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ISTE , Wiley eBooks

Bose-Einstein Condensates

Kamel Ourabah

Published Jan 5, 2024• 0 citations
Publisher

Abstract

This chapter will focus on the application of kinetic and hydrodynamic approaches to Bose–Einstein condensates. A Bose–Einstein condensate is a state of matter, formed of identical bosons (usually atoms behaving like bosons), so that at a sufficiently low temperature, many of the particles making up the system occupy the lowest energy state (ground state). This is only possible for bosons (particles with an integer spin) unlike fermions (particles with a half-integer spin) due to the Pauli exclusion principle.

DOI
10.1115/1.862ppe_ch7

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This chapter will focus on the application of kinetic and hydrodynamic approaches to Bose–Einstein condensates. A Bose–Einstein condensate is a state of matter, formed of identical bosons (usually atoms behaving like bosons), so that at a sufficiently low temperature, many of the particles making up the system occupy the lowest energy state (ground state). This is only possible for bosons (particles with an integer spin) unlike fermions (particles with a half-integer spin) due to the Pauli exclusion principle.
Bose Einstein Condensate (BEC) is the fifth state of matter in condensed matter physics. It is the most impressive example of quantum behaviour on a macroscopic scale but the most difficult state to observe. When low-density boson gas is cooled to a temperature nearly absolute zero, then BEC is formed. In this condition, the bosons have almost no free energy to move relative to each other. They clump together, come into the lowest quantum state, and behave as a single atom. Then microscopic quantum mechanical phenomena work on a macroscopic scale. This chapter summarizes the history and the developments regarding BEC with a brief discussion of the key scientists in this field. In the next section, the summary of the all chapters is given.
In 1924 the Indian physicist Satyendra Nath Bose sent Einstein a paper in which he derived the Planck law for black-body radiation by treating the photons as a gas of identical particles. Einstein generalized Bose's theory to an ideal gas of identical atoms or molecules for which the number of particles is conserved and, in the same year, predicted that at sufficiently low temperatures the particles would become locked together in the lowest quantum state of the system. We now know that this phenomenon, called Bose-Einstein condensation (BEC), only happens for “bosons” – particles with a total spin that is an integer multiple of h, the Planck constant divided by 2π.
In quantum mechanics, elementary particles of the same type are considered identical. For example, an electron in an atom could be replaced by another electron and the atom would behave in exactly the same way. Nature has taken particular advantage of this, allowing only two types of elementary particles: bosons and fermions. They differ fundamentally in how a collection of identical particles interact. Identical fermions cannot occupy the same quantum state (only one per state!). Identical bosons can occupy the same quantum state. The statistics of identical particles (how they act in groups) has profound affects. For example, the rich and complex structure of the periodic table arises from the principle that only one electron can occupy each quantum state. The spin and the statistics of particles are closely connected: (fermions) bosons have (half-)integer spin. (Spin is an internal angular momentum measured in units of Planck’s constant.)
Bose-Einstein condensation is a macroscopic quantum phenomenon that was first predicted by Albert Einstein in the 1920s, at a time when quantum theory was still developing and was being applied to microscopic systems, such as individual particles and atoms. Einstein applied the new concept of Bose statistics to an ideal gas of identical atoms that were at thermal equilibrium and trapped in a box. He predicted that at sufficiently low temperatures the particles would accumulate in the lowest quantum state in the box, giving rise to a new state of matter with many unusual properties.
Bose–Einstein condensation is a phenomenon, first proved by Einstein, in which a gas of bosons condenses into the lowest quantum state below a certain critical temperature. It occurs due to the symmetry, under particle exchange, of the boson wave function. The chapter discusses temperature, the Kelvin scale, the concept of absolute zero, and how laser cooling can reach ultralow temperatures. The property of bosons in which they often prefer to be in the same state is seen to apply to lasers, superfluid liquid helium, and to dilute nearly ideal gases. The latter are trapped in magnetic or optical potential wells where the condensation can be observed directly. These large condensate matter waves show quantum interference in a variety of possible experiments.
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.