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Physica Scripta

Entropic uncertainty and quantum correlations in perylene-qubit dimers under decoherence channels

Ahmad N. Khedr, Samira Elghaayda, Mostafa Mansour

Published Feb 21, 2026• 1 citation
Publisher

Abstract

Abstract We explore how thermal fluctuations and noisy decoherence affect non-classical correlations and entropic uncertainty relations in a perylene-bisimide (PBI) dimer system represented by two coupled molecular two-level systems. The composite Hamiltonian includes dipole-dipole interaction between the monomers, and the system’s initial state is considered the thermal Gibbs state, which exhibits entanglement at a finite temperature. Environmental noise is introduced through amplitude damping, phase damping, and phase-flip channels, allowing us to trace the evolution of logarithmic negativity, trace distance discord, and the quantum-memory-assisted entropic uncertainty relation (QMA-EUR). The investigation demonstrates that entanglement decays rapidly with increasing temperature and decoherence strength, whereas trace discord remains resilient over a more comprehensive parameter range. This robustness suggests that PBI dimers can retain useful quantum resources under realistic environmental conditions, highlighting their potential as building blocks for molecular quantum information devices.

DOI
10.1088/1402-4896/ae48b4

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The uncertainty principle limits the ability for observer to precisely measure two incompatible observables, and plays a crucial role in quantum precision measurement in the quantum information science. When quantum systems interact with their surroundings, they inevitably result in decoherence, which increases the uncertainty of the system. In the process of quantum information processing, the effective regulation of uncertainty becomes a key problem that needs to be solved. In this work, we investigate the quantum-memory-assisted entropic uncertainty relation of a two-qubit system under correlated channels with dephasing colored noise. We demonstrate that it is possible to control the entropic uncertainty, U, and its lower bound, Ub, by combining correlations between successive uses of channels and the non-Markovianity of the dynamical evolution. Firstly, the evolutionary characteristics of the trace distance are employed to distinguish between Markovianity and non-Markovianity of the channel. Subsequently, the system is selected to be either a maximally entangled state or separated state initially. By adjusting the strength η of the correlations, we find that with the increase of η, the entropic uncertainty and its lower bound decrease. Especially, if the channel is fully correlated (η = 1), the entropic uncertainty and its lower bound remain constant under the channel, indicating that decoherence is completely suppressed. A comparison of Markovian channel with non-Markovian channel reveals that the entropic uncertainty and its lower bound exhibit oscillatory behaviour under non-Markovian channels. The combination of correlations and non-Markovianity of the channel demonstrates that the entropic uncertainty and its lower bound can be reduced under fully correlated channels where the non-Markovianity has no effect. This is because fully correlated channels suppress decoherence to a greatest extent. Under partially correlated channels, the combination of correlations and non-Markovianity can more effectively reduce the entropic uncertainty and its lower bound. Under such channels, correlations of the channel reduce the entropic uncertainty and its lower bound during the whole evolution, while the non-Markovianity contributes to their oscillations and reduce them in some specific time. Furthermore, the results show that the entropic uncertainty and its lower bound reach steady values that depend only on the strength of the correlations after long-time evolution. In other words, the stronger the correlations, the lower the entropy uncertainty and its lower bound of steady states will be. Finally, we analyse the physical nature of the decrease of the entropic uncertainty and its lower bound, and it is found that the decrease of the entropic uncertainty and its lower bound originate from the increase of the quantum correlations in the system.
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