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Cambridge University Press eBooks

Time-Dependent Quantum and Ensemble Averages: Initial Preparation of the System

Giancarlo Calvanese Strinati

Published Feb 6, 2026• 0 citations
Publisher

Abstract

This chapter considers the initial preparation of the many-particle system, whose control is achieved before the reference time t ₀ when the time-dependent perturbation begins to act on the system. After t ₀, the system is let to evolve in time according to the full time-dependent Hamiltonian. The initial control can be either full or partial. Full control signifies that at t ₀ the system is prepared in a definite “pure” quantum state (like the ground state), while partial control signifies that initially the system is only known to be in a “mixture” of states with given probabilities, such that the information on the phases of the superposition is lost. These two cases are here treated separately.

DOI
10.1017/9781009411509.005

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This chapter considers the initial preparation of the many-particle system, whose control is achieved before the reference time t ₀ when the time-dependent perturbation begins to act on the system. After t ₀, the system is let to evolve in time according to the full time-dependent Hamiltonian. The initial control can be either full or partial. Full control signifies that at t ₀ the system is prepared in a definite “pure” quantum state (like the ground state), while partial control signifies that initially the system is only known to be in a “mixture” of states with given probabilities, such that the information on the phases of the superposition is lost. These two cases are here treated separately.
Ensembles and expectation values Equations of motion provide predictions of time-evolving variables of a dynamical system, and thereby enable us to predict the changing behavior. These equations are characteristic of a particular type of system, say a classical harmonic oscillator or a two-state quantum system. To complete the description of behavior one must specify initial conditions that select, from the many possible solutions to the equations of motion, a particular realization. In the example of a classical point particle the equation is second order in time, and so we need two initial conditions, of position and velocity, to specify a particular solution. These two numbers, taken with the classical equation of motion, provide a complete description of the behavior of a specific harmonic oscillator. Similarly the two-state quantum system requires two initial values to complete its definition. The initial conditions are never defined with infinite precision, even for classical mechanics. More generally we deal with an ensemble, that is, a collection of similar dynamical systems (e.g. oscillators) that differ in their preparation. The individual cases share some common attributes, but not necessarily all. Thus we have only incomplete information about any single system. We might, for example, consider planetary motion in which we know only the mean energy and the orbital plane. The loci of positions of the planets then form ellipses that make up the ensemble. Although it is possible to prepare a single two-state quantum system in which the initial state is known (apart from an overall phase), often one deals with ensembles of such systems, each of which may differ in some uncontrollable property.
This chapter introduces the contour Schwinger–Keldysh method for time-dependent averages, in light of its relevance to nonequilibrium processes. A key feature of this approach is that it leaves open the possibility that no state of a system in the future can be identified with any of its states in the past. This method is here illustrated in detail with reference to time-dependent quantum averages, whereby for definiteness the system is initially prepared at the reference time t ₀ in a definite quantum state.
We now consider systems for which the Hamiltonian contains time-dependent interaction terms. In such cases we cannot reduce the time-dependent Schro¨dinger equation to an eigenvalue equation. However, if the time-dependent terms can be regarded as small perturbations, we can develop a form of perturbation theory that can be used to calculate the effects of time-dependent terms. Consider a system for which the Hamiltonian may be written as the sum of a dominant unperturbed part Hˆ0 and a small perturbation Hˆ ′ as Hˆ = Hˆ0 + λHˆ ′(t) , (10.1.1) where the unperturbed Hamiltonian Hˆ0 is independent of time, whereas the perturbation Hˆ ′ may depend on time. The parameter 0 < λ < 1 has been introduced to keep track of various orders of approximations as in the case of time-independent perturbation theory discussed in Chapter 8. The basic idea is that a small perturbation to the Hamiltonian will produce a small change in the wave function. For a time-dependent perturbation, this change means that a system, initially in a particular eigenstate of Hˆ0, will find itself in a time-dependent admixture of the eigenstates. Thus the time-dependent perturbation causes the system to undergo transition to different eigenstates of Hˆ0. So for time-dependent perturbations our interest lies in calculating the probabilities for transition to different states.
This chapter aims to present the essence of the general theory in the particularly simple and convenient case of systems at finite temperature which may be treated in the grand canonical ensemble. It describes how thermal averages of time-ordered products of Heisenberg operators in imaginary time emerge naturally from path integrals and how to evaluate them in perturbation theory. The chapter considers at the outset what level of mathematical rigor one can actually expect and how in practice one may select and assess an approximation scheme. In view of the general lack of mathematical control on the convergence properties of the original series and the obvious ambiguity associated with regrouping divergent series, any such resummations must be understood ultimately on physical grounds. The ultimate objective of the quantum theory of many-particle systems is to understand experimentally observable properties of a diverse range of physical systems.