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Thermalization Dynamics in Open Quantum Systems: Competition Between Hamiltonian Strength and Decoherence Rate

M. L. Smith

Published Jan 23, 2026• 0 citations
Publisher

Abstract

Abstract Understanding thermalization and irreversibility in open quantum systems requires char-acterizing the competition between coherent unitary dynamics and dissipative environmen-tal interactions. In this work, we present a systematic numerical study of thermalization dynamics in a two-qubit open quantum system governed by a completely positive and trace-preserving Lindblad master equation. The coherent evolution rate is controlled by a real scaling parameter α multiplying the Hamiltonian commutator, while decoherence is indepen-dently controlled by a dephasing rate γ . Although such a scaling of coherent dynamics can be absorbed into a rescaling of time in isolated systems, it becomes physically meaningful in open systems where decoherence introduces an absolute timescale. We investigate how the relative strength of coherent evolution and decoherence influences observable dynamics, purity decay, entropy production, and thermalization times. Using robust local and two-site observables, we show that varying α at fixed γ produces distinct transient trajectories, even though all evolutions converge to the same steady state. We further define an operational thermalization time τ ( γ, α ) based on a purity threshold and map the resulting thermalization-time surface across a broad parameter range. Increasing α generally accelerates oscillatory dynamics and modifies the approach to equilibrium, leading to measurable shifts in thermalization times without altering asymptotic states. These findings provide a clear and physically consistent characterization of how Hamil-tonian strength and decoherence rate jointly determine thermalization behavior in open quantum systems. The framework offers a practical parameterization for numerical mod-eling and experimental studies of coherent–dissipative competition in quantum information processing, quantum control, and open-system dynamics.

DOI
10.21203/rs.3.rs-8629227/v1

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Abstract Understanding thermalization and irreversibility in open quantum systems requires char-acterizing the competition between coherent unitary dynamics and dissipative environmen-tal interactions. In this work, we present a systematic numerical study of thermalization dynamics in a two-qubit open quantum system governed by a completely positive and trace-preserving Lindblad master equation. The coherent evolution rate is controlled by a real scaling parameter α multiplying the Hamiltonian commutator, while decoherence is indepen-dently controlled by a dephasing rate γ . Although such a scaling of coherent dynamics can be absorbed into a rescaling of time in isolated systems, it becomes physically meaningful in open systems where decoherence introduces an absolute timescale. We investigate how the relative strength of coherent evolution and decoherence influences observable dynamics, purity decay, entropy production, and thermalization times. Using robust local and two-site observables, we show that varying α at fixed γ produces distinct transient trajectories, even though all evolutions converge to the same steady state. We further define an operational thermalization time τ ( γ, α ) based on a purity threshold and map the resulting thermalization-time surface across a broad parameter range. Increasing α generally accelerates oscillatory dynamics and modifies the approach to equilibrium, leading to measurable shifts in thermalization times without altering asymptotic states. These findings provide a clear and physically consistent characterization of how Hamil-tonian strength and decoherence rate jointly determine thermalization behavior in open quantum systems. The framework offers a practical parameterization for numerical mod-eling and experimental studies of coherent–dissipative competition in quantum information processing, quantum control, and open-system dynamics.
We present a comprehensive analytical and numerical study of time-dependent decoherence in open quantum systems, focusing on a single-qubit model with time-varying Lindblad dissipation rates. Employing a master equation framework, we derive exact solutions for the evolution of off-diagonal density matrix elements and characterize the emergence of robust pointer states. Our findings reveal an initial rapid coherence decay followed by a gradual slowdown, mirroring experimental trends observed in superconducting qubits influenced by quasiparticle dynamics and in photonic cavities subject to fluctuating environments. By incorporating real experimental parameters and validating the model through quantum simulations using QuTiP, we provide a robust quantitative tool for analyzing decoherence in quantum technologies. This extended model addresses limitations in static-rate approximations, offering insights into non-Markovian effects without resolving the measurement problem, and suggests extensions to multi-qubit systems.
Open quantum systems with nearly degenerate energy levels have been shown to exhibit long-lived metastable states in the approach to equilibrium, even when modelled with certain Lindblad-form quantum master equations. This is a result of dramatic separation of timescales due to differences between Liouvillian eigenvalues. These metastable states often have nonzero coherences that die off only in the long-time limit once the system reaches thermal equilibrium. We examine two distinct situations that give rise to this effect: one in which dissipative dynamics couple together states only within a nearly degenerate subspace, and one in which they give rise to jumps over finite-energy splittings, between nearly degenerate subspaces. We find, in each case, that a change of basis can often lead to a representation that more naturally captures the impact of the system-bath interaction than does the energy eigenbasis, revealing that separate timescales are associated with separate processes (e.g., decoherence into a nonenergy eigenbasis, decay of population correlations to the initial state). This approach is paired with the inspection of quantum trajectories, which further provide intuition as to how open system evolution is characterized when coherent oscillations, thermal relaxation, and decoherence all occur simultaneously. Published by the American Physical Society 2024
The study of entanglement has gained prominence in recent years due to the advent of fields such as Quantum Optics and Quantum Information Theory — advances that have harnessed such counter-intuitive quantum phenomena into elements of everyday life, improving it in the process. Ideal quantum systems, “closed” to the outside world, remain quantum forever and thus manage to retain entanglement. Real quantum systems, however, are “open” to the environment and are therefore susceptible to the phenomenon of decoherence. The resultant loss of entanglement is a major hindrance to the effectiveness of quantum information tasks. In this thesis we have studied the evolution of entanglement in various types of open quantum systems (OQS) coupled in various ways to local baths. We have also studied existing ways and means of controlling the decay of entanglement and have proposed a new method of doing so. We have studied the evolution of entanglement in OQS undergoing Markovian dynamics by using the Lindblad master equation as well as the method of quantum trajectories. We have analyzed the onset of the phenomenon of entanglement sudden death in finite as well as infinite dimensional OQS, connected either locally to a thermal bath or its squeezed variant, or via a quantum non-demolition-type (QND-type) interaction to a local thermal bath. We have found that the QND-type system-bath interaction works best to conserve entanglement in finite dimensional systems, whereas a squeezed thermal bath causes entanglement sudden death even at zero temperature. We have also studied some well-known methods of controlling decoherence in open systems with respect to their ability of preserving entanglement. Some of these procedures include coupling the system to a thermal bath of photonic crystals where the photonic band gap suppresses decoherence, modulation of the systembath frequency in an attempt to contain decoherence, using the method of resonance fluorescence where an external field modulates the transition frequency of the two-qubit systems with each qubit being a two-state atomic system to contain decoherence, and using high-frequency radio waves to decouple the system and bath dynamically and thus reducing decoherence. Our study has revealed a rather startling fact — some of these decoherence control procedures actually result in an elevated rate of loss and a resultant quicker death of entanglement. This is a 6 surprising and extremely counter-intuitive result. Finally, we have proposed a new method of shielding the entanglement in the system from dissipative environmental effects. In this procedure, an ancillary system in a fixed initial state is allowed to interact with the main system through exchange interactions. We have, through numerical computation, showed that an ancilla in the ground state extends the lifespan of entanglement in the main system. Increasing the size of the ancilla, that is, increasing the value of n in an n-qubit ancilla slows down entanglement loss for a two-qubit system connected locally to a thermal bath.
The hyperfine structure of the hydrogen atom provides a clean, experimentally relevant two-qubit platform in which the coupled electron and proton spins exhibit rich quantum behavior. We investigate the open-system dynamics of this system under the simultaneous influence of the intrinsic hyperfine coupling, an external static magnetic field (via the Zeeman interaction), and local Markovian dephasing noise. Employing the Lindblad master equation, we derive the exact time evolution of the density matrix for general X-shaped initial states and focus on two complementary measures of quantum coherence—the L1-norm coherence CL(t) and the relative entropy of coherence CR(t)—together with the state purity P(t). Numerical results reveal that all three quantities display characteristic damped oscillatory evolution. For a vanishing magnetic field, the decay is relatively rapid and smooth, whereas increasing the proton magnetic parameter markedly raises the oscillation frequency and slows the overall envelope of both coherence and purity. Even under stronger dephasing rates, a suitably chosen external field can substantially postpone the loss of quantum features, acting effectively as a control knob that reshapes the coherent unitary dynamics to counteract dissipative effects. These findings underscore the delicate competition between intrinsic atomic interactions and environmental noise, while offering a practical route for protecting quantum resources in spin-based systems. Our work bridges fundamental atomic physics with resource-theoretic concepts and highlights promising strategies for coherence preservation in realistic, controllable quantum platforms.
In this work, we investigate the quantum coherence and purity in hydrogen atoms under dissipative dynamics, with a focus on the hyperfine structure states arising from the electron-proton spin interaction. Using the Lindblad master equation, we model the time evolution of the density matrix of the system, incorporating both the unitary dynamics driven by the hyperfine Hamiltonian and the dissipative effects due to environmental interactions. Quantum coherence is quantified using the L1 norm and relative entropy measures, while purity is assessed via von Neumann entropy, for initial states, including a maximally entangled Bell state and a separable state. Our results reveal distinct dynamics: for the Bell states, both coherence and purity decay exponentially with a rate proportional to the dissipation parameter, whereas for a kind of separable state, coherence exhibits oscillatory behavior modulated via the hyperfine coupling constant, superimposed on an exponential decay, and accompanied by a steady increase in entropy. Higher dissipation rates accelerate the loss of coherence and the growth of von Neumann entropy, underscoring the environment's role in suppressing quantum superposition and driving the system towards mixed states. These findings enhance our understanding of coherence and purity preservation in atomic systems and offer insights for quantum information applications where robustness against dissipation is critical.