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Cambridge University Press eBooks

Time-Dependent Hartree–Fock Approximation and Mean-Field Decoupling

Giancarlo Calvanese Strinati

Published Feb 6, 2026• 0 citations
Publisher

Abstract

Mean-field decouplings can also be utilized in time-dependent (nonequilibrium) situations. This chapter considers the time-dependent Hartree–Fock approximation for fermions in the normal phase, as obtained in terms of a time-dependent mean-field decoupling (postponing to Part II the Gor’kov generalization to the superfluid phase). A connection is also established with a more standard formulation of the time-dependent Hartree–Fock approximation in terms of a set of time-dependent single-particle wave functions.

DOI
10.1017/9781009411509.020

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Mean-field decouplings can also be utilized in time-dependent (nonequilibrium) situations. This chapter considers the time-dependent Hartree–Fock approximation for fermions in the normal phase, as obtained in terms of a time-dependent mean-field decoupling (postponing to Part II the Gor’kov generalization to the superfluid phase). A connection is also established with a more standard formulation of the time-dependent Hartree–Fock approximation in terms of a set of time-dependent single-particle wave functions.
This chapter considers the analog of the time-dependent Hartree–Fock (mean-field) decoupling treated in Part I and extends it to the broken-symmetry phase for superfluid fermions. Two coupled equations for the “normal” and “anomalous” time-dependent single-particle Green’s functions are obtained, which extend to nonequilibrium situations the equations originally obtained at equilibrium by Gor’kov, soon after the BCS original article on the theory of superconductivity. Accordingly, the time-dependent gap (order) parameter is also introduced.
This article examines the time-dependent Hartree-Fock (TDHF) approximation of single-particle dynamics in systems of interacting fermions. We find the TDHF approximation to be accurate when there are sufficiently many particles and the initial many-particle state is a Slater determinant, or any Gibbs equilibrium state for noninteracting fermions. Assuming a bounded two-particle interaction, we obtain a bound on the error of the TDHF approximation, valid for short times. We further show that the error of the the TDHF approximation vanishes at all times in the mean field limit.
A Gaussian operator representation for the many-body density matrix of fermionic systems, developed by Corney and Drummond [Phys. Rev. Lett. 93, 260401 (2004)], is used to derive approximate decoupling schemes for their dynamics. In this approach the reduced single electron density-matrix elements serve as stochastic variables which satisfy an exact Fokker-Planck equation. The number of variables scales as $\ensuremath{\sim}{N}^{2}$ rather than $\ensuremath{\sim}\text{exp}(N)$ with the basis set size, and the time-dependent Hartree-Fock approximation (TDHF) is recovered in the ``classical'' limit. An approximate closed set of equations of motion for the one- and two-particle reduced density matrices provides a direct generalization of the TDHF.
This article concerns the time-dependent Hartree-Fock (TDHF) approximation of single-particle dynamics in systems of interacting fermions. We find that the TDHF approximation is accurate when there are sufficiently many particles and the initial many-particle state is any Gibbs equilibrium state for noninteracting fermions (with Slater determinants as a special example). Assuming a bounded two-particle interaction, we obtain a bound on the error of the TDHF approximation, valid for short times. We further show that the error of the TDHF approximation vanishes at all times in the mean field limit.