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Detection of ultracold ground state molecules with a time-of-flight mass spectrometer [Kurzvortrag]

Stephan David Kraft, Peter Frøhlich Staanum, Jochen Mikosch, Jörg Lange, Roland Wester, A. Fioretti, Matthias Weidemüller

Published Jan 1, 2005• 0 citations
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Formation of Cold Cs2 Molecules through Photoassociation

A. Fioretti, D. Comparat, A. Crubellier +3 more

We have performed photoassociative spectroscopy of cold Cs atoms in a vapor-cell magneto-optical trap, within $10{\mathrm{cm}}^{\ensuremath{-}1}$ below the dissociation limit $6s^{2}S_{1/2}+6p^{2}P_{3/2}$. Our detection method is based on pulsed-laser photoionization of ${\mathrm{Cs}}_{2}$ molecules, selectively detected through a time-of-flight mass spectrometer. Temporal and spatial analysis of ${\mathrm{Cs}}_{2}^{+}$ ions show for the first time the formation of translationally cold ${\mathrm{Cs}}_{2}$ triplet ground state molecules, at a temperature $T\ensuremath{\sim}300\ensuremath{\mu}\mathrm{K}$.

Physical Review Letters•May 18, 1998•545 citations
We have performed photoassociative spectroscopy of cold Cs atoms in a vapor-cell magneto-optical trap, within $10{\mathrm{cm}}^{\ensuremath{-}1}$ below the dissociation limit 6s2S1/2+6p2P3/26s^{2}S_{1/2}+6p^{2}P_{3/2}6s2S1/2​+6p2P3/2​. Our detection method is based on pulsed-laser photoionization of Cs2{\mathrm{Cs}}_{2}Cs2​ molecules, selectively detected through a time-of-flight mass spectrometer. Temporal and spatial analysis of Cs2+{\mathrm{Cs}}_{2}^{+}Cs2+​ ions show for the first time the formation of translationally cold Cs2{\mathrm{Cs}}_{2}Cs2​ triplet ground state molecules, at a temperature $T\ensuremath{\sim}300\ensuremath{\mu}\mathrm{K}$.