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Philosophical Problems in Science (Zagadnienia Filozoficzne w Nauce)

Quantum mechanics of identical particles

Marek Kuś

Published Nov 8, 2022• 0 citations
Publisher

Abstract

Leibniz’s principium identitatis indiscernibilium excludes the existence of two different objects possessing all properties identical. Although perfectly acceptable for macroscopic systems, it becomes questionable in quantum mechanics, where the concept of identical particles is quite natural and has measurable consequences. On the other hand, Leibniz’s principle seems to be indispensable when we want to individuate an item and ascribe to it particular property (e.g. value of the projection of spin on a chosen axis). We may thus abandon the principle on the quantum level, claiming it falsity here, or (better) try to find other ways of individuation of objects, possibly by adopting appropriately the very concept of it. All these problems, and many other connected with identity and indiscernibility of quantum objects, are thoroughly discussed in the book of Tomasz Bigaj, unique in the world literature due to its comprehensiveness.

DOI
10.59203/zfn.72.591

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Leibniz’s principium identitatis indiscernibilium excludes the existence of two different objects possessing all properties identical. Although perfectly acceptable for macroscopic systems, it becomes questionable in quantum mechanics, where the concept of identical particles is quite natural and has measurable consequences. On the other hand, Leibniz’s principle seems to be indispensable when we want to individuate an item and ascribe to it particular property (e.g. value of the projection of spin on a chosen axis). We may thus abandon the principle on the quantum level, claiming it falsity here, or (better) try to find other ways of individuation of objects, possibly by adopting appropriately the very concept of it. All these problems, and many other connected with identity and indiscernibility of quantum objects, are thoroughly discussed in the book of Tomasz Bigaj, unique in the world literature due to its comprehensiveness.
Abstract Drawing on philosophical accounts of identity and individuality, as well as the histories of both classical and quantum physics, this book explores two alternative metaphysical approaches to quantum particles. It asks if quantum particles can be regarded as individuals, just like books, tables, and people. Taking the first approach, the book argues that if quantum particles are regarded as individuals, then Leibniz’s famous Principle of the Identity of Indiscernibles is in fact violated. Recent discussions of this conclusion are analysed in detail and the costs involved in saving the Principle are carefully considered. For the second approach, the book considers recent work in non-standard logic and set theory to indicate how we can make sense of the idea that objects can be non-individuals. The concluding chapter suggests how these results might then be extended to quantum field theory.
The treatment of identical particles in quantum mechanics rests on two (related) principles: the spin‐statistics connection and the Symmetrization Postulate. In light of recent theories (such as q‐deformed commutators) that allow for ‘small’ violations of the spin‐statistics connection and the Symmetrization Postulate, we revisit the issue of how quantum mechanics deals with identical particles and how it supports or fails to support various philosophical stances concerning individuality. As a consequence of the expanded possibilities for quantum statistics, we argue that permutation symmetry is best formulated as a formal property of the state function describing the system of particles rather than as a property of the individual particles.1 Introduction2 Philosophical background2.1 Important terminology2.1.1 Identity2.1.2 Indistinguishability2.1.3 Indiscernibility2.2 When are particles indistinguishable?2.3 The Principle of the Identity of Indiscernibles and quantum mechanics2.4 The Principle of the Identity of Indiscernibles and logic2.5 Particle history2.6 Transcendental individuality3 Some quantum formalism3.1 The Principle of Permutation Invariance and the Symmetrization Postulate3.2 The configuration‐space approach3.3 Commutators and anticommutators, and identical particle statistics3.4 Q‐mutators4 Identical particle statistics: a holistic point of view5 Conclusions
Abstract According to classical physics particles are basic building blocks of the world. These classical particles are distinguishable objects, individuated by unique combinations of physical properties. By contrast, in quantum mechanics the received view is that particles of the same kind (“identical particles”) are physically indistinguishable from each other and lack identity. This doctrine rests on the quantum mechanical (anti)symmetrization postulates together with the “factorist” assumption that each single particle is represented in exactly one factor space of the tensor product Hilbert space of a many-particle system. Even though standard in theoretical physics and the philosophy of physics, the assumption of factorism and the ensuing indistinguishability of particles are problematic. Particle indistinguishability is irreconcilable with the everyday meaning of “particle”, and also with how this term is used in the practice of physics. Moreover, it is a consequence of the standard view that identical quantum particles remain indistinguishable even in the classical limit, which makes a smooth transition to the classical particle concept impossible. Lubberdink (1998; 2009) and Dieks and Lubberdink (2011) have proposed an alternative conception of quantum particles that does not rely on factorism and avoids these difficulties. We further explain and discuss this alternative framework here. One of its key consequences is that particles in quantum theory are not fundamental but emergent; another that once they have emerged, quantum particles are always physically distinguishable and thus possess a physically grounded identity.
Alberto Cortes, in [1], attempts to show (a) that Leibniz's Principle of The Identity of Indiscernibles (L) is a principle restricted to individuals (as distinct from a class of entities Cortes takes to be non-individuals), and (b) that photons (light quanta) appear to violate L (since they don't obey Pauli's Exclusion Principle). L is stated by Leibniz as “no two substances are completely similar, or differ solo numero.” In second-order quantification theory with identity L becomes:
Elementary particles appear in different ways.Particles of the same kind (similar particles) share all state-independent properties like mass, charge, and spin quantum number; there are many similar particles, but they are indistinguishable with respect to a certain class of properties.However, the case might even be stronger: similar particles apparently share all state-dependent properties, like spatial location and spin projection.This threatens the validity of Leibniz's famous Principle of the Identity of Indiscernibles (PII; see Rodriguez-Pereyra (2014) for a historical reconstruction).As it is usually understood, quantum mechanics requires for similar particles to be in permutation invariant states.Take the following state, for example: