This article is a continuation of Part(I) to demonstrate more aspects for a successful merge of classical mechanics to the quantum theory. The article starts first with the deduction of the general form of the complimentary energy, next a robust firm mathematical proof is given indicates that the complimentary energy has a wave nature and it is a potential energy, then the radiation condition has been determined, a vector formula expresses the corresponding force was deduced and this force was called adhesion force. A mathematical convergence process has proved the duality of the electromagnetic wave parameters and particle parameters, which results in the existence of a “wave-particle” object. While finding the relationship between the electromagnetic wave parameters and particle parameters, a mathematical relationship was found indicating that not every moving charged mass generates a magnetic field. This relationship for the mass was linked to the effective mass tensor, The geometric representation of the constant energy surface and its relationship to the energy levels of both the orbital model (Bohr model) and the cloud model for different geometric 3D shapes were investigated as a sample of the possible geometric interpretations of the energy equation, that is by employing the triangle method, it is possible to create a geometric representation of the constant energy surfaces. The relation between the energy levels, quantum numbers, and band width is represented geometrically. As a result of proving the relationship between the motion of an electromagnetic wave and the motion of a particle associated with the wave, two new, unprecedented mathematical formulas were developed. The first formula specifies a moving charged mass and its relationship to the resulting wavelength. Thus, the radius of the charged mass is obtained in terms of its wavelength and mass density. The second formula specifies the kinetic energy of a photon. The grand potentials are the potential energy of the Newton’s Law of Universal Gravitation, Coulomb’s Law, and Inverse Square Law of Electromagnetic Waves Intensity. From the potential energy of Newton’s law of universal gravitation, the wavelength of the gravitational wave, as well as the wavelength of quantum gravity were deduced. A mathematical relationship was then deduced that determines the lengths of the functions of conic sections, and in particular the length of perimeter of ellipses. From the potential energy of Coulomb’s law of attraction, a mathematical formulation of the energy levels in general for any atom of an element was obtained. This mathematical formulation was compared with the results obtained by Bohr and Schrödinger for the hydrogen atom. As for the inverse square law of electromagnetic radiation intensity, several innovative mathematical equations have been deduced that link different parameters together. Following the contents of this article requires to be quite familiar with the contents of the first part with the same title, as well as a complete understanding of the concepts of intermediate parameters derived and used in the various equations. Otherwise, it will be extremely difficult to follow the contents of this article.
This article is a continuation of Part(I) to demonstrate more aspects for a successful merge of classical mechanics to the quantum theory. The article starts first with the deduction of the general form of the complimentary energy, next a robust firm mathematical proof is given indicates that the complimentary energy has a wave nature and it is a potential energy, then the radiation condition has been determined, a vector formula expresses the corresponding force was deduced and this force was called adhesion force. A mathematical convergence process has proved the duality of the electromagnetic wave parameters and particle parameters, which results in the existence of a “wave-particle” object. While finding the relationship between the electromagnetic wave parameters and particle parameters, a mathematical relationship was found indicating that not every moving charged mass generates a magnetic field. This relationship for the mass was linked to the effective mass tensor, The geometric representation of the constant energy surface and its relationship to the energy levels of both the orbital model (Bohr model) and the cloud model for different geometric 3D shapes were investigated as a sample of the possible geometric interpretations of the energy equation, that is by employing the triangle method, it is possible to create a geometric representation of the constant energy surfaces. The relation between the energy levels, quantum numbers, and band width is represented geometrically. As a result of proving the relationship between the motion of an electromagnetic wave and the motion of a particle associated with the wave, two new, unprecedented mathematical formulas were developed. The first formula specifies a moving charged mass and its relationship to the resulting wavelength. Thus, the radius of the charged mass is obtained in terms of its wavelength and mass density. The second formula specifies the kinetic energy of a photon. The grand potentials are the potential energy of the Newton’s Law of Universal Gravitation, Coulomb’s Law, and Inverse Square Law of Electromagnetic Waves Intensity. From the potential energy of Newton’s law of universal gravitation, the wavelength of the gravitational wave, as well as the wavelength of quantum gravity were deduced. A mathematical relationship was then deduced that determines the lengths of the functions of conic sections, and in particular the length of perimeter of ellipses. From the potential energy of Coulomb’s law of attraction, a mathematical formulation of the energy levels in general for any atom of an element was obtained. This mathematical formulation was compared with the results obtained by Bohr and Schrödinger for the hydrogen atom. As for the inverse square law of electromagnetic radiation intensity, several innovative mathematical equations have been deduced that link different parameters together. Following the contents of this article requires to be quite familiar with the contents of the first part with the same title, as well as a complete understanding of the concepts of intermediate parameters derived and used in the various equations. Otherwise, it will be extremely difficult to follow the contents of this article.
Since the interest in the quantum phenomena started, there have been two main approaches to the quantum theory, the first approach investigates the motion of a wave-particle object by assuming the wave has the characteristics of a moving particle, momentum and energy, this approach was developed by physicists Max Planck, Albert Einstein, and others. The second approach investigates the motion of a particle-wave object by assuming the particle has the characteristics of a moving wave, wavelength, wave vector, and frequency, this approach was developed by physicists De Broglie, Schrodinger and others which led to the presence of quantum mechanics. This article focuses on the second approach and merging it with classical mechanics. An early mathematical formulation for the quantum theory was proposed by De Broglie’s relations and later on, another formulation was given by Schrodinger’s equation. A successful attempt to bridge the gap between classical mechanics with quantum theory implemented via a mathematical derivation for De Broglie’s relations and Schrodinger formulation, The derivation process overcame a main obstacle was the convergence of the deterministic nature of classical mechanics with the probabilistic nature of the quantum theory by adopting an innovative method based upon replacing constant values in a deterministic relation with probabilistic variables in the same relation, and this led to switch the relation from deterministic representation to probabilistic representation. Both classical and quantum explanation are given for the deduced formulas. An energy approach is instrumented. Since classical mechanics formulas are not sufficient to explain the quantum phenomena, a new concept of complementary energy introduced in order to connect the parameters of a moving particle with the parameters of an associated wave, the value of the complementary energy for each particle adjusted the total energy equation of N moving particles without changing the magnitude of the total energy of a system of N particles. In special cases, the value of the complementary energy for some particles equals the value of the total energy for the particles. The derivation process indicates that complementary energy corresponds to the potential energy on the surface of the material which prevents the particles to escape from the boundary of the matter to the outer space and maintains its coherence, complementary energy concept also manifest the impact of the moving particles on a single particle due to the energy conveyed during direct contact in case of collision or by the remote influence through an existing field in the space, so it represents an energy of dual nature for both matter and radiation wave combined. The complementary energy is not introduced as mathematical assumption in order to manipulate the total energy equation, it’s actually exists in the total energy equation and its validity has not been applied before. A general format for any potential energy is obtained regardless the nature of field it represents (a universal format for potential energy) that is by using mathematical manipulation for the equation of total energy of N moving particles. The derivation process led to a particle-wave formula. The substitution into the particle-wave formula with the speed of light, De Broglie’s relations, revealed. Some additional applications for the particle-wave formula are suggested, also as a well known energy quantization formula obtained by applying all of De Broglie’s relation, a general energy, and speed formulas resulting during the derivation process. Matching time independent equation called Schrodinger’s amplitude equation with classical mechanics formulation demonstrated by deducing both the wave function and the magnitude of the wave vector from the classical formulation after converting it to probabilistic formulation. A dedicated section for wave function solutions for Schrodinger’s time dependent equation was given in terms of the wave functions and the magnitude of the wave vectors obtained from the matching process of Schrodinger’s amplitude equation with classical mechanics.
The explanation of quantum mechanics has never been satisfactory. The successful application of quantum mechanics is generally attributed to the mathematical system of quantum mechanics. The application research of quantum encryption communication and quantum computers using quantum entanglement is very difficult. The binary opposition between quantum and classical has hindered human scientific thinking. The widespread quest to quantize gravity mirrors humanity's enduring drive to unify quantum and macroscopic physical frameworks. This research initiates its inquiry by integrating quantum mechanics with classical mechanics, yielding novel analytical perspectives, and introduces the Schrödinger-Tu equation—a wave function that incorporates gravitational potential energy and is capable of describing macroscopic objects. Validating the practical viability of merging quantum and classical approaches, several computational cases involving atoms and molecules yield successful outcomes. Additionally, this study derives a wavemechanical formulation of classical mechanical laws, furnishing direct empirical evidence that quantum mechanics and classical mechanics are not mutually exclusive but rather compatible and complementary. Further substantiation of their compatibility encompasses the following key points: The mass term m in the Schrödinger equation (SE) can be scaled to sufficiently large values to characterize macroscopic entities; The steady-state SE (Tψ+Vψ=Eψ) inherently integrates the wave function ψ with the classical energy conservation relation T+V=E; Potential energy functions within the SE can be derived from macroscopic force fields; Newton's second law F=ma and the SE are mutually derivable, establishing a fundamental theoretical linkage; Electron diffraction experiments concurrently demonstrate wave-particle duality, a phenomenon that bridges both mechanical frameworks. This paradigm shift—recasting the relationship between quantum mechanics and classical mechanics from one of incompatibility to compatibility—represents a pivotal theoretical advancement, with the potential to catalyze the development of a generalized wave mechanics.
The widespread quest to quantize gravity mirrors humanity’s enduring drive to unify quantum and macroscopic physical frameworks. This research initiates its inquiry by integrating quantum mechanics with classical mechanics, yielding novel analytical perspectives, and introduces the Schrödinger-Tu equation—a wave function that incorporates gravitational potential energy and is capable of describing macroscopic objects. Validating the practical viability of merging quantum and classical approaches, several computational cases involving atoms and molecules yield successful outcomes. Additionally, this study derives a wave-mechanical formulation of classical mechanical laws, furnishing direct empirical evidence that quantum mechanics and classical mechanics are not mutually exclusive but rather compatible and complementary. Further substantiation of their compatibility encompasses the following. key points: • The mass term m in the Schrödinger equation (SE) can be scaled to sufficiently large values to characterize macroscopic entities • The steady-state SE (Tψ +Vψ=Eψ) inherently integrates the wave function ψ with the classical energy conservation relation T+V=E; • Potential energy functions within the SE can be derived from macroscopic force fields; • Newton’s second law F=ma and the SE are mutually derivable, establishing a fundamental theoretical linkage; 5.Electron diffraction experiments concurrently demonstrate wave-particle duality, a phenomenon that bridges both mechanical frameworks.This paradigm shift—recasting the relationship between quantum and classical mechanics from one of incompatibility to ompatibility—represents a pivotal theoretical advancement, with the potential to catalyze the development of a generalized wave echanics.
We use 3 equations as postulates: Pem referring to electromagnetism, Pgrav referring to gravity, and Pqm referring to quantum mechanic and defining the wave function. Combining Pem with Sommerfeld's quantum rules corresponds to the original quantum theory of Hydrogen, which produces the correct relativistic energy levels of atoms (Sommerfeld's and Dirac's theories of matter produces the same energy levels, and Schrodinger's theory produces the approximation of those energy levels). Pqm implies that the wave function is solution of both Schrodinger's and Klein-Gordon's equations in the non interacting case while, in the interacting case it implies Sommerfeld's quantum rules: Pem and Pqm then produce the correct relativistic energy levels of atoms (the same as Dirac's energy levels). We check that the required degeneracy is justified by pure deduction, without any other assumption (Schrodinger's theory only justifies one half of the degeneracy). We observe the connection between Pqm, Quantum Field Theories and tunnel effect. From Pgrav we deduce an equation of motion very similar to general relativity (with accuracy 10^{-6} at the surface of the Sun), our postulate being explicitly an approximation. First of all, we discuss classical Kepler problems (Newtonian motion of the Earth around the Sun), explain the link between Kelpler's law of periods (1619) and Plank's law (1900) and observe the links between all historical models of atoms (Bohr, Sommerfeld, Pauli, Schrodinger, Dirac, Fock).
People believe that the Schrödinger equation cannot be used to describe macroscopic objects like the Earth, and Newtonian mechanics cannot be used to describe microscopic systems. The old concept of the relationship between the existing laws of quantum mechanics and classical mechanics undoubtedly has a serious impact on people's understanding of the natural world, the development of physics theories, and the application of existing physics theories. The continuous development of physics theory requires constant changes to some incorrect old concepts. The Schrödinger equation that can describe planetary motion was successfully obtained by replacing the potential energy in the Hamiltonian operator from electromagnetic interaction potential energy to gravitational interaction potential energy. If the distance between the sun and the earth is approximated as a constant, the energy eigenvalues obtained by solving the Schrödinger equation for the Earth's revolution are completely consistent with the results obtained directly using classical mechanics. The direct significance of establishing and applying such equations is that they can simultaneously use classical mechanics and wave dynamics to describe all objects (no longer limited by the mass of the objects), simplifying the calculation process of quantum mechanics. It has been proven that classical mechanics and wave dynamics are compatible, and there is no insurmountable gap between them. This result has a huge positive impact on the theoretical updates and applications of quantum mechanics.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.