Controlling the states of quantum systems is a subject of major interest for both fundamental science and technological development. In this thesis, we carry out theoretical studies on how this can be achieved using light, both of classical and of quantum mechanical nature. We study a driven cavity system, where the driving field is classical and the cavity field is quantum mechanical. We demonstrate how virtual scattering of driving photons inside the cavity via two-photon processes can induce controllable long-range electron interactions in two-dimensional materials. We show that both the strength and the sign of the interactions can be tuned by the driving parameters and that the interactions are not screened effectively except at very low frequencies. For realistic cavity parameters, driving-induced heating of the electrons by inelastic photon scattering is suppressed and coherent electron interactions dominate. When the interactions are attractive, they cause an instability in the Cooper channel at a temperature proportional to the square root of the driving intensity. Our results open up a new avenue for engineering quantum materials on-demand and the possibility of studying the effect of long-range interactions in condensed matter systems. Following that, we take a more general approach to investigate the effect of long-range density-density electron attractive interactions on a superconductor. We show that the low-lying excitations of a 2D conventional superconductor can be significantly altered by these long-range interactions. Using BCS theory, we find that these interactions combine non-linearly with the intrinsic local attractions of the superconductor to increase the Bogoliubov quasiparticle excitation energies, thus enlarging the superconducting gap. Moreover, we show how the long-range nature of the driven-cavity-induced attractions qualitatively changes the collective excitations of the superconductor. Specifically, they lead to the appearance of additional collective excitations of the excitonic modes. They further push the Higgs mode "in gap": it lies below the Bogoliubov quasiparticle continuum such that it cannot decay through the quasiparticle excitations.
Controlling the states of quantum systems is a subject of major interest for both fundamental science and technological development. In this thesis, we carry out theoretical studies on how this can be achieved using light, both of classical and of quantum mechanical nature. We study a driven cavity system, where the driving field is classical and the cavity field is quantum mechanical. We demonstrate how virtual scattering of driving photons inside the cavity via two-photon processes can induce controllable long-range electron interactions in two-dimensional materials. We show that both the strength and the sign of the interactions can be tuned by the driving parameters and that the interactions are not screened effectively except at very low frequencies. For realistic cavity parameters, driving-induced heating of the electrons by inelastic photon scattering is suppressed and coherent electron interactions dominate. When the interactions are attractive, they cause an instability in the Cooper channel at a temperature proportional to the square root of the driving intensity. Our results open up a new avenue for engineering quantum materials on-demand and the possibility of studying the effect of long-range interactions in condensed matter systems. Following that, we take a more general approach to investigate the effect of long-range density-density electron attractive interactions on a superconductor. We show that the low-lying excitations of a 2D conventional superconductor can be significantly altered by these long-range interactions. Using BCS theory, we find that these interactions combine non-linearly with the intrinsic local attractions of the superconductor to increase the Bogoliubov quasiparticle excitation energies, thus enlarging the superconducting gap. Moreover, we show how the long-range nature of the driven-cavity-induced attractions qualitatively changes the collective excitations of the superconductor. Specifically, they lead to the appearance of additional collective excitations of the excitonic modes. They further push the Higgs mode "in gap": it lies below the Bogoliubov quasiparticle continuum such that it cannot decay through the quasiparticle excitations.
We show that low-lying excitations of a 2D Bardeen--Cooper--Schrieffer superconductor are significantly altered when coupled to an externally driven cavity, which induces controllable long-range attractive interactions between the electrons. We find that they combine nonlinearly with intrinsic local interactions to increase the Bogoliubov quasiparticle excitation energies, thus enlarging the superconducting gap. The long-range nature of the driven-cavity-induced attraction qualitatively changes the collective excitations of the superconductor. Specifically, they lead to the appearance of additional collective excitations of the excitonic modes. Furthermore, the Higgs mode is pushed into the gap and now lies below the Bogoliubov quasiparticle continuum such that it cannot decay into quasiparticles. This way, the Higgs mode's lifetime is greatly enhanced.
When in a quantum optical system the coupling between matter and cavity mode becomes comparable to the bare excitation frequency, we enter a non-perturbative coupling regime, as perturbation theory fails describing the system’s dynamics. While recent advances in Cavity Quantum Electrodynamics allowed to achieve very high values of the coupling strength, thanks to the resonators properties optimization and the employment of solid-state devices, an ever growing interest has been shown about the possibility of significantly modify materials’ properties. It has been demonstrated that the chemical structure of molecules strongly coupled to a photon mode can be altered, which opens the possibility to manipulate and control chemical reactions. The aim of this thesis is to explore non-perturbative regimes on several quantum systems, and to investigate the effects of the coupling upon their properties, such as internal degrees of freedom or electronic states structure. I first developed a novel theory to determine the polariton spectrum of a dipolar ensamble in which a Ising-like dipole-dipole interaction in the 2 non-perturbative regime is considered. A further important focus is the investigation of the saturation effects due to the inclusion of the inter-dipole interaction, and the interplay between the latter and light-matter coupling strength. I also explored specifically the influence of the coupling on the rotational degrees of freedom of an ensemble of two-dimensional freely rotating dipoles, all coupled to a single cavity mode, finding that they are driven by the collective light-matter coupling to undergo a crossover between an isotropic and an aligned phase. I then investigated the case of cavity-embedded doped quantum wells, demonstrating that not only it is possible to couple a discrete cavity mode and bound-to-continuum transitions, but also that a novel bound exciton state appears, induced by the coupling strength. This results shows how light–matter coupling can be used to tune both optical and electronic properties of semiconductor heterostructures beyond those permitted by mere crystal properties. Finally, I explored the physics of an array of THz metamaterial resonators coupled to cyclotron resonances of a two-dimensional electron gas, developing a multiple-mode theory that takes in account the interaction between multiple photon modes mediated by the electrons. My results show that this cross-interaction, due to the strong two-dimensional geometry of the optically active medium, leads to the hybridization of different uncoupled photon modes, and manifests as a visible change of the distribution of the coupled electromagnetic field.
In modern physics, the investigation of the interaction between light and matter is important from both a fundamental and an applied point of view. Cavity quantum electrodynamics (cavity QED) is the study of the interaction between light confined in a reflective cavity and atoms or other particles where the quantum nature of light photons is significant. The strong interaction between an exciton and cavity photon in a high-finesse microcavity can induce a hybrid light-matter eigenstate which is usually named as polariton in solid-state systems. This strong light-matter interaction can be achieved when this interaction is larger than all broadenings caused by other various factors e.g. electron phonon scattering and cavity loss. The polariton is now stimulating tremendous research interests due to its high potential in cavity quantum electrodynamics (QED) and the achievement of polaritonic devices. Moreover, when the interaction strength between an excitation and the cavity photon, quantified by vacuum Rabi frequency, becomes comparable to or larger than the corresponding electronic transition frequency in a cavity, the system can enter an ultrastrong coupling regime, which has been experimentally observed. In this regime, the standard rotating-wave approximation is no longer valid and the antiresonant term of the interaction Hamiltonian starts to play an important role, giving rise to exciting effects in cavity QED. The Aharonov-Bohm (AB) effect is a fundamental quantum phenomenon that bears the significance of the nature of electromagnetic fields and potentials. Besides its fundamental significance in quantum theory, its importance for applications in interferometric devices is omnipresent. Recently, since the 2D materials have triggered immense interest, some work has been done to integrate the AB effect with the electronic and transport properties of 2D materials. This thesis consists of two parts. In the first part, the light-matter coupling between cyclotron transition and photon is theoretically investigated in some 2-D materials such as the monolayer MoS2, graphene and monolayer black phosphorene (BP) systems. The results show that, in these 2-D materials, the ultrastrong light-matter coupling can be achieved at a high filling factor of Landau levels. Furthermore, we show that, in contrast to the case for conventional semiconductor resonators, the MoS2 system shows a vacuum instability. In monolayer MoS2 resonator, the diamagnetic term can still play an important role in determining magnetopolariton dispersion which is different from monolayer graphene system. The diamagnetic term arises from electron-hole asymmetry which indicates that electron-hole asymmetry can influence the quantum phase transition. Meanwhile, we show that, similar with some other 2D materials such as graphene and MoS2, the monolayer BP system shows a vacuum instability. However, in contrast with other 2D materials, the BP system displays a large energy gap between three branches of polaritons because of its strong anisotropic behavior in the eigenstates of the band structures. For the graphene system, we investigate the coupling of cyclotron transition and a multimode cavity described by a multimode Dicke model. This model exhibits a superradiant quantum phase transition, which we describe exactly in an effective Hamiltonian approach. The complete excitation spectrum in both the normal phase and superradiant phase regimes is given. At last, in contrast to the single mode case, multimode coupling of cavity photon and cyclotron transition can greatly reduce the critical vacuum Rabi frequency required for quantum phase transition, and dramatically enhance the superradiant emission by fast modulating the Hamiltonian. Our study provides new insights in cavity-controlled magneto-transport in these 2-D systems, which could lead to the development of polariton-based devices. The second part is a diversion from the main content of this thesis; readers who are not interested in foundational issues of physics can skip this part. For one charged quantum particle P moving in an electromagnetic vector potential Aˆµ = ( φˆ, - Aˆ ) created by some other charged particles, we can either use the framework of one particle quantum mechanics (OPQM) to calculate the evolutions of P, or we can treat this as an multi-particles problem in the framework of quantum field theory and calculate the evolution of P. These two methods need to be equivalent, i.e., they produce the same result for the evolution of P. One open question is how to describe the evolution of P within the framework of quantum field theory and show that these two methods yield the same result? In chapter 5, we are going to derive the OPQM from the quantum field theory, i.e., the quantum electrodynamics (QED) to be specific. We start with the discussions on the AB effect then raise a plausible interpretation within the QED framework. We provide a quantum treatment of the source of the electromagnetic potential and argue that the underlying mechanism in AB effect can be viewed as interactions between electrons described by QED theory where the interactions are mediated by virtual photons. On further analysis, we show that the framework of one particle quantum mechanics (OPQM) can be given, in general, as a mathematically approximated model which is reformulated from QED theory while the AB effect scheme provides a platform for our derivations. In addition, the classical Maxwell equations are derived from QED scattering process while both classical electromagnetic fields and potentials serve as mathematical tools that are constructed to approximate the interactions among elementary particles described by QED physics. This work opens up a new perspective on the nature of electromagnetic fields and potentials.
Confining electromagnetic fields inside an optical cavity can enhance the light–matter coupling between quantum materials embedded inside the cavity and the confined photon fields. When the interaction between the matter and the photon fields is strong enough, even the quantum vacuum field fluctuations of the photons confined in the cavity can alter the properties of the cavity-embedded solid-state materials at equilibrium and room temperature. This approach to engineering materials with light avoids fundamental issues of laser-induced transient matter states. To clearly differentiate this field from phenomena in driven systems, we call this emerging field cavity materials engineering . In this review, we first present theoretical frameworks, in particular, ab initio methods, for describing light–matter interactions in solid-state materials embedded inside a realistic optical cavity. Next, we overview a few experimental breakthroughs in this domain, detailing how the ground state properties of materials can be altered within such confined photonic environments. Moreover, we discuss state-of-the-art theoretical proposals for tailoring material properties within cavities. Finally, we outline the key challenges and promising avenues for future research in this exciting field.
Quantum light-matter interactions, described by the theory of quantum electrodynamics (QED), have motivated numerous scientific discoveries and technological developments over the past few decades. Considerable effort has been made to develop different QED platforms, e.g., free space, waveguides, cavities, and photonic crystals, for engineering quantum light-matter interactions. This thesis explores a new frontier, deep microscopic QED, which leverages the deep microscopic response of materials to reveal new topological, quantum, and thermal photonic phenomena with applications to quantum sensing and information processing. In the first part of this thesis, we investigate unique topological photonic effects arising in the deep microscopic QED regime. Previous efforts focused on topological photonic phases and edge states arising from artificial spatial structures of materials (e.g., photonic crystals or metamaterials). One fundamental question is whether topological photonic states can also arise from the intrinsic response of many-body systems and do not rely on materials' macroscopic structures. Here, we first discuss a new topological electromagnetic phase - ‘optical N-phase’ arising in two-dimensional (2D) viscous hydrodynamic electrons in graphene, which originates from the microscopic response of 2D materials and does not rely on materials' macroscopic structures. We then introduce the associated edge states, optical N-plasmons, which are topologically protected ultra-subwavelength edge magneto-plasmons. We further show how these topological plasmons can be harnessed to design chiral radio-frequency nonreciprocal circuit components, topological hydrodynamic circulators, that interface quantum and classical hardware.In the second part of this thesis, we focus on collective atom-photon interactions in the deep microscopic QED regime. In atom interactions with photonic environments, there exist two non-unitary processes -- pure dephasing and spontaneous emission. Despite considerable interest in collective effects in spontaneous emission since the 1950s, one long-standing problem is whether collective effects in pure dephasing can arise in atom-photon interactions. This question is particularly important in the quantum information era since pure dephasing is the main obstacle in current quantum information technologies. Here, we first introduce a new collective quantum phenomenon, ‘nanophotonic superdephasing,’ occurring in atom/spin ensembles in nanoscale photonic environments. This nanophotonic superdephasing phenomenon originates from low-frequency photonic environment correlations, and leads to collectively accelerated disentanglement without photon emission, in stark contrast to conventional collective spontaneous emission/superradiance effects. We further reveal the effects of nanophotonic environment mediated correlated dynamics on quantum computing and sensing. We demonstrate that correlations of nanoscale EM environments in spin qubit quantum computing devices can induce correlated errors and limit quantum gate fidelity. Meanwhile, based on nanophotonic collective dephasing, we also propose a multiqubit quantum sensing protocol that exploits spatially correlated noise near materials to enable order parameter symmetry characterization of materials beyond single-qubit methods.In the final part, we explore thermal photonic phenomena in the deep microscopic regime. Conventional techniques in engineering near-field radiative heat transfer typically rely on phonons, plasmons, and electromagnetic modes in structured materials. Here, we reveal a new approach to enhance near-field thermal radiation: leveraging intrinsic quantum coherence in superconducting materials. We reveal the quantum fingerprint of superconductivity in thermal photonics, ‘superconducting coherence peak’ in near-field thermal radiation, which originates from quantum coherence of Bogoliubov quasiparticles, with potential applications in thermal engineering in superconducting circuits.Overall, the thesis establishes a deep microscopic QED platform for new quantum, topological, and thermal photonic phenomena in many-body systems, with applications in quantum sensors and devices.
Quasiparticle descriptions are a powerful tool in condensed matter physics as they provide an analytical treatment of interacting systems. In this thesis we will apply this tool to theoretically describe two systems: a superconductor interacting with cavity photons and a flowing Bose-Einstein condensate forming a sonic black hole. First we will consider a two-dimensional s-wave BCS superconductor coupled to microwave cavity photons. We show how a nonequilibrium occupation of the photons can induce a nonequilibrium distribution of superconductor Bogoliubov quasiparticles, yielding an enhancement of the superconducting gap. The analytic dependence of this enhancement is provided in terms of the photon spectral and occupation functions, offering a large parameter space over which enhancement exists. Next, we analyze the equilibrium properties of a similar superconductor-cavity structure which has strong sub-dominant d-wave pairing interaction. In this case there is a collective mode known as the Bardasis-Schrieffer mode, which is essentially an uncondensed d-wave Cooper pair. We show that by driving an external supercurrent through the sample the Bardasis-Schrieffer mode can be hybridized with cavity photons, forming exotic Bardasis-Schrieffer-polaritons. We then turn to consider a flowing Bose-Einstein condensate. In the presence of inhomogeneous flow, the long-wavelength motion of quasiparticles can be mapped onto the kinematics of matter fields in a curved spacetime. This mapping allows for the simulation of a black hole and its interactions with quantum fields via analogy. We show that in the case of a step-like jump in the condensate flow the emission of analogue Hawking radiation is accompanied by evanescent modes which are pinned to the event horizon. Finally, we generalize this setup to include pseudo-spin half spinor Bose condensates. In this case, we show that the analogue spacetime the quasiparticles experience can be of the exotic Newton-Cartan type. Newton-Cartan gravity -- the geometric formulation of Newtonian gravity -- is realized when the Goldstone mode disperses quadratically as opposed to linearly. The nature of the analogue spacetime is controlled by the presence or absence of an easy-axis anisotropy in the boson spin-exchange interaction. We conclude by arguing that this Newton-Cartan spacetime can be experimentally realized in current platforms.