 THz field resonant with the 14P3/2 → 13D5/2 transition is applied, the atoms respond by emitting a green optical fluorescence corresponding to the 13D5/2 → 6P3/2 decay. This response is exploited to investigate the absorption coefficient for different polymer materials that transmit well in the THz frequency range using the Beer–Lambert law. We calibrate the system to obtain a measure of THz intensity. As the THz imaging system is highly sensitive to environmental changes, and to show that our results are consistent, we provide a comparison of results between our atomic detection method and a commercial thermal power meter. Additionally, we measure the absorption coefficient of the same materials at a frequency of 1.1 THz, and the results are compared with those measured at 0.55 THz. The THz imaging system is also used to perform some experiments in order to demonstrate its effectiveness in real-world applications. The system provides an interesting image contrast in the case of a sample containing two different polymer materials measured at two THz frequencies. The result is a proof-of-concept that multispectral THz imaging can provide additional information and is motivation to improve our THz imaging system by introducing a dual-species THz imager. We also investigate the polarisation spectroscopy of an excited-state transition of rubidium vapour at room temperature as a step towards a rubidium THz imaging system. The narrow dispersive signal produced by this spectroscopy technique is ideal for laser frequency stabilisation of excited-state transitions.
This thesis investigates the interaction between Rydberg atoms and THz radiation and details development of an atom-based imaging system for THz frequency fields. Room temperature caesium atoms are excited to a Rydberg state using resonant infrared lasers and the response of these atoms to THz radiation is studied in multiple ways. We look at the absorption of the initial excitation laser and show how the observed lineshape changes in response to an applied THz field. We use this to measure the power of a THz field across a range of 350 GHz. These measurements also lead us to determine values for the quantum defects in caesium without reliance on data from any other sources. These values agree within error with those previously reported in literature. We study the optical fluorescence emitted by the laser-excited \nvapour and develop a model to predict this emission. We highlight deviations from this model and suggest possible mechanisms for this discrepancy. We show how this model can be used to determine the optimum transition for atom-based THz imaging within our experimental parameters. We demonstrate a high-speed THz imaging system using Rydberg atoms and show that it has near diffraction-limited \nspatial resolution and is able to capture images at kHz framerates. We measure the minimum THz power that the system can detect and show how it compares to other technologies. This system is then used to perform some proof-of-principle experiments to highlight its usefulness in commercial settings. Using optical elements \ndesigned and produced in-house we create and characterise THz vortex beams with both radial and azimuthal phase. We show how these beams are similar to Laguerre-Gauss modes and highlight some important differences.
We demonstrate simultaneous imaging at 0.549 THz and 1.012 THz with an optical overlay using a two-species atomic-vapour-based technique. The atomic vapour, comprising laser-pumped rubidium and caesium atoms contained within the same cell, is used to convert two narrowband terahertz signals to optical frequencies which can then be detected using standard CMOS sensors. We use the system to image and perform spectral analysis of material samples. As atomic vapour is optically transparent, by using optically-transparent terahertz lenses, we can achieve simultaneous optical imaging, allowing for potential integration of terahertz sensitivity into a range of optical imaging devices.
Terahertz imaging has become increasingly important across various fields and practical production applications. Achieving both high sensitivity and high speed remains a primary challenge for most current THz imaging technologies. In this work, we present an imaging system based on Rydberg atomic vapor operating at frequencies exceeding 1 THz. By utilizing Cesium 133 atoms coupled with THz waves, de-excitation radiation generated after atomic excitation to Rydberg states converts invisible THz waves into visible light, enabling the acquisition of spatial information and intensity distributions of THz fields. The system achieves a minimum detectable power of 330 fW /s 1/2 per (2.4×2.4) μm 2 , an imaging resolution of approximately 1.7 mm, and an imaging bandwidth of 8.6 MHz. Additionally, the theoretical imaging rate can exceed 1 MHz. The Rydberg-atom-based THz imaging system exhibits a simple structure and is amenable to miniaturization. This THz imaging method holds promise for advancing applications in THz nondestructive testing, biomedical imaging, and concealed object detection.
This thesis reports the investigation of cooperative non-equilibrium dynamics in a thermal Rydberg ensemble. Cooperative behaviour arises due to resonant dipole-dipole interactions between highly excited Rydberg atoms. In order to transfer atomic population from the ground state to the Rydberg state in a caesium vapour, a three-photon excitation scheme is developed. This scheme has a number of benefits over traditional two-photon Rydberg excitation as each transition utilises in- expensive high-power diode lasers. The process of developing the excitation scheme produces a number of important results, including an excited-state polarisation spectroscopy technique and the observation of coherent three-photon electromagnetically induced transparency. The optical response and atomic dynamics of the interacting ensemble can be separated into two distinct phases. When the Rydberg number density is low and the interactions are negligible, the system can be described by the behaviour of a single atom. However, when the Rydberg number density is high, resonant dipole-dipole interactions result in a significant modification of the ensemble properties. This cooperative many-body phase cannot be described by the behaviour of a single atom. In the frequency domain, the interactions produce an excitation-dependent cooperative energy shift that is observed using probe transmission spectroscopy. In the time domain, the interactions result in a cooperative enhancement of the atomic decay rate that is analysed using fluorescence spectroscopy. At the transition between the single-body and many-body phase, a first-order non-equilibrium phase transition occurs. This is observed spatially along the length of the excitation region as a sharp switch in the emitted fluorescence. The first-order phase transition is also observed in the temporal response of the ensemble through critical slowing down. The divergence of the switching time to steady state follows a universal scaling law for phase transitions and the determined critical exponent is in excellent agreement with previous work on non-equilibrium phase transitions.
Rydberg electromagnetically induced transparency (EIT) and Autler-Townes (AT) splitting in an atomic vapor cell can be used as novel methods for electric-magnetic field detection. Here we make use of 3 infrared lasers to realize a Rydberg EIT system in a thermal rubidium vapor cell. With the AT splitting induced by the THz radiation, we observe a linear trend between THz field amplitude and the frequency splitting of the absorption dips and EIT transmission peaks. Due to the well-known atomic transition dipole moment of the Rydberg state, the THz electric field can be calibrated from the frequency splitting, making this Rydberg atomic measurement system a practical tool for THz field detection.
Broadband and sensitive terahertz (THz) detectors are essential for advancing applications in THz technology. Rydberg atoms were proven to be a promising THz detector, but its detection bandwidth and sensitivity still remain challenging. In this paper, a four-level cesium Rydberg atom system was designed, and it can be operated using electromagnetically induced transparency (EIT). Above all, a high-performance THz detection scheme was demonstrated by introducing frequency detuning of the THz wave relative to the atomic resonance and analyzing the asymmetric splitting between the EIT main peak and the off-resonant Autler–Townes (AT) peak. This method exploits the linear dependence of Rydberg eigenfrequencies on THz detuning and allows us to resolve weak THz electric fields even in the nonlinear regime. Furthermore, the probe laser power was found to influence the EIT signal, with low power producing a narrow but weak signal and high power yielding a stronger yet broader signal; therefore, under a probe power of 20 μW, a minimum detectable field of 2.43 V/m at 108.9 GHz was achieved, while a probe power of 500 μW allowed the detection bandwidth to be extended to 14 GHz. That means that the sensitivity was improved by 50% and the bandwidth was improved by three orders compared with the conventional EIT–AT method. Theoretical modeling results based on the Lindblad master equation are consistent with the experimental results. This frequency-detuning-based strategy offers a physically traceable and scalable approach to advancing quantum-enhanced THz sensing under ambient conditions.