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Physical review. D/Physical review. D.

Scattering phase shift in quantum mechanics on quantum computers

Peng Guo, Paul LeVan, Frank X. Lee, Yong Zhao

Published Mar 5, 2026• 3 citations
Publisher
DOI
10.1103/ds7x-7bkp

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We investigate the feasibility of extracting infinite volume scattering phase shift on quantum computers in a simple one-dimensional quantum mechanical model, using the formalism established in Ref.~\cite{Guo:2023ecc} that relates the integrated correlation functions (ICF) for a trapped system to the infinite volume scattering phase shifts through a weighted integral. The system is first discretized in a finite box with periodic boundary conditions, and the formalism in real time is verified by employing a contact interaction potential with exact solutions. Quantum circuits are then designed and constructed to implement the formalism on current quantum computing architectures. To overcome the fast oscillatory behavior of the integrated correlation functions in real-time simulation, different methods of post-data analysis are proposed and discussed. Test results on IBM hardware show that good agreement can be achieved with two qubits, but complete failure ensues with three qubits due to two-qubit gate operation errors and thermal relaxation errors.

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Toward extracting scattering phase shift from integrated correlation functions on quantum computers

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Based on an established relation that relates the integrated correlation functions for a trapped system to the infinite volume scattering phase shifts through a weighted integral, we propose to extract the infinite volume scattering phase shifts through quantum simulation of the integrated correlation functions of trapped two-particle systems on quantum computers. The integrated correlation function can be computed by an ancilla-based algorithm. The proposal is demonstrated with a simple contact interaction fermion model.

arXiv:2504.14474•Physical Review Research•Nov 12, 2025•2 citations
We investigate the feasibility of extracting infinite volume scattering phase shift on quantum computers in a simple one-dimensional quantum mechanical model, using the formalism established in Ref.~\cite{Guo:2023ecc} that relates the integrated correlation functions (ICF) for a trapped system to the infinite volume scattering phase shifts through a weighted integral. The system is first discretized in a finite box with periodic boundary conditions, and the formalism in real time is verified by employing a contact interaction potential with exact solutions. Quantum circuits are then designed and constructed to implement the formalism on current quantum computing architectures. To overcome the fast oscillatory behavior of the integrated correlation functions in real-time simulation, different methods of post-data analysis are proposed and discussed. Test results on IBM hardware show that good agreement can be achieved with two qubits, but complete failure ensues with three qubits due to two-qubit gate operation errors and thermal relaxation errors.
Rutherford classical scattering theory, as its quantum mechanical analogue, is modified for scattering cross-section and the impact parameter by using quantum mechanical momentum, (de Broglie hypothesis), energy relationship for matter oscillator (Einstein’s oscillator) and quantum mechanical wave vectors, and , respectively. It is observed that the quantum mechanical scattering cross-section and the impact parameter depended on inverse square law of quantum action (Planck’s constant). Born approximation is revisited for quantum mechanical scattering. Using Bessel and Neumann asymptotic functions and response of nuclear surface potential barrier, born approximations were modified. The coulombic fields inside the nucleus of the atom are studied for reflection and transmission with corresponding wave vectors, phase shifts and eigenfunctions Bulk quantum mechanical tunneling and reflection scattering, both for ruptured and unruptured nucleus of the atom, are deciphered with corresponding wave vectors, phase shifts and eigenfunction. Similar calculation ware accomplished for quantum surface tunneling and reflection scattering with corresponding wave vectors, phase shifts and eigenfunctions. Such diverse quantum mechanical scattering cross-section with corresponding wave vectors for tunneling and reflection, phase shifts and eigenfunctions will pave a new dimension to understanding the behavior of exchange fields in the nucleus of the atom with insides layers both ruptured and unruptured. Phase shifts, δl for each of the energy profile (partial) will be different and indeed their corresponding wave vectors for exchange energy eigenvalues.
Based on an established relation that relates the integrated correlation functions for a trapped system to the infinite volume scattering phase shifts through a weighted integral, we propose to extract the infinite volume scattering phase shifts through quantum simulation of the integrated correlation functions of trapped two-particle systems on quantum computers. The integrated correlation function can be computed by an ancilla-based algorithm. The proposal is demonstrated with a simple contact interaction fermion model.