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日本物理学会年会講演予稿集

2a-D-3 Bose気体の2体分布函数II

啓明 原, 浩 市村

Published Apr 2, 1967• 0 citations
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By using far-infrared laser spectroscopy we have studied the temperature dependence of the absorption that is due to transitions between the E ((2)E) and 2A ((2)E) levels of excited Cr(3+) ions in ruby. From the temperature dependence of the linewidth we determined the inhomogeneous and the homogeneous contributions to line broadening. From the homogeneous width the lifetime of the 2A level was obtained. We found that, for emperatures up to 70 K, the lifetime is due mainly to one-phonon relaxation, whereas at higher temperatures another relaxation process, probably a two-phonon Raman process, becomes strong.
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The technique of accumulated photon echo is used in combination with a high-pressure diamond anvil cell to measure the splitting of the 4^{4}4A2{\mathit{A}}_{2}A2​ ground state and the one-phonon spontaneous decay rate of the 2A\ifmmode\bar\else\textasciimacron\fi{}(2{(}^{2}(2E) level at 1.5 K in ruby up to 4.3 GPa of hydrostatic pressure. The 4^{4}4A2{\mathit{A}}_{2}A2​ ground-state splitting is found to be 0.383\ifmmode\pm\else\textpm\fi{}0.001 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ at ambient pressure, and increases with a slope of +(6\ifmmode\pm\else\textpm\fi{}1)\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}3}$ ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$/GPa. The spontaneous decay rate of 2A\ifmmode\bar\else\textasciimacron\fi{}(2{(}^{2}(2E) increases only weakly with pressure. The pressure dependences of both quantities are accounted for in terms of the trigonal-field and spin-orbit-coupling parameters.