The measurement by Duff and Heymann in 1962 of the pressure-proportional pick-off quenching rate of orthopositronium in helium gas may be interpreted as giving an effective number of electrons per atom in a singlet state relative to the positron of 0 108 ± 0 010 for thermal orthopositronium kinetic energies. A trial wave function used in the study of collisions of orthopositronium with helium, arising from an extension of work by Fraser in 1962, is employed to calculate this effective number of electrons. The unsatisfactory result at low energies is 0.019. A possible improvement in the collision trial wave function is suggested.
When orthopositronium collides with a closed-shell atom or ion the ``pick-off'' process is the dominant process for positron annihilation. In pick-off annihilation the positron annihilates with electrons in the target but not with the electron that is part of the positronium atom. The rate for pick-off annihilation, expressed in terms of the dimensionless parameter
1Zeff, for orthopositronium scattering from
Li+,Na+, and
K+ was computed with an
L2 variant of the fixed-core stochastic variational method. The threshold
1Zeff for
Li+ and
Na+, which can form a stable bound state with Ps were found to be 0.067 and 0.73, respectively, while that for
K+, which does not bind Ps, was 0.064.
Abstract A single rearrangement collision between two spin-polarized orthopositronium beams leading to the production of either negative or positive positronium ions is studied. Negative or positive ions can be produced by the attachment of an electron or positron to a positronium atom, respectively. The probabilities for the formation of all possible spin states for both types of positronium ions are determined. The spin scattering matrix constructed using angular-momentum coupling as well as the spin density matrix containing the probabilities are given. The probabilities depend on the angle between the polarization vectors of the incoming beams and the real parts of complex scattering amplitudes labeled with total electron and total positron spin. We describe the effect of the spin alignment between the two beams on the probabilities and how the annihilation rates for ion decay and the real parts of the amplitudes can be obtained.