Coupled-cluster (CC) theory and Green's function many-body perturbation theory (MBPT) have long evolved as distinct yet complementary frameworks for describing electronic correlation. While CC methods employ exponential wavefunction parametrizations that guarantee size extensivity and systematic improvability, Green's function approaches such as the
GW approximation describe quasiparticle and optical excitations through diagrammatic resummations. Recent analyses have established a formal correspondence between these frameworks: the
GW approximation is equivalent to an equation-of-motion (EOM) treatment of the direct-ring coupled-cluster doubles (drCCD) method. Within this context, the extended CC (ECC) ansatz offers a unified framework connecting CC and MBPT. This formulation bridges CC-based and Green's function-based methods, providing novel avenues for incorporating vertex corrections within a CC framework that preserves a sum-over-state representation of the self-energy and lead to potentially systematically improvable Green's function approaches.
Coupled-cluster (CC) theory and Green’s function many-body perturbation theory (MBPT) have long evolved as distinct yet complementary frameworks for describing electronic correlation. While CC methods employ exponential wave function parametrizations that guarantee size extensivity and systematic improvability, Green’s function approaches, such as the GW approximation, describe quasiparticle and optical excitations through diagrammatic resummations. Recent analyses have established a formal correspondence between these frameworks: the GW approximation is equivalent to an equation-of-motion (EOM) treatment of the direct-ring coupled-cluster doubles (drCCD) method. Within this context, the extended CC (ECC) ansatz offers a unified framework connecting CC and MBPT. This formulation bridges CC-based and Green’s function-based methods, providing novel avenues for incorporating vertex corrections within a CC framework that preserves a sum-over-state representation of the self-energy and leads to potentially systematically improvable Green’s function approaches.
(by translator) A perturbation theory is developed for normal many-particle systems by expanding the inverse of the advanced and retarded Green functions. Both systems with direct interactions and systems with interactions through a quantum field are considered. For the former, the infinite set of coupled equations is written down and the various methods of decoupling discussed. Systems with weak, hard sphere type, or coulomb interactions are considered and the connections with other methods discussed. For systems with quantum field interactions, the chain of equations involves both fermion and boson Green functions and the first approximation can be much better than in earlier cases. This latter approach seems to be more convenient when collective oscillations are important.