Classical and quantum chaos in atomic nuclei

Oleg Vorov

Dominique Delande

Sandro Wimberger

The field of chaos in many-body quantum systems has a long history, going back to Wigner's simple models for heavy nuclei. Quantum chaos is being investigated in a broad variety of experimental platforms such as heavy nuclei, driven (few-electron) atoms, ultracold quantum gases, and photonic or microwave realizations. Quantum chaos plays a new and important role in many branches of physics, from condensed matter problems of many-body localization, including thermalization studies in closed and open quantum systems, and the question of dynamical stability relevant for quantum information and quantum simulation. This Special Issue and its related book address theories and experiments, methods from classical chaos, semiclassics, and random matrix theory, as well as many-body condensed matter physics. It is dedicated to Prof. Shmuel Fishman, who was one of the major representatives of the field over almost four decades, who passed away in 2019.

Sandro Wimberger

Pavel Cejnar, Pavel Stránský

We use two models of nuclear collective dynamics-the geometric collective model and the interacting boson model-to illustrate principles of classical and quantum chaos. We propose these models as a suitable testing ground for further elaborations of the general theory of chaos in both classical and quantum domains.

Vladimir V. Egorov

In quantum mechanics, the theory of quantum transitions is grounded on the convergence of a series of time-dependent perturbation theory. In nuclear and atomic physics, this series converges because the dynamics of quantum transitions (quantum jumps) are absent by definition. In molecular and chemical physics, on the contrary, the dynamics of "quantum" transitions, being determined by the joint motion of a light electron (or electrons) and very heavy nuclei, are present by definition, and the series of time-dependent perturbation theory becomes singular. An exception is the dynamic problem for stationary states in the Born-Oppenheimer adiabatic approximation, when the electronic subsystem turns out to be "off" from the general dynamic process and therefore is not dynamically full-fledged: it only forms an electric potential in which the nuclei oscillate. Removing the aforementioned singularity can be accomplished in two ways. The first method was consisted of introducing an additional postulate in the form of the Franck-Condon principle into molecular quantum mechanics, in which the adiabatic approximation is used. The second method was proposed by the author and consisted of damping the singular dynamics of the joint motion of an electron and nuclei in the intermediate (transient) state of molecular "quantum" transitions by introducing chaos. This chaos arises only during molecular quantum transitions and is called dozy chaos. Formally, the damping is carried out by replacing an infinitely small imaginary addition in the spectral representation of the complete Green's function of the system with its finite quantity. The damping chaos (dozy chaos) leads to the continuity of the energy spectrum in the molecular transient state, which is a sign of classical mechanics. Meanwhile, the initial and final states of the molecule obey quantum mechanics in the adiabatic approximation. Molecular quantum mechanics, which takes into account the chaotic dynamics of the transient state of molecular "quantum" transitions, can be called quantum-classical (dozy-chaos) mechanics. The efficacy of the damping for the aforementioned singularity was previously shown by dozy-chaos mechanics of elementary electron transfers in condensed matter, which is the simplest case of dozy-chaos mechanics, and its applications to a whole number of problems, especially to the optical spectra in polymethine dyes and their aggregates. This paper provides a regular exposition of this dozy-chaos (quantum-classical) mechanics of the elementary electron transfers. The main results of its applications presented in the introduction are also described.