Three-Particle Decay of Rydberg Molecules of Triatomic Hydrogen,

We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground-state atoms bound to a Rydberg atom via $s$ - and $p$ -wave interactions. By employing the finite basis set representation of the unperturbed Rydberg electron Green's function we reduce the computational effort to solve the electronic problem substantially. This method is subsequently applied to determine the potential energy surfaces of triatomic systems in electronic $s$ - and $p$ -Rydberg states. Their molecular geometry and resulting vibrational structure are analyzed within an adiabatic approach that separates the vibrational bending and stretching dynamics. This procedure yields information on the radial and angular arrangement of the nuclei and indicates in particular that kinetic couplings between bending and stretching modes induce a linear structure in triatomic $l=0$ ultralong-range Rydberg molecules.We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground-state atoms bound to a Rydberg atom via $s$- and $p$-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg electron Green's function we reduce the computational effort to solve the electronic problem substantially. This method is subsequently applied to determine the potential energy surfaces of triatomic systems in electronic $s$- and $p$-Rydberg states. Their molecular geometry and resulting vibrational structure are analyzed within an adiabatic approach that separates the vibrational bending and stretching dynamics. This procedure yields information on the radial and angular arrangement of the nuclei and indicates in particular that kinetic couplings between bending and stretching modes induce a linear structure in triatomic $l=0$ ultralong-range Rydberg molecules.

arXiv:1605.03856Physical Review AJul 28, 201629 citations

Decay Dynamics of High Rydberg States in Atoms and Molecules: Discussion

Paul Marie Guyon, Uzi Even

Aug 1, 19970 citations

Collisions of Rydberg Atoms with Molecules

F. B. Dunning, R. F. Stebbings

Annual Review of Physical ChemistryOct 1, 198240 citations

Ultralong-range triatomic Rydberg molecules in an electric field

Javier Aguilera Fernández, Peter Schmelcher, Rosario González‐Férez

Abstract We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the s -wave and p -wave interactions, we perform electronic structure calculations and analyze the adiabatic electronic potentials evolving from the Rb ( n = 35 , l ≥ 3 ) Rydberg degenerate manifold. We hereby focus on three different classes of geometries of the Rydberg molecules, including symmetric, asymmetric and planar configurations. The metamorphosis of these potential energy surfaces in the presence of an external electric field is explored.Abstract We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the s -wave and p -wave interactions, we perform electronic structure calculations and analyze the adiabatic electronic potentials evolving from the Rb ( n = 35 , l ≥ 3 ) Rydberg degenerate manifold. We hereby focus on three different classes of geometries of the Rydberg molecules, including symmetric, asymmetric and planar configurations. The metamorphosis of these potential energy surfaces in the presence of an external electric field is explored.

arXiv:1601.05049Journal of Physics B Atomic Molecular and Optical PhysicsMay 18, 201617 citations

We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground-state atoms bound to a Rydberg atom via

s

- and

p

-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg electron Green's function we reduce the computational effort to solve the electronic problem substantially. This method is subsequently applied to determine the potential energy surfaces of triatomic systems in electronic

s

- and

p

-Rydberg states. Their molecular geometry and resulting vibrational structure are analyzed within an adiabatic approach that separates the vibrational bending and stretching dynamics. This procedure yields information on the radial and angular arrangement of the nuclei and indicates in particular that kinetic couplings between bending and stretching modes induce a linear structure in triatomic

l=0

ultralong-range Rydberg molecules.