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Advanced Statistical Mechanics

Barry M. McCoy

Published Dec 1, 2009• 99 citations
Publisher

Abstract

Abstract This book begins where elementary books and courses leave off and covers the advances made in statistical mechanics in the past fifty years. The book is divided into three parts. The first part is on general theory which includes a summary of the basic principles of statistical mechanics; a presentation of the physical phenomena covered and the models used to discuss them; theorems on the existence and uniqueness of partition functions; theorems on order; and critical phenomena and scaling theory. The second part is on series and numerical methods which includes derivations of the Mayer and Ree–Hoover expansions of the low density virial equation of state; Groeneveld's theorems; the application to hard spheres and discs; a summary of numerical studies of systems at high density; and the use of high temperature series expansions to estimate critical exponents for magnets. The third part covers exactly solvable models which includes a detailed presentation of the Pfaffian methods of computing the Ising partition function, magnetization, correlation functions, and susceptibility; the star-triangle (Yang–Baxter equation); functional equations and the free energy for the eight-vertex model; and the hard hexagon and chiral Potts models. All needed mathematics is developed in detail and many open questions are discussed. The goal is to guide the reader to the current forefront of research.

DOI
10.1093/acprof:oso/9780199556632.001.0001

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Abstract This book begins where elementary books and courses leave off and covers the advances made in statistical mechanics in the past fifty years. The book is divided into three parts. The first part is on general theory which includes a summary of the basic principles of statistical mechanics; a presentation of the physical phenomena covered and the models used to discuss them; theorems on the existence and uniqueness of partition functions; theorems on order; and critical phenomena and scaling theory. The second part is on series and numerical methods which includes derivations of the Mayer and Ree–Hoover expansions of the low density virial equation of state; Groeneveld's theorems; the application to hard spheres and discs; a summary of numerical studies of systems at high density; and the use of high temperature series expansions to estimate critical exponents for magnets. The third part covers exactly solvable models which includes a detailed presentation of the Pfaffian methods of computing the Ising partition function, magnetization, correlation functions, and susceptibility; the star-triangle (Yang–Baxter equation); functional equations and the free energy for the eight-vertex model; and the hard hexagon and chiral Potts models. All needed mathematics is developed in detail and many open questions are discussed. The goal is to guide the reader to the current forefront of research.
Abstract Phase transitions and critical phenomena have consistently been among the principal subjects of active studies in statistical physics. The simple act of transforming one state of matter or phase into another, for instance by changing the temperature, has always captivated the curious mind. This book provides an introductory account on the theory of phase transitions and critical phenomena, a subject now recognized to be indispensable for students and researchers from many fields of physics and related disciplines. The first five chapters are very basic and quintessential, and cover standard topics such as mean-field theories, the renormalization group and scaling, universality, and statistical field theory methods. The remaining chapters develop more advanced concepts, including conformal field theory, the Kosterlitz-Thouless transition, the effects of randomness, percolation, exactly solvable models, series expansions, duality transformations, and numerical techniques. Moreover, a comprehensive series of appendices expand and clarify several issues not developed in the main text. The important role played by symmetry and topology in understanding the competition between phases and the resulting emergent collective behaviour, giving rise to rigidity and soft elementary excitations, is stressed throughout the book. Serious attempts have been directed toward a self-contained modular approach so that the reader does not have to refer to other sources for supplementary information. Accordingly, most of the concepts and calculations are described in detail, sometimes with additional/auxiliary descriptions given in appendices and exercises. The latter are presented as the topics develop with solutions found at the end of the book, thus giving the text a self-learning character.
Phase transitions and critical phenomena have consistently been among the principal subjects of active studies in statistical physics. The simple act of transforming one state of matter or phase into another, for instance by changing the temperature, has always captivated the curious mind. This book provides an introductory account on the theory of phase transitions and critical phenomena, a subject now recognized to be indispensable for students and researchers from many fields of physics and related disciplines. The first five chapters are very basic and quintessential, and cover standard topics such as mean-field theories, the renormalization group and scaling, universality, and statistical field theory methods. The remaining chapters develop more advanced concepts, including conformal field theory, the Kosterlitz-Thouless transition, the effects of randomness, percolation, exactly solvable models, series expansions, duality transformations, and numerical techniques. Moreover, a comprehensive series of appendices expand and clarify several issues not developed in the main text. The important role played by symmetry and topology in understanding the competition between phases and the resulting emergent collective behaviour, giving rise to rigidity and soft elementary excitations, is stressed throughout the book. Serious attempts have been directed toward a self-contained modular approach so that the reader does not have to refer to other sources for supplementary information. Accordingly, most of the concepts and calculations are described in detail, sometimes with additional/auxiliary descriptions given in appendices and exercises. The latter are presented as the topics develop with solutions found at the end of the book, thus giving the text a self-learning character.
Abstract This book provides a thorough introduction to the fascinating world of phase transitions as well as many related topics, including random walks, combinatorial problems, quantum field theory and S-matrix. Fundamental concepts of phase transitions, such as order parameters, spontaneous symmetry breaking, scaling transformations, conformal symmetry, and anomalous dimensions, have deeply changed the modern vision of many areas of physics, leading to remarkable developments in statistical mechanics, elementary particle theory, condensed matter physics and string theory. This self-contained book provides an excellent introduction to frontier topics of exactly solved models in statistical mechanics and quantum field theory, renormalization group, conformal models, quantum integrable systems, duality, elastic S-matrix, thermodynamics Bethe ansatz and form factor theory. The clear discussion of physical principles is accompanied by a detailed analysis of several branches of mathematics, distinguished for their elegance and beauty, such as infinite dimensional algebras, conformal mappings, integral equations or modular functions. Besides advanced research themes, the book also covers many basic topics in statistical mechanics, quantum field theory and theoretical physics. Each argument is discussed in great detail, paying attention to an overall coherent understanding of physical phenomena. Mathematical background is provided in supplements at the end of each chapter, when appropriate. The chapters are also followed by problems of different levels of difficulty. Advanced undergraduate and graduate students will find a rich and challenging source for improving their skills and for accomplishing a comprehensive learning of the many facets of the subject.
From the exact solution of the Ising model by Onsager in 1944 up to that of the hard hexagon model by Baxter in 1980, the statistical mechanics of two-dimensional systems has been enriched by a number of exact results. One speaks (in quick manner) of exact models once a convenient mathematical expression has been obtained for a physical quantity such as the free energy, an order parameter or some correlation, or at the very least once their evaluation is reduced to a problem of classical analysis. Such solutions, often considered as singular curiosities upon their appearance, often have the interest of illustrating the principles and general theorems rigorously established in the framework of definitive theories, and also enabling the control of approximate or perturbative methods applicable to more realistic and complex models. In the theory of phase transitions, the Ising model and the results of Onsager and Yang have eminently played such a reference role. With the various vertex models, the methods of Lieb and Baxter have extended this role and the collection of critical exponents, providing new useful elements of comparison with extrapolation methods, and forcing a refinement of the notion of universality. Intimately linked to two-dimensional classical models (but of less interest for critical phenomena), one-dimensional quantum models such as the linear magnetic chain and Bethe's famous solution have certainly contributed to the understanding of fundamental excitations in many-body systems. One could also mention the physics of one-dimensional conductors.
The stated goal of this book is to fill a perceived gap between undergraduate texts on critical phenomena and advanced texts on quantum field theory, in the general area of renormalization methods. It is debatable whether this gap really exists nowadays, as a number of books have appeared in which it is made clear that field-theoretic renormalization group methods are not the preserve of particle theory, and indeed are far more easily appreciated in the contexts of statistical and condensed matter physics. Nevertheless, this volume does have a fresh aspect to it, perhaps because of the author's background in fluid dynamics and turbulence theory, rather than through the more traditional migration from particle physics. The book begins at a very elementary level, in an effort to motivate the use of renormalization methods. This is a worthy effort, but it is likely that most of this section will be thought too elementary by readers wanting to get their teeth into the subject, while those for whom this section is apparently written are likely to find the later chapters rather challenging. The author's particular approach then leads him to emphasise the role of renormalized perturbation theory (rather than the renormalization group) in a number of problems, including non-linear systems and turbulence. Some of these ideas will be novel and perhaps even surprising to traditionally trained field theorists. Most of the rest of the book is on far more familiar territory: the momentum-space renormalization group, epsilon-expansion, and so on. This is standard stuff, and, like many other textbooks, it takes a considerable chunk of the book to explain all the formalism. As a result, there is only space to discuss the standard ϕ 4 field theory as applied to the Ising model (even the N -vector model is not covered) so that no impression is conveyed of the power and extent of all the applications and generalizations of the techniques. It is regrettable that so much space is spent on rather oversimplified and unrelated models in the first part of the book that, in the end, the reader is left breathless on the threshold of the really interesting material. Despite the earlier emphasis on the application of renormalization ideas in dynamics, in the end the full power of the field-theoretical approach is not applied to the obvious arena of dynamic critical phenomena (where there certainly is currently a gap in the literature) but to the Navier--Stokes equations. The development of the book is somewhat illogical in places. Mean field theory interrupts discussion of block spin methods and scaling arguments---the two are distinct approaches. The Callan--Symanzik equation is introduced before Feynman diagrams are explained, so that there is a hiatus before the actual results for the critical exponents can be found. I think this book is too broad in some respects, and too limited in others, to be a really useful textbook for a course on renormalization methods. Those who have learned these ideas either from field theory, or from nonlinear systems, will find it more rewarding for the sections covering the topics with which they are less familiar. For this reason alone, the book should at least find a place on most library reference shelves.
The main aim of this book is to give a self-contained and representative cross section through present-day research in solid-state physics. This covers metallic and mesoscopic transport, localization by disorder and superconductivity, including questions related to high-temperature superconductors and to heavy fermion systems. An important part of the book is devoted to itinerant-electron magnetism, discussing paramagnons, strong correlation, magnetization fluctuations and spin density waves. All the formal tools used in these chapters are developed in the first part of the book which contains a thorough discussion of second quantization, and of perturbation theory for an arbitrary complex time path, and also describes the functional approach to Feynman diagrams, including general ward identities. Each chapter contains an extensive list of the relevant literature and a series of problems with detailed solutions which complement the main text. The book is meant as both a course and a research tool.