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Photo-Equilibrium of Barium

G. T. Best, Victor L. Corbin, Air Force Cambridge Research Laboratories (U.S.)

Published Nov 30, 1971• 1 citation
OpenAlex

Abstract

A model for numerical simulation of the solar pumping of a simple atomic system is constructed and compared with the exact analytical solution. The process is then extended to cover the more complex 5-level 5-transition barium ion term scheme and the 61-level 86-transition barium neutral term scheme. An advantage of the step-wise simulation is that in addition to yielding the equilibrium relative level populations and transition intensities, it also permits the dynamic grow-in to equilibrium to be studied. The neutral barium system has also been studied with the inclusion of photoionization from each of several metastable levels.

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Physical Review A•Apr 1, 1993•11 citations
A model for numerical simulation of the solar pumping of a simple atomic system is constructed and compared with the exact analytical solution. The process is then extended to cover the more complex 5-level 5-transition barium ion term scheme and the 61-level 86-transition barium neutral term scheme. An advantage of the step-wise simulation is that in addition to yielding the equilibrium relative level populations and transition intensities, it also permits the dynamic grow-in to equilibrium to be studied. The neutral barium system has also been studied with the inclusion of photoionization from each of several metastable levels.
Abstract The kinetics of two-step photoionization of barium atoms through excited P 1 1 , 3 levels was studied by numerical simulation method in the optically dense approximation. The first laser at wavelength λ 1 = 553.5 nm ( λ 1 = 791 nm) pumps transition S 0 1 ↔ P 1 1 ( S 0 1 ↔ P 1 3 ). The second laser with λ 2 = 266 nm ( λ 2 = 310 nm) ionizes atoms from the level P 1 1 ( P 1 3 ). The third probe laser with wavelength λ i = 493.41 nm causes resonant fluorescence of barium ions. It is shown that the metastable D 2 3 from the D 1 , 2 , 3 3 triplet in barium is strongly populated through P 1 <
A numerical model has been developed, which is well suited to describe the kinetics of a laser-pumped barium vapour. The numerous processes essential for the temporal evolution in the population of the various barium levels are outlined in detail. A number of approximations and simplifications have to be introduced to adapt the complex problem to a numerical solution at an economical expense. Since the authors consider all substantial features of the laser-pumped barium vapour like the population development of low-lying levels, the ionisation of the vapour, stimulated infrared emission and radiative transfer, the requirement for a quantitative interpretation of experimental data is fulfilled.
Simple and effective techniques for loading barium ions into linear Paul traps are demonstrated. Two-step photoionization of neutral barium is achieved using a weak intercombination line ($6{s}^{2}\phantom{\rule{0.2em}{0ex}}^{1}S_{0}\ensuremath{\leftrightarrow}6s6p\phantom{\rule{0.2em}{0ex}}^{3}P_{1}$, $\ensuremath{\lambda}=791\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$) followed by excitation above the ionization threshold using a nitrogen gas laser $(\ensuremath{\lambda}=337\phantom{\rule{0.3em}{0ex}}\mathrm{nm})$. Isotopic selectivity is achieved by using a near Doppler-free geometry for excitation of the triplet 6s6p3P16s6p\phantom{\rule{0.2em}{0ex}}^{3}P_{1}6s6p3P1​ state. Additionally, we report a particularly simple and efficient trap loading technique that employs an inexpensive uv epoxy curing lamp to generate photoelectrons.
The kinetics of ionization and recombination of an ultracold barium plasma created in a two-step process, taking into account the transfer of resonant radiation in 3D cylindrical geometry, is studied by numerical simulation. At the first step, a pump laser excites the upper level of the resonant transition 6s2 S10↔6s6p P11 (λ1=553.5 nm). At the second step, the laser with quantum energy exceeding the ionization potential from the level 6s6p P11 (λ2=417.79 nm) ionizes the atoms. A scheme is proposed for increasing the efficiency of electron yield: at the second ionization step, the laser radiation with frequency corresponding to the continuum from the metastable D32 is used. The electron temperature from the initial value 0.1 K during the action of the pump and ionizing lasers increases by more than 200 times due to superelastic processes. As a result, the time of three-body recombination of plasma increases significantly. The results of numerical simulation indirectly confirm the fact of Killian et al. [Phys. Rev. Lett. 83(23), 4776 (1999)] that the deceleration of recombination of ultracold xenon plasma can be explained by the heating of electrons in superelastic quenching collisions.
A simple theory describing selective excitation of a three-level atom with a tuneable laser is developed. Effects of number density, line widths and laser parameters on the final populations of the levels with laser excitation are discussed. An experiment is described in which a tuneable dye laser is used to pump large numbers of barium atoms into the 6s5d 3 D metastable term from the (bs) 2 1 S 0 ground state via the 6s6p 3 P term. The theory for the interaction of the laser with this 'three-level system' predicts that approximately 80% of the barium atoms should be excited into the 3 D term. Experimentally the largest amount of excitation to the 3 D term observed was (78+or-5)%.
We demonstrate an experimental technique that selects the nuclear spin I=0 isotope 138Ba^{138}\mathrm{Ba}138Ba for spectroscopic measurements from a beam of natural barium containing seven stable isotopes. A cw dye laser is used to optically pump the I=3/2 isotopes 135Ba^{135}\mathrm{Ba}135Ba and 137Ba^{137}\mathrm{Ba}137Ba into the metastable 6s5d 1^{1}1D2{\mathit{D}}_{2}D2​ and 3^{3}3D1,2{\mathit{D}}_{1,2}D1,2​ levels via the 6s6p 1^{1}1P1{\mathit{P}}_{1}P1​ excited state, leaving nearly pure 138Ba^{138}\mathrm{Ba}138Ba in the ground state. Photoionization spectra of the excited 5d6p 3^{3}3D1{\mathit{D}}_{1}D1​ even isotope state recorded with optical pumping of 135Ba^{135}\mathrm{Ba}135Ba and 137Ba^{137}\mathrm{Ba}137Ba to the metastable levels are essentially devoid of forbidden features associated with the hyperfine interaction in the odd isotopes.