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Mathematics

Detecting and Preserving Quantum Steering in Hydrogen Atoms: Entropic Inequalities and Lindblad Dynamics

K. Berrada, Smail B. Bougouffa

Published Dec 11, 2025• 1 citation
Publisher

Abstract

In the present work, we investigate the detection and control of quantum correlations in the hyperfine structure of hydrogen atoms under dissipative dynamics. The hydrogen atom serves as a fundamental platform for studying bipartite quantum correlations between the electron and proton spins, where entanglement is quantified by concurrence and EPR steering is witnessed through violation of the entropic steering inequality. By modeling the open-system evolution via the Lindblad master equation, we analyze the time-dependent behavior of concurrence, steering, and fidelity under varying dissipation rates. Numerical illustrations highlight the resilience of entanglement relative to steering in noisy environments, providing insights into the control of non-classical phenomena.

DOI
10.3390/math13243953

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In the present work, we investigate the detection and control of quantum correlations in the hyperfine structure of hydrogen atoms under dissipative dynamics. The hydrogen atom serves as a fundamental platform for studying bipartite quantum correlations between the electron and proton spins, where entanglement is quantified by concurrence and EPR steering is witnessed through violation of the entropic steering inequality. By modeling the open-system evolution via the Lindblad master equation, we analyze the time-dependent behavior of concurrence, steering, and fidelity under varying dissipation rates. Numerical illustrations highlight the resilience of entanglement relative to steering in noisy environments, providing insights into the control of non-classical phenomena.
We investigate the quantum dynamics of entanglement and fidelity in the hyperfine structure of hydrogen atoms under dephasing noise, modeled via the Lindblad master equation. The effective Hamiltonian captures the spin–spin interaction between the electron and proton, with dephasing incorporated through local Lindblad operators. Analytical solutions for the time-dependent density matrix are derived for various initial states, including separable, partially entangled, and maximally entangled configurations. Entanglement is quantified using the concurrence, while fidelity measures the similarity between the evolving state and the initial state. Numerical results demonstrate that entanglement exhibits oscillatory decay modulated by the dephasing rate, with anti-parallel spin states displaying greater robustness compared to parallel configurations, often leading to entanglement sudden death. Fidelity dynamics reveal similar damped oscillations, underscoring the interplay between coherent hyperfine evolution and environmental dephasing. These insights elucidate strategies for preserving quantum correlations in atomic systems, with implications for quantum information processing and metrology.
In this work, we investigate the quantum coherence and purity in hydrogen atoms under dissipative dynamics, with a focus on the hyperfine structure states arising from the electron-proton spin interaction. Using the Lindblad master equation, we model the time evolution of the density matrix of the system, incorporating both the unitary dynamics driven by the hyperfine Hamiltonian and the dissipative effects due to environmental interactions. Quantum coherence is quantified using the L1 norm and relative entropy measures, while purity is assessed via von Neumann entropy, for initial states, including a maximally entangled Bell state and a separable state. Our results reveal distinct dynamics: for the Bell states, both coherence and purity decay exponentially with a rate proportional to the dissipation parameter, whereas for a kind of separable state, coherence exhibits oscillatory behavior modulated via the hyperfine coupling constant, superimposed on an exponential decay, and accompanied by a steady increase in entropy. Higher dissipation rates accelerate the loss of coherence and the growth of von Neumann entropy, underscoring the environment's role in suppressing quantum superposition and driving the system towards mixed states. These findings enhance our understanding of coherence and purity preservation in atomic systems and offer insights for quantum information applications where robustness against dissipation is critical.
In this paper, we investigate the dynamics of quantum correlations in the ground-state hyperfine manifold of the hydrogen atom subjected to a static external magnetic field and local pure dephasing. The electron–proton spin pair is modeled as a bipartite two-qubit system evolving under the combined effects of hyperfine coupling, Zeeman splitting, and a Lindblad master equation that describes Markovian dissipative processes. Employing exact analytical solutions for the time-dependent density matrix elements (derived in the Markovian open-system framework), we quantify entanglement persistence via concurrence and state stability via Uhlmann fidelity with respect to the initial preparation. For an initial Werner state, numerical results reveal that the external magnetic field substantially modifies the system dynamics: Both concurrence and fidelity exhibit pronounced dependence on the Zeeman parameter, producing field-controlled oscillations, delayed entanglement sudden death, and altered decoherence rates. This behavior originates from Zeeman-induced lifting of hyperfine degeneracies, symmetry breaking of the isotropic Werner state, and redistribution of populations and coherences. Unlike previous studies that treat hyperfine interactions, Zeeman splitting, or decoherence in isolation, the present work provides a unified analytical treatment that simultaneously incorporates all three mechanisms. The findings underscore the competition between coherent hyperfine coupling and environmental noise and open new pathways for precision spectroscopy and robust quantum information protocols based on atomic spin degrees of freedom.
In this work, we investigate quantum correlations, including entanglement and quantum discord, within the hyperfine structure of the hydrogen atom using the Lindblad master equation to model its dynamics as an open quantum system interacting with an environment. By incorporating realistic environmental influences, we examine the time evolution of two key measures of quantum correlations: concurrence, which quantifies entanglement, and local quantum uncertainty (LQU), a broader indicator of quantumness. Our analysis spans various initial states, including coherent superpositions of hyperfine states, to capture a wide range of possible configurations and demonstrate how these measures capture distinct aspects of quantum behavior. The results reveal the robustness of LQU in regimes where entanglement may vanish. This resilience of LQU underscores its utility as a robust measure of quantum correlations beyond entanglement alone in the hydrogen atom. By elucidating the dynamics of quantum correlations in the hydrogen atom under realistic conditions, this work not only deepens our fundamental understanding of atomic systems but also highlights their potential relevance to quantum information science and the development of quantum technologies.
We investigate the time evolution of bipartite quantum correlations in the ground-state hyperfine manifold of the hydrogen atom subjected to an external magnetic field and independent Markovian dephasing. Treating the electron–proton spin pair as an effective two-qubit system, we derive the exact solution of the Lindblad master equation for an X-shaped initial state and quantify the dynamics using three complementary measures: entanglement of formation (through concurrence), quantum steering (through the CJWR inequality) and Bell nonlocality (through normalized CHSH violation). The dynamics are obtained within a unified open-system framework that combines hyperfine interaction, Zeeman splitting, and Markovian dissipation in a single analytically solvable Lindblad model, allowing a complete operator-level characterization of the correlation decay. This exact treatment provides a transparent link between the underlying spectral structure of the Hamiltonian and the observed hierarchy in the robustness of quantum correlations. Our results reveal that all three quantities exhibit damped oscillations whose frequency and decay rate are strongly tuned by the proton magnetic parameter through the Zeeman splitting. While entanglement decays relatively quickly, steering persists noticeably longer and Bell nonlocality proves to be the most fragile, confirming the expected hierarchy of quantum correlations under local dephasing. The external magnetic field emerges as a practical control knob that can extend the lifetime of these resources even in the presence of noise. These findings provide a clear physical picture of how hyperfine coupling, Zeeman effects, and environmental fluctuations jointly govern quantum coherence in atomic spin systems, with direct implications for spin-based quantum technologies and fundamental tests of nonlocality in realistic laboratory settings.
This work presents a comprehensive study of quantum correlations and their degradation under environmental dephasing within the atomic hydrogen system. By analyzing the magnetic coupling between the electron and proton spins in the 1s hyperfine state, we elucidate how coherent spin interactions generate entangled states and govern their temporal evolution. The investigation focuses on three key measures of quantum correlations—Bell nonlocality, Einstein–Podolsky–Rosen (EPR) steering, and quantum purity—each reflecting a different level within the hierarchy of nonclassical correlations. Analytical formulations and numerical simulations reveal that, in the absence of decay, all quantities remain steady, indicating the preservation of coherence. When dephasing is introduced, each measure decays exponentially toward a stationary lower bound, with Bell nonlocality identified as the most fragile, followed by steering and purity. A three-dimensional analysis of Werner states under dephasing further establishes the critical purity thresholds required for Bell inequality violations. The results highlight the interdependence between magnetic coupling, decoherence, and initial entanglement, providing a unified framework for understanding correlation dynamics in open quantum systems. These findings have direct implications for the development of noise-resilient quantum information protocols and spin-based quantum technologies, where preserving nonlocal correlations is essential for reliable quantum operations.