Chemistry of light

Ed Gerstner

Leonardo F. Calderón, Humberto Triviño, Leonardo A. Pachón

Polaritonic chemistry has ushered in new avenues for controlling molecular dynamics. However, two key questions remain: (i) Can classical light sources elicit the same effects as certain quantum light sources on molecular systems? (ii) Can semiclassical treatments of light-matter interaction capture nontrivial quantum effects observed in molecular dynamics? This work presents a quantum-classical approach addressing issues of realizing cavity chemistry effects without actual cavities. It also highlights the limitations of the standard semiclassical light-matter interaction. It is demonstrated that classical light sources can mimic quantum effects up to the second order of light-matter interaction, provided that the mean-field contribution, symmetrized two-time correlation function, and the linear response function are the same in both situations. Numerical simulations show that the quantum-classical method aligns more closely with exact quantum molecular-only dynamics for quantum light states such as Fock states, superpositions of Fock states, and vacuum squeezed states than the conventional semiclassical approach.

Jennifer I. L. Chen, Georg von Freymann, Sung Yeun Choi +2 more

A driving force in the rapidly developing field of photonic crystals has been the photonic bandgap, a range of energies where the propagation of light is completely forbidden. The photonic bandgap allows the design of photonic lattices that localize, guide and bend light at sub-micron length scales, providing opportunities for the creation of miniature optical devices and integrated optical circuits to help drive the revolution in photonics. A less well known attribute of photonic crystals is their theoretical ability to slow light to a velocity of zero. This phenomenon can be achieved at the high and low energy edges of photonic stopgaps where the photonic bands are flat and light exists as a standing wave commensurate with the photonic lattice and travels at a group velocity of zero, referred to as “slow photons” herein. It has been shown theoretically that the probability of harvesting slow photons scales inversely with their group velocity. This means that a number of well known photon driven processes and devices in chemistry and physics can be enhanced by capturing this unique property of slow photons. In this paper we will look at slow photons mainly through the eye of chemistry and highlight some recent developments in this exciting and emerging field that demonstrate the potential of slow photons in materials chemistry and nanochemistry.

Steven S. Andrews

H. M. MacDonald