George Birtwistle
Wave mechanics In the classical dynamics the state of the system whose coordinates are q 1 … q s and momenta p 1 … p s is denoted by a point in 2s-dimensional space (the q-space); changes in the system are indicated by the passage of the point along some curve in this space, a ‘ray,’ it may be called. Schrödinger's new concept is that changes in the system should be represented in the q-space not by ‘rays’ but by ‘waves.’ He regards the classical mechanics as only an approximation to actual mechanical events, which he says can only be described by wave mechanics; the former in his view bears to the latter just the same relation as geometrical (or ‘ray’) optics does to physical (or ‘wave’) optics. A large scale (macroscopic) mechanical process corresponds to a wave signal in the g-space, which can be regarded as a point in comparison with the geometrical structure of its path. But for small scale (microscopic) processes, such as atomic phenomena are, the rigorous wave theory must be used. The wave equation must replace the usual dynamical equations. The latter are just as unfruitful for the purposes of atom mechanics as geometrical optics alone would be to clear up the fine points of diffraction phenomena.
Cambridge University Press eBooks•Jul 20, 2009•0 citations