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Journal of Physics Conference Series

Excited-State Annihilation of Positronium in Cryogenic Silica Aerogel for In-Material Laser Cooling

Akira Ishida, Toshio Namba, Nagayasu Oshima, Brian E. O’Rourke, Koji Michishio, Kenji Ito, Toshio Hyodo, Izumi Mochizuki, Ken Wada, M. Maekawa

Published Nov 1, 2025• 0 citations

Abstract

Abstract We report recent progress toward achieving positronium (Ps) Bose–Einstein condensation (BEC) by combining thermalization in nanoporous materials with ultraviolet (UV) laser Doppler cooling. Experiments were performed using silica aerogels held at two distinct thermal conditions—approximately room temperature and cryogenic temperature down to 8 K (measured at the sample-holder)—to study the laser-induced annihilation of Ps atoms excited to the 2P state. Resonant excitation at 243 nm significantly enhanced gamma-ray emission, with the annihilation signal reduced by approximately 50 % at low temperature compared to room temperature. Increasing the delay between Ps formation and laser excitation further reduced the annihilation probability. These observations confirm that Ps thermalization affects 2P-Ps annihilation. The results support a model of surface-induced 2P-state decay and suggest that excited-state Ps serves as a sensitive probe of surface interactions in nanoporous media. This constitutes an important step toward implementing laser cooling of Ps confined in solids—an essential prerequisite for realizing Ps-BEC. Ongoing efforts focus on systematic evaluation of pore structure, surface chemistry, and temperature effects to optimize Ps dynamics toward condensation.

DOI: 10.1088/1742-6596/3149/1/012001

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Abstract We report recent progress toward achieving positronium (Ps) Bose–Einstein condensation (BEC) by combining thermalization in nanoporous materials with ultraviolet (UV) laser Doppler cooling. Experiments were performed using silica aerogels held at two distinct thermal conditions—approximately room temperature and cryogenic temperature down to 8 K (measured at the sample-holder)—to study the laser-induced annihilation of Ps atoms excited to the 2P state. Resonant excitation at 243 nm significantly enhanced gamma-ray emission, with the annihilation signal reduced by approximately 50 % at low temperature compared to room temperature. Increasing the delay between Ps formation and laser excitation further reduced the annihilation probability. These observations confirm that Ps thermalization affects 2P-Ps annihilation. The results support a model of surface-induced 2P-state decay and suggest that excited-state Ps serves as a sensitive probe of surface interactions in nanoporous media. This constitutes an important step toward implementing laser cooling of Ps confined in solids—an essential prerequisite for realizing Ps-BEC. Ongoing efforts focus on systematic evaluation of pore structure, surface chemistry, and temperature effects to optimize Ps dynamics toward condensation.

Laser cooling of positronium (Ps) is an important technique to advance the frontier of science by, for instance, realizing the first Bose-Einstein condensation of antimatters. It was proposed that performing laser cooling on Ps trapped in a cryogenic porous material would be more efficient, but a recent study (Cooper, et al., Phys. Rev. B 97, 205302 (2018)) reported that Ps in the excited (2P) state inside nano pores of silica had a large decay rate into γ-rays, and the resonant spectrum of the transition was significantly broadened, both of which are critically problematic for the proposed cooling scheme. A possible cause of these unexplained results was proposed to be residual impurities which trapped Ps in the vicinity of the pore surface and then enhanced interactions between Ps and the material. This work reports fabrication and inspection of a new porous silica cavity without such impurities, and construction of an experimental system to induce the Lyman-α transition of Ps trapped in pores of the cavity.

We have measured the kinetic energy of positronium (Ps) atoms emitted into a vacuum from a porous silica film subsequent to positron bombardment, via the Doppler spread of the linewidth of the Ps

{1}^{3}S

-

{2}^{3}P

transition. We find that the deeper in the target film that positrons are implanted the colder is the emitted Ps, an effect we attribute to cooling via collisions in the pores as the atoms diffuse back to the film surface. We observed a lower limit to the mean Ps kinetic energy associated with motion in the direction of the laser, ${E}_{x}=42\ifmmode\pm\else\textpm\fi{}3$ meV, that is consistent with conversion of the confinement energy of Ps in the 2.7-nm-diameter pores to kinetic energy in vacuum. An implication is that a porous sample would need to be composed of pores greater than around 10 nm in diameter in order to produce thermal Ps in vacuum with temperatures of less than 100 K. By performing Doppler spectroscopy on intense pulses of Ps we have experimentally demonstrated the production of many excited-state Ps atoms simultaneously, which could have numerous applications, including laser cooling and fundamental spectroscopic studies of Ps and the production of antihydrogen.

Realization of the Bose–Einstein condensation (BEC) of positronium is a long-standing challenge of positron physics. Since the positron is the antimatter of the electron, the positronium is the antimatter of itself, and its gravity interaction is a sum of matter and antimatter components. In this sense, it can be used to study antimatter gravity. It can also be used as a source of a γ-ray laser. We have proposed a new method to realize a positronium BEC: a combination of thermalization in a cold silica target and laser cooling using 1S-2P transitions. We have started some basic studies based on our new idea. Here we report a preliminary result of our positronium thermalization measurement in cryogenic environment and development status of a new laser system for positronium cooling.

We report orthopositronium $(o\text{\ensuremath{-}}\mathrm{Ps})$ thermalization observed in cryogenic silica aerogel cooled from room temperature to 25 K. It was observed that the $o\text{\ensuremath{-}}\mathrm{Ps}$ thermalization rate gets slower as $o\text{\ensuremath{-}}\mathrm{Ps}$ itself is colder than room temperature. This energy dependence can be explained based on a model where the efficiency of kinetic energy exchange between $o\text{\ensuremath{-}}\mathrm{Ps}$ and silica is determined by the de Broglie wavelength of $o\text{\ensuremath{-}}\mathrm{Ps}$. The present measurement confirmed that a cooling method which utilizes the thermalization process at cryogenic temperatures followed by laser cooling is applicable for the efficient production of an $o\text{\ensuremath{-}}\mathrm{Ps}$ Bose-Einstein condensate.

Abstract A proposed new method of cooling positronium is to realize the Bose–Einstein condensation (BEC) of positronium. We perform detailed studies of three processes: (1) thermalization processes between positronium and the silica walls of a cavity, (2) Ps–Ps scattering and (3) laser cooling. The thermalization process is shown to be not sufficient for BEC. Ps–Ps collision is shown to have a big effect on the cooling performance. We combine both methods and establish an efficient cooling process for BEC. We also propose a new optical laser system for the cooling.

We numerically study laser deceleration, cooling and trapping of host fast ortho-positronium (Ps) bunches as produced in silica microchannel targets using positron bunches from a Surko trap. While Doppler laser cooling routinely allows to cool neutral atom species below milli-Kelvin kinetic temperatures, the fast ground state annihilation and the high recoil shift to line-width ratio in Ps pose new challenging limitations on timing and the required laser power. Earlier theoretical work and first experiments already exhibit viable prospects for radiation pressure cooling to create unprecedented cold and dense Ps ensembles. Our extended numerical studies confirm very good prospects to simultaneously decelerate, cool and optically trap Ps atoms in a standard Doppler cooling geometry on the

1^3\mathrm{S}

--

2^3\mathrm{P}

transition. Including the full Zeeman state manifolds and adding additional transverse lasers on the

2^3\mathrm{P}

--

3^3\mathrm{D}

transition improves timing and final temperature to allow for optical trapping at the end. The required laser powers and geometry parameters to implement effective slowing and trapping within a time frame, where the majority of atoms is not annihilated, is in reach of current technology of

\mathrm{mJ}

energy pulses of approximately

100\ \mathrm{ns}

duration. Future extensions to collectively enhance cooling and trapping in optical cavities or hollow-core fibres should finally allow fast preparation of ultra-cold Ps systems as future basis of superradiant lasing and Bose--Einstein condensates.