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A Phenomenological Framework for Entropy-Driven Decoherence and the Thermodynamic Arrow of Time

Vasiliki Sioutopoulou

Published Jan 11, 2026• 0 citations
Publisher

Abstract

We propose a speculative but quantitatively constrained phenomenological framework in which the thermodynamic arrow of time emerges from entropy-dependent decoherence in open quantum systems. Higher environmental entropy strengthens decoherence, preferentially de- stroying quantum coherence in one temporal direction, thus providing a microscopic mechanism for irreversibility. The formalism is constructed within an effective Lindblad master-equation approach, recovering unitary quantum mechanics and standard thermodynamics in appropriate limits. A toy two-level system illustrates the emergence of coherence decay and an effective microscopic arrow of time.

DOI
10.5281/zenodo.18213439

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Annals of Physics•Dec 3, 2025•1 citation
We propose a speculative but quantitatively constrained phenomenological framework in which the thermodynamic arrow of time emerges from entropy-dependent decoherence in open quantum systems. Higher environmental entropy strengthens decoherence, preferentially de- stroying quantum coherence in one temporal direction, thus providing a microscopic mechanism for irreversibility. The formalism is constructed within an effective Lindblad master-equation approach, recovering unitary quantum mechanics and standard thermodynamics in appropriate limits. A toy two-level system illustrates the emergence of coherence decay and an effective microscopic arrow of time.
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The arrow of time paradox between quantum mechanics and thermodynamicsarises from the fundamental conflict between the time-symmetric evolution of thewave function and the irreversible increase of thermodynamic entropy. This pa?per introduces a ”small observer” model with quantum resolution capabilities andcombines quantum measurement theory with open quantum system dynamics toreveal the influence of observer scales on the perception of the arrow of time. Byestablishing a quantum master equation model for N coupled small observers, wedemonstrate the emergence of macroscopic thermodynamic entropy from micro?scopic quantum entropy production, providing a novel theoretical framework forunifying the understanding of the arrow of time. Numerical simulations based onthe quantum Darwinism framework validate the theoretical predictions.
Standard quantum mechanics describes the evolution of physical systems through unitary Schr¨odinger dynamics, while decoherence and wavefunction collapse are introduced through additional postulates or environmental interactions. Although highly successful operationally, the theory does not provide a fundamental dynamical mechanism explaining the emergence of classical localization from microscopic evolution. n this work we propose an entropy-weighted causal dynamics framework, referred to as Quantum Causal Entropy (QCE), in which each microscopic causal transition contributes both a phase increment and an entropy cost. Starting from a local causal update rule, Ψ → eiθℓ−∆SℓΨ, we derive a modified evolution equation in which the standard Hamiltonian generator is supplemented by an entropy-production operator. The resulting entropy-corrected Schr¨odinger equation takes the form iℏ dΨ dt =H − iℏλSˆΨ, where Sˆ represents the entropy rate associated with microscopic causal processes and λ is an entropy coupling constant. We show that the standard unitary Schr¨odinger evolution is recovered in the limit of vanishing entropy coupling, while finite entropy production leads naturally to decoherence, interference suppression, and effective measurement localization without invoking an explicit collapse postulate. A corresponding density-matrix evolution equation is derived, providing a thermodynamic description of coherence decay. The framework therefore provides a dynamical link between quantum evolution, information entropy, and emergent classicality, and suggests experimentally testable corrections to coherence behavior in controlled quantum systems
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This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.