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Vremenska nesimetričnost generalisane kvantno-mehaničke Boltzmannove kinetičke jednačine koju je izveo Keldysh

Nikolić-Mojse, Zlatiborka A.

Published Jan 1, 1983• 0 citations
OpenAlex

Abstract

Considering the time-reversed system and using diagram techniques for anticausal Green function it was shown that the origin of time-reversal noninvariance of generalized quantum-mechanical Boltzmann kinetic equation derived by Keldysh stems from the selection of the boundary condition that the perturbed system was in the thermodynamical equilibrium at the moment t = -∞.

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Considering the time-reversed system and using diagram techniques for anticausal Green function it was shown that the origin of time-reversal noninvariance of generalized quantum-mechanical Boltzmann kinetic equation derived by Keldysh stems from the selection of the boundary condition that the perturbed system was in the thermodynamical equilibrium at the moment t = -∞.
Time reversal symmetry is a fundamental property of many quantum mechanical systems. The relation between statistical physics and time reversal is subtle and not all statistical theories conserve this particular symmetry, most notably hydrodynamic equations and kinetic equations such as the Boltzmann equation. In this article, it is shown analytically that quantum kinetic generalizations of the Boltzmann equation that are derived using the nonequilibrium Green functions formalism as well as all approximations that stem from Φ-derivable self-energies are time reversal invariant.
Time‐reversal symmetry is a fundamental property of many quantum mechanical systems. The relation between statistical physics and time reversal is subtle, and not all statistical theories conserve this particular symmetry—most notably, hydrodynamic equations and kinetic equations such as the Boltzmann equation. Here, we consider quantum kinetic generalizations of the Boltzmann equation using the method of reduced density operators, leading to the quantum generalization of the Bogolyubov‐Born‐Green‐Kirkwood‐Yvon (BBGKY) hierarchy. We demonstrate that all commonly used approximations, including Vlasov; Hartree‐Fock; and the non‐Markovian generalizations of the Landau, T‐matrix, and Lenard‐Balescu equations, are originally time‐reversal invariant, and we formulate a general criterion for time reversibility of approximations to the quantum BBGKY hierarchy. Finally, we illustrate, through the example of the Born approximation, how irreversibility is introduced into quantum kinetic theory via the Markov limit, making the connection with the standard Boltzmann equation. This paper is a complement to paper I (Scharnke et al., J. Math. Phys., 2017, 58, 061903), where the time‐reversal invariance of quantum kinetic equations was analysed in the frame of the independent non‐equilibrium Green functions formalism.
In the present article we consider some general class of divergent diagrams in Keldysh diagram technique. These divergences arise for nonequilibrium matter and closely related to the divergences in the kinetic theory of gases. We suggest a scheme of renormalization of such divergences and illustrate it on some examples. In the other papers of these series we develop the general theory of renormalization of nonequilibrium diagram technique. The fact that thermal divergences in non-equilibrium diagram technique can be renormalized leads to the following consequence: to prove that the system tends to the thermal equilibrium one should to take into account the behaviour of the system on its boundary. In this paper we illustrate this fact on Bogoliubov derivation of kinetic equations.
Equations for correlation functions in nonequilibrium systems are derived using a generalization of the diagrammatic Keldysh method. The four field operators of the correlation function are ordered on a time contour that consists of four axes extending from -\ensuremath{\infty} to +\ensuremath{\infty} and from +\ensuremath{\infty} to -\ensuremath{\infty} (doubled Keldysh contour). For those correlation functions that may be considered as correlation functions of one-particle Green-functions' fluctuations, a closed system of equations is obtained in the case of weak interaction of the particles with the scattering system. Its structure may be related to the Langevin approach: on the left-hand side a linear operator acts on each of two pairs of the correlation-function arguments, each of these two operators being just the operator of the linearized quantum kinetic equation. The expression for the right-hand side of this equation is derived. It has the meaning of the correlation function of extraneous Langevin sources, and the equation may be called the quantum Boltzmann-Langevin equation. In the quasi-classical limit it reduces to the usual Boltzmann-Langevin equation for the particles' distribution-function fluctuations. Possible applications of the method are discussed.