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METALLOFIZIKA I NOVEISHIE TEKHNOLOGII

Thermodynamics of the Fermi Gas in a Sphere of Arbitrary Radius

Published Sep 30, 2025• 0 citations
Publisher

Abstract

For the Fermi gas filling the space inside the spherical cavity of arbitrary radius and with an arbitrary, including small, number of particles, the thermodynamic characteristics are calculated in the general form, namely: entropy, energy, thermodynamic potential, constituent elements of equation of state, heat capacities, and compressibilities.The size effects relating to the discrete structure of levels are investigated.On the example of the two-and three-level models, there is traced both the sequence of level filling with increasing temperature and the temperature dependence of the chemical potential.As shown, at temperatures, at which the filling of a new level begins, the heat capacity undergoes jumps.

DOI
10.15407/mfint.47.09.0907

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For the Fermi gas filling the space inside the spherical cavity of arbitrary radius and with an arbitrary, including small, number of particles, the thermodynamic characteristics are calculated in the general form, namely: entropy, energy, thermodynamic potential, constituent elements of equation of state, heat capacities, and compressibilities.The size effects relating to the discrete structure of levels are investigated.On the example of the two-and three-level models, there is traced both the sequence of level filling with increasing temperature and the temperature dependence of the chemical potential.As shown, at temperatures, at which the filling of a new level begins, the heat capacity undergoes jumps.
For the ideal Fermi gas that fills a quantum well confined by two parallel planes, there are calculated the thermodynamic characteristics in general form for arbitrary temperatures, namely: the thermodynamic potential, energy, entropy, equations of state, heat capacities and compressibilities. The distance between planes is considered as an additional thermodynamic variable. Owing to the anisotropy, the pressure of the Fermi gas along and transverse to the planes is different, so that the system is characterized by two equations of state and a set of different heat capacities. Limiting cases of low and high temperatures are considered. The temperature dependencies of the entropy and heat capacities at low temperatures remain linear, just as in the volume case, and their dependencies on the chemical potential and density undergo jumps at the beginning of the filling of new discrete levels. It is shown that the behavior of thermodynamic quantities with the distance between plates can be either oscillating or monotonic, depending on what quantity is assumed to be fixed: the volume or surface density. For high temperatures the corrections to thermodynamic quantities are obtained, which are proportional to the ratio of the thermal de Broglie wavelength to the distance between planes.
For the ideal Fermi gas that fills the space inside a cylindrical tube, there are calculated the thermodynamic characteristics in general form for arbitrary temperatures, namely: the thermodynamic potential, energy, entropy, equations of state, heat capacities and compressibilities. All these quantities are expressed through the introduced standard functions and their derivatives. The radius of the tube is considered as an additional thermodynamic variable. It is shown that at low temperatures in the quasi-one-dimensional case the temperature dependencies of the entropy and heat capacities remain linear. The dependencies of the entropy and heat capacities on the chemical potential have sharp maximums at the points where the filling of a new discrete level begins. The character of dependencies of thermodynamic quantities on the tube radius proves to be qualitatively different in the cases of fixed linear and fixed total density. At the fixed linear density these dependencies are monotonous and at the fixed total density they have an oscillating character. Key words: Fermi particle, nanotube, thermodynamic functions, low-dimensional systems, equation of state, heat capacity, compressibility
The effects of low dimensionality on the thermodynamics of a Fermi gas trapped by isotropic power-law potentials are analyzed. Particular attention is given to different characteristic temperatures that emerge, at low dimensionality, in the thermodynamic functions of state and in the thermodynamic susceptibilities (isothermal compressibility and specific heat). An energy-entropy argument that physically favors the relevance of one of these characteristic temperatures, namely, the nonvanishing temperature at which the chemical potential reaches the Fermi energy value, is presented. Such an argument allows interpreting the nonmonotonic dependence of the chemical potential on temperature, as an indicator of the appearance of a thermodynamic regime, where the equilibrium states of a trapped Fermi gas are characterized by larger fluctuations in energy and particle density as is revealed in the corresponding thermodynamics susceptibilities.
At zero-temperature and finite-temperature, the thermodynamic properties of finite unitary Fermi gas in a three-dimensional harmonic trap are investigated by using fractional exclusion statistics, and the results are compared with those of the system which satisfies the thermodynamic limit. At zero-temperature, Fermi energy and average energy of per particle increase with the increase of the number of particles for finite unitary Fermi gas, and their limits are the corresponding parameters of the system which satisfy thermodynamic limits. Fermi energy and average energy of per particle each have a maximum value changing with the boundary of the potential well. For the finite-temperature trapped unitary Fermi system, when the number of particles is certain the average energy of per particle, average entropy of per particle, average heat capacity of per particle each have a characteristic temperature, respectively, when the temperature is equal to the characteristic temperature of the physical parameter, the corresponding parameters for the finite system and the thermodynamic limit system are equal, when the temperature is lower (or higher) than the characteristic temperature of parameter, the physical parameter of the finite system will be greater (or less) than the corresponding parameter of the thermodynamic limit system. The characteristic temperature has particle number effect and boundary effect. When the temperature is determined, the average energy of per particle, average entropy of per particle and average heat capacity of per particle each have a characteristic number of particles, respectively, when the number of particles is equal to the characteristic number of particles for physical parameter, the corresponding parameters for the finite system and the thermodynamic limit system are equal, when the number of particles is less (or more) than the characteristic number of particles for corresponding parameter, the corresponding parameter of the finite system will be less (or larger) than the thermodynamic limit of system.
The properties of an ideal Fermi gas in an external potential in any dimensional space are studied, based on the semiclassical (Thomas-Fermi) approximation. The general analytical expressions of the total particle number N,N,N, density of states $D(\ensuremath{\varepsilon}),$ Fermi energy EF,{E}_{F},EF​, total energy E,E,E, and heat capacity CCC have been derived, where N,N,N, E,E,E, and CCC are expressed by the Fermi integration. Moreover, the analytical expressions of the total energy E,E,E, chemical potential \ensuremath{\mu}, and heat capacity CCC in the high- and low-temperature approximations are given. From these results, how the characteristics of the Fermi gas depend on an external potential and the dimension of space is discussed.
Thermodynamic properties of matter generally depend on the details of interactions between its constituent parts. However, in a unitary Fermi gas where the scattering length diverges, thermodynamics is determined through universal functions that depend only on the particle density and temperature. By using only the general form of the equation of state and the equation of force balance, we measured the local internal energy of the trapped gas as a function of these parameters. Other universal functions, such as those corresponding to the Helmholtz free energy, chemical potential, and entropy, were calculated through general thermodynamic relations. The critical parameters were also determined at the superfluid transition temperature. These results apply to all strongly interacting fermionic systems, including neutron stars and nuclear matter.