Having introduced the birth of quantum physics at the end of the last chapter, we now formally explain some aspects of quantum mechanics. Instead of the usual material one can find in standard textbooks, we will start by motivating the standard “trick” of Wick rotation via the heat equation, and the Black–Scholes equation in finance, which gives us the Schrödinger equation. We then explore how Wick rotation in a path integral works, and how temperature of a field theory is essentially cyclic imaginary time. Later on we will discuss quantum entanglement and the Bell inequality, as well as how the cosmos provides an arena to close a certain loophole in the Bell test. We also discuss how quantum mechanics can explain various phenomena in astrophysics and cosmology, such as: how the Sun shines; how white dwarfs and neutron stars are supported by degenerative pressure; how neutrino oscillation works and what is a Majorana particle; and what is “quantum cosmology”.
Having introduced the birth of quantum physics at the end of the last chapter, we now formally explain some aspects of quantum mechanics. Instead of the usual material one can find in standard textbooks, we will start by motivating the standard “trick” of Wick rotation via the heat equation, and the Black–Scholes equation in finance, which gives us the Schrödinger equation. We then explore how Wick rotation in a path integral works, and how temperature of a field theory is essentially cyclic imaginary time. Later on we will discuss quantum entanglement and the Bell inequality, as well as how the cosmos provides an arena to close a certain loophole in the Bell test. We also discuss how quantum mechanics can explain various phenomena in astrophysics and cosmology, such as: how the Sun shines; how white dwarfs and neutron stars are supported by degenerative pressure; how neutrino oscillation works and what is a Majorana particle; and what is “quantum cosmology”.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
Introduction to the Maths and Physics of Quantum Mechanics details the mathematics and physics that are needed to learn the principles of quantum mechanics. It provides an accessible treatment of how to use quantum mechanics and why it is so successful in explaining natural phenomena. This book clarifies various aspects of quantum physics such as ‘why quantum mechanics equations contain “I”, the imaginary number?’, ‘Is it possible to make a transition from classical mechanics to quantum physics without using postulates?’ and ‘What is the origin of the uncertainty principle?’. A significant proportion of discussion is dedicated to the issue of why the wave function must be complex to properly describe our “real” world. The book also addresses the different formulations of quantum mechanics. A relatively simple introductory treatment is given for the “standard” Heisenberg matrix formulation and Schrodinger wave-function formulation and Feynman path integrals and second quantization are then discussed. This book will appeal to first- and second-year university students in physics, mathematics, engineering and other sciences studying quantum mechanics who will find material and clarifications not easily found in other textbooks. It will also appeal to self-taught readers with a genuine interest in modern physics who are willing to examine the mathematics and physics in a simple but rigorous way. Key Features: Written in an engaging and approachable manner, with fully explained mathematics and physics concepts Suitable as a companion to all introductory quantum mechanics textbooks Accessible to a general audience
This chapter considers the birth of quantum theory, which marks another important event in the modernization of physics and chemistry as it facilitates explaining phenomena at an atomic scale. In a first step, the chapter provides an overview of several phenomena that have long been a source of controversies among scientists, namely the nature of light, the nature of matter, and the fact that the colour of solids heated in a furnace is determined by temperature rather than the make-up of the material. None of these could be adequately explained by classical mechanics. The chapter then discusses Planck’s quantum hypothesis, which provided a major breakthrough in this regard. Finally, it traces the formalization of quantum mechanics, which was required to enable its application to a wider range of problems.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.
Some aspects of the interpretation of microscopic physics in terms of quantum theory are discussed. It is first emphasized that quantum theory is formulated in a Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutation relations between ''canonically conjugated'' coordinate and momentum operators leads to a wrong version of quantum mechanics. In this connection the Feynman integral formalism is also discussed. In this formalism the measure is not well defined, and there is no idea how to distinguish between the true version of quantum mechanics and an incorrect one. In this respect, the Feynman approach consists of a mnemonic rule to generate perturbation series from an undefined zero-order term. The origin of time in the quantum framework is then analyzed in detail and illustrated by the example of atomic collisions. It is shown that the time-dependent Schr ¨ odinger equation for the closed three-body (two nuclei + electron) system has no physical meaning because in the high-impact energy limit it transforms into an equation with two independent time-like variables; time naturally appears in the stationary Schr ¨ odinger equation as a result of extraction of a classical subsystem (two nuclei) from a closed three-body system. Finally, following the well-known Einstein-Rosen-Podolsky experiment and Bell's inequality, we reiterate that the wave function must be interpreted as an actual field of information, in a form as elementary as the usual material particles and electromagnetic fields. In fact, experimental measurements transfer this quantum information field into the classical world, which is directly discernable. In my conclusion, the relation between physical reality and its mathematical formulation is discussed. 2012 Physics Essays Publication. (DOI: 10.4006/0836-1398-25.1.27) R ´
Quantum mechanics forms the foundation of all modern physics, including atomic, nuclear, and molecular physics, the physics of the elementary particles, condensed matter physics. Modern astrophysics also relies heavily on quantum mechanics. Quantum theory is needed to understand the basis for new materials, new devices, the nature of light coming from stars, the laws which govern the atomic nucleus, and the physics of biological systems. As a result the subject of this book is a required course for most physics graduate students. While there are many books on the subject, this book targets specifically graduate students and it is written with modern advances in various fields in mind. Many examples treated in the various chapters as well as the emphasis of the presentation in the book are designed from the perspective of such problems. For example, the book begins by putting the Schrodinger equation on a spatial discrete lattice and the continuum limit is also discussed, inspired by Hamiltonian lattice gauge theories. The latter and advances in quantum simulations motivated the inclusion of the path integral formulation. This formulation is applied to the imaginary-time evolution operator to project the exact ground state of the harmonic oscillator as is done in quantum simulations. As an example of how to take advantage of symmetry in quantum mechanics, one-dimensional periodic potentials are discussed, inspired by condensed matter physics. Atoms and molecules are discussed within mean-field like treatment (Hartree-Fock) and how to go beyond it. Motivated by the recent intense activity in condensed matter and atomic physics to study the Hubbard model, the electron correlations in the hydrogen molecule are taken into account by solving the two-site Hubbard model analytically. Using the canonical Hamiltonian quantization of quantum electrodynamics, the photons emerge as the quanta of the normal modes, in the same way as the phonons emerge in the treatment of the normal modes of the coupled array of atoms. This is used later to treat the interaction of radiation with atomic matter.