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Il Nuovo Cimento B

THE FINE STRUCTURE OF THE N-DIMENSIONAL HYDROGEN ATOM

Sami M. Al-Jaber

Published May 1, 1998• 1 citation
OpenAlex

Abstract

The fine structure of energy levels of a hydrogen atom in N dimensions is given. This is done by calculating the first-order energy corrections due to the relativistic correction to kinetic energy, spin-orbit coupling, and Darwin term. Thus we emphasize the role of the topological structure of the configuration space of a physical system on the quantum nature of an observable of the system.

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We begin our study of atomic physics by relying on the phenomenological notions summarized in chapter 1 and by fully exploiting the quantum mechanical formalism outlined in chapter 2. A hierarchy of approximations will be introduced in the first instance to describe the hydrogen atom, which allows one to focus on the main features of its energy spectrum and quantum properties, including the key ‘atomic orbital’ concept. Next, these results will be extended to the more general case of hydrogenic atoms. The physical picture will be made more rigorous by introducing the magnetic interactions, included those linked to the intrinsic spin degree of freedom, leading to the full description of the fine and hyperfine structure of one-electron atoms. The effects of a static external magnetic or electric field will be eventually discussed by calculating the corresponding energy shifts and splittings of the energy levels.

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The fine structure of energy levels of a hydrogen atom in N dimensions is given. This is done by calculating the first-order energy corrections due to the relativistic correction to kinetic energy, spin-orbit coupling, and Darwin term. Thus we emphasize the role of the topological structure of the configuration space of a physical system on the quantum nature of an observable of the system.
The fine structure of hydrogen energy was calculated by using the usual momentum-wavefunction relation directly, rather than establishing the well-known Dirac wave equation. As the results, the energy levels are completely the same as that of the Dirac wave equation, while the wavefunction is single component that is quite different from Dirac's four component wavefunction, the most important thing is that the present calculation brings out electronic spin in a new way which has never been reported and indicates that the electronic spin is a kind of orbital motion.
Abstract The simple hydrogen atom has had a great influence on the development of quantum theory, particularly in the first half of the twentieth century when the foundations of quantum mechanics were laid. As measurement Fine structure Further reading Exercises techniques improved, finer and finer details were resolved in the spectrum of hydrogen until eventually splittings of the lines were observed that cannot be explained even by the fully relativistic formulation of quantum mechanics, but require the more advanced theory of quantum electrodynamics. In the first chapter we looked at the BohrSommerfeld theory of hydrogen that treated the electron orbits classically and imposed quantisation rules upon them.
Purpose of the study: The goal of this work is to present a comparative study between the semi-relativistic theory of Sakho and the relativistic theory of Dirac applied to calculations of the eigenvalue of the Hamiltonian fine structure of the hydrogen like systems. The three small perturbative corrections (relativistic mass correction, spin-orbit coupling, and the Darwin term) of the Hamiltonian are considered. Methodology: This research is based on correction of the semi-classical Bohr’s theory on the hydrogen like systems considering the relativistic mass correction by ignoring the electron’s spin. This approach referred to as semi-relativistic theory allows one to express the eigenvalues of the Hamiltonian fine structure to be compared to that from the relativistic wave function of Dirac Main Findings: The research gives the first expression of the quantized energy of hydrogen like systems taking only into account, the relativistic mass correction. This result provides exactly the eigenvalues of the Hamiltonian fine structure predicted from Dirac’s relativistic theory for all the non-degenerated quantum states n2Lj (j = l ± s) of the hydrogen like systems (i.e. 1 2s1/2, 2 2p3/2, 3 2d5/2, 42f7/2, and so on). Novelty/Originality of this study: Theoretical determination of the eigenvalue of the Hamiltonian fine structure predicted from Dirac’s relativistic theory for all the non-degenerated quantum states is obtained with a soft semi-relativistic theory without including in the calculations the spin-orbit coupling and the Darwin term corrections.
We begin our study of atomic physics by relying on the phenomenological notions summarized in chapter 1 and by fully exploiting the quantum mechanical formalism outlined in chapter 2. A hierarchy of approximations will be introduced in the first instance to describe the hydrogen atom, which allows one to focus on the main features of its energy spectrum and quantum properties, including the key ‘atomic orbital’ concept. Next, these results will be extended to the more general case of hydrogenic atoms. The physical picture will be made more rigorous by introducing the magnetic interactions, included those linked to the intrinsic spin degree of freedom, leading to the full description of the fine and hyperfine structure of one-electron atoms. The effects of a static external magnetic or electric field will be eventually discussed by calculating the corresponding energy shifts and splittings of the energy levels.