In this chapter we review the ideas and discoveries that lead to the development of quantum mechanics. Like other theories in physics, it was motivated by a series of experimental results that were at odds with the prevailing theories of the time. New concepts were introduced to explain those experiments, which in turn led to new experiments and more discoveries. Quantum mechanics took its current shape about 100 years ago and continues to provide a formidable framework for describing not only natural phenomena but also for leading us to new technologies, such as quantum information processing.
In this chapter we review the ideas and discoveries that lead to the development of quantum mechanics. Like other theories in physics, it was motivated by a series of experimental results that were at odds with the prevailing theories of the time. New concepts were introduced to explain those experiments, which in turn led to new experiments and more discoveries. Quantum mechanics took its current shape about 100 years ago and continues to provide a formidable framework for describing not only natural phenomena but also for leading us to new technologies, such as quantum information processing.
This chapter presents the basic physical ideas that underpin the quantum theory. Historians place the beginnings of the quantum theory at 1900. That year Max Planck published his famous formula for the distribution of energy as a function of frequency in black-body radiation. Curiously, although radiation theory gave birth to quantum mechanics, the interaction of matter and electromagnetic radiation is a rather advanced topic in quantum mechanics and it took almost fifty years for an acceptable formulation to be achieved. One reason for this is that photons are quanta of the electromagnetic field, and the quantum theory of fields requires a relativistic treatment to be entirely successful. The corpuscular nature of light was only half of the input that gave birth to quantum mechanics. The other half concerns matter. Given that the discreteness of photons manifests itself during the emission and absorption process, it is not surprising to find that quantum oddities afflict the behaviour of material particles too.
Quantum mechanics is essentially a 20th century development that is based on a number of observations that defied classical explanations. While some of these experiments have semiclassical explanations, the triumph of quantum mechanics is that it gives precise verification for an overwhelming number of experimental observations. Its extensions into relativistic quantum mechanics through quantum electrodynamics (QED), electro-weak theory, and quantum chromodynamics (QCD) have led us to the Standard Model of today. While the number of unanswered questions remains approximately constant at each stage of development, the number of answered questions that relate theory with experiment continues to grow rapidly. In this chapter, some of the historical landmarks in the development of the theory are noted. The resolution of the dilemmas presented by classical theory will be dealt with in later chapters, but these are listed to motivate the break from classical mechanics. Because of the apparently unphysical nature of the postulates upon which quantum mechanics is founded, we supply motivation and justification for this break. In the first part of this chapter, we will review some of the experiments that confounded classical theory, and then introduce a formalism that provides some rationale for the postulates upon which quantum mechanics is based. In the end, these postulates will stand on their own.
Quantum mechanics is a theory to explain and predict the behavior of particles such as electrons, protons, neutrons, atomic nuclei, atoms, and molecules, as well as the photon–the particle associated with electromagnetic radiation or light. From quantum theory we obtain the laws of chemistry as well as explanations for the properties of materials, such as crystals, semiconductors, superconductors, and superfluids. Applications of quantum behavior give us transistors, computer chips, lasers, and masers. The relatively new field of molecular biology, which leads to our better understanding of biological structures and life processes, derives from quantum considerations. Thus, quantum behavior encompasses a large fraction of modern science and technology. Quantum theory was developed during the first half of the twentieth century through the efforts of many scientists. In 1926, E. Schrödinger interjected wave mechanics into the array of ideas, equations, explanations, and theories that were prevalent at the time to explain the growing accumulation of observations of quantum phenomena. His theory introduced the wave function and the differential wave equation that it obeys. Schrödinger's wave mechanics is now the backbone of our current conceptional understanding and our mathematical procedures for the study of quantum phenomena. Our presentation of the basic principles of quantum mechanics is contained in the first three chapters. Chapter 1 begins with a treatment of plane waves and wave packets, which serves as background material for the subsequent discussion of the wave function for a free particle.
ENGLISH ABSTRACT: What are the information processing capabilities of physical systems? As recently as the first half of the 20th century this question did not even have a definite meaning. What is information, and how would one process it? It took the development of theories of computing (in the 1930s) and information (late in the 1940s) for us to formulate mathematically what it means to compute or communicate. Yet these theories were abstract, based on axiomatic mathematics: what did physical systems have to do with these axioms? Rolf Landauer had the essential insight - "Information is physical" - that information is always encoded in the state of a physical system, whose dynamics on a microscopic level are well-described by quantum physics. This means that we cannot discuss information without discussing how it is represented, and how nature dictates it should behave. Wigner considered the situation from another perspective when he wrote about "the unreasonable effectiveness of mathematics in the natural sciences". Why are the computational techniques of mathematics so astonishingly useful in describing the physical world [1]? One might begin to suspect foul play in the universe's operating principles. Interesting insights into the physics of information accumulated through the 1970s and 1980s - most sensationally in the proposal for a "quantum computer". If we were to mark a particular year in which an explosion of interest took place in information physics, that year would have to be 1994, when Shor showed that a problem of practical interest (factorisation of integers) could be solved easily on a quantum computer. But the applications of information in physics - and vice versa - have been far more widespread than this popular discovery. These applications range from improved experimental technology, more sophisticated measurement techniques, methods for characterising the quantum/classical boundary, tools for quantum chaos, and deeper insight into quantum theory and nature. In this thesis I present a short review of ideas in quantum information theory. The first chapter contains introductory material, sketching the central ideas of probability and information theory. Quantum mechanics is presented at the level of advanced undergraduate knowledge, together with some useful tools for quantum mechanics of open systems. In the second chapter I outline how classical information is represented in quantum systems and what this means for agents trying to extract information from these systems. The final chapter presents a new resource: quantum information. This resource has some bewildering applications which have been discovered in the last ten years, and continually presents us with unexpected insights into quantum theory and the universe.
Reality is that which, when you stop believing in it, does not go away. Philip K. Dick In Chapters 1 and 2 we developed the necessary mathematical apparatus and terminology that will be used throughout this book. Chapter 3 has provided some heuristics and gently led us to the threshold of quantum mechanics. It is now time to open the door, introduce the basic concepts and tools of the trade, and continue our journey to quantum computing. In Section 4.1 we spend a few words on the motivations behind quantum mechanics. We then introduce quantum states and how they are distinguishable from one another through observations. Section 4.2 describes observable physical quantities within the quantum framework. How observable quantities are measured is the topic of Section 4.3. The dynamics of quantum systems, i.e., their evolution in time, is the focus of Section 4.4. Finally, in Section 4.5, we revisit the tensor product and show how it describes the way in which larger quantum systems are assembled from smaller ones. In the process, we meet the crucial notion of entanglement, a feature of the quantum world that pops up again in the chapters ahead. QUANTUM STATES Why quantum mechanics? To answer this question, we have to hearken back in time to the dawn of the twentieth century. Classical mechanics still dominated the scene, with its double-pronged approach: particles and waves .