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Bulletin of the Institute of Mathematics Academia Sinica NEW SERIES

Phase transition between two-component and three-component ground states of spin-1 Bose-Einstein condensates

Lin Liren, I‐Liang Chern

Published Jun 1, 2025• 0 citations
Publisher

Abstract

For an antiferromagnetic spin-1 Bose-Einstein condensate under an applied uniform magnetic field, its ground state $(\psi_1,\psi_0,\psi_{-1})$ undergoes a phase transition from a two-component state ($\psi_0 \equiv 0$) to a three-component state ($\psi_j\ne 0$ for all $j$) at a critical value of the magnetic field. This phenomenon has been observed in numerical simulations as well as in experiments. In this paper, we provide a mathematical proof based on a simple principle found by the authors: a redistribution of the mass densities between different components will decrease the kinetic energy.

DOI
10.21915/bimas.2025202

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質量重分配及其在自旋-1玻色-愛因斯坦凝聚基態上之應用

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Spin-1 Bose-Einstein condensate (BEC) is a special three-component system, written as $Psi=(psi_1,psi_0,psi_{-1})$. Its behavior is described by an energy functional $E[Psi]$ with two constraints: the conservation of the number of atoms and the conservation of total magnetization. That is $int |Psi|^2$ and $intlt(|psi_1|^2-|psi_{-1}|^2t)$ are fixed numbers. And a ground state is a minimizer of $E$ under the constraints. To explain what we do in this thesis, we remark that according to the sign of a specific parameter in the energy $E$, spin-1 BECs are classified into two groups: ferromagnetic ones and antiferromagnetic ones. The works in this thesis are motivated by the following two phenomena: 1. Any ground state of a ferromagnetic system is of the form begin{align*} Psi = (gamma_1 psi,gamma_0 psi,gamma_{-1} psi), end{align*} where $gamma_j$ are constants and $psi$ a function. This is called single-mode approximation. 2. When an external magnetic field is applied, the ground state of an antiferromagnetic system undergoes a bifurcation from $psi_0 equiv 0$ to $psi_0 ne 0$ as the strength of the magnetic field surpasses a critical value. Although these phenomena have been well-known from numerical simulations for quite a long time, there were no rigorous mathematical justifications before our investigations. In this thesis, our works [16,17] on their proofs are given, with more details. The proofs rely on a principle which says that a redistribution of the mass densities (i.e. $|psi_1|^2$, $|psi_0|^2$ and $|psi_{-1}|^2$) will decrease the kinetic energy. This principle can be regarded as a simple generalization of a well-known convexity inequality for gradients. We will show how this principle can give a rather unified approach toward our problems.

•Jan 1, 2013•0 citations
For an antiferromagnetic spin-1 Bose-Einstein condensate under an applied uniform magnetic field, its ground state (ψ1,ψ0,ψ−1)(\psi_1,\psi_0,\psi_{-1})(ψ1​,ψ0​,ψ−1​) undergoes a phase transition from a two-component state (ψ0≡0\psi_0 \equiv 0ψ0​≡0) to a three-component state (ψj≠0\psi_j\ne 0ψj​=0 for all jjj) at a critical value of the magnetic field. This phenomenon has been observed in numerical simulations as well as in experiments. In this paper, we provide a mathematical proof based on a simple principle found by the authors: a redistribution of the mass densities between different components will decrease the kinetic energy.
For an antiferromagnetic spin-1 Bose-Einstein condensate under an applied uniform magnetic field, its ground state (ψ1,ψ0,ψ−1)(ψ_1,ψ_0,ψ_{-1})(ψ1​,ψ0​,ψ−1​) undergoes a phase transition from a two-component state (ψ0≡0ψ_0 \equiv 0ψ0​≡0) to a three-component state (ψj≠0ψ_j\ne 0ψj​=0 for all jjj) at a critical value of the magnetic field. This phenomenon has been observed in numerical simulations as well as in experiments. In this paper, we provide a mathematical proof based on a simple principle found by the authors: a redistribution of the mass densities between different components will decrease the kinetic energy.
We justify some characterizations of the ground states of spin-1 Bose-Einstein condensates exhibited from numerical simulations. For ferromagnetic systems, we show the validity of the single-mode approximation (SMA). For an antiferromagnetic system with nonzero magnetization, we prove the vanishing of the mF=0m_F=0mF​=0 component. In the end of the paper some remaining degenerate situations are also discussed. The proofs of the main results are all based on a simple observation, that a redistribution of masses among different components will reduce the kinetic energy.
We study antiferromagnetic spin-1 Bose-Einstein condensates under external uniform magnetic fields. The bifurcation between two-component and three-component regimes of ground states with respect to the magnetization M and the quadratic Zeeman effect q is justified. The proof is based on the technique of “mass redi stribution” introduced in the authors previous work, which gives interesting inequalities and equalities satisfied by ground states. Some open problems arising naturally from our investigation are also discussed in the end.
We justify some characterizations of the ground states of spin-1 Bose-Einsteincondensates exhibited from numerical simulations. For ferromagnetic systems, weshow the validity of the single-mode approximation (SMA). For anantiferromagnetic system with nonzero magnetization, we prove the vanishing ofthe mF=0m_F=0mF​=0 component. In the end of the paper some remaining degeneratesituations are also discussed. The proofs of the main results are all based ona simple observation, that a redistribution of masses among differentcomponents will reduce the kinetic energy.
We develop an analytic theory for the ground state patterns and their phase transitions for spin-1 Bose-Einstein condensates on a bounded domain in the presence of a uniform magnetic field. Within the Thomas-Fermi approximation, these ground state patterns are composed of four basic states: magnetic state, nematic state, two-component state and three-component state, separated by interfaces. A complete phase diagram of the ground state patterns are found analytically with different quadratic Zeeman energy q and total magnetization M for both ferromagnetic and antiferromagnetic systems. Using the Γ-convergence technique, it is found that the semi-classical limits of these ground states minimize an energy functional which consists of interior interface energy plus a boundary contact energy. As a consequence, the interface between two different basic states has constant mean curvature, and the contact angle between the interface and the boundary obeys Young's relation.
Spin-1 Bose-Einstein condensate (BEC) is a special three-component system, written as Psi=(psi1,psi0,psi−1)Psi=(psi_1,psi_0,psi_{-1})Psi=(psi1​,psi0​,psi−1​). Its behavior is described by an energy functional E[Psi]E[Psi]E[Psi] with two constraints: the conservation of the number of atoms and the conservation of total magnetization. That is int∣Psi∣2int |Psi|^2int∣Psi∣2 and intlt(∣psi1∣2−∣psi−1∣2t)intlt(|psi_1|^2-|psi_{-1}|^2t)intlt(∣psi1​∣2−∣psi−1​∣2t) are fixed numbers. And a ground state is a minimizer of EEE under the constraints. To explain what we do in this thesis, we remark that according to the sign of a specific parameter in the energy EEE, spin-1 BECs are classified into two groups: ferromagnetic ones and antiferromagnetic ones. The works in this thesis are motivated by the following two phenomena: 1. Any ground state of a ferromagnetic system is of the form begin{align*} Psi = (gamma_1 psi,gamma_0 psi,gamma_{-1} psi), end{align*} where gammajgamma_jgammaj​ are constants and psipsipsi a function. This is called single-mode approximation. 2. When an external magnetic field is applied, the ground state of an antiferromagnetic system undergoes a bifurcation from psi0equiv0psi_0 equiv 0psi0​equiv0 to psi0ne0psi_0 ne 0psi0​ne0 as the strength of the magnetic field surpasses a critical value. Although these phenomena have been well-known from numerical simulations for quite a long time, there were no rigorous mathematical justifications before our investigations. In this thesis, our works [16,17] on their proofs are given, with more details. The proofs rely on a principle which says that a redistribution of the mass densities (i.e. ∣psi1∣2|psi_1|^2∣psi1​∣2, ∣psi0∣2|psi_0|^2∣psi0​∣2 and ∣psi−1∣2|psi_{-1}|^2∣psi−1​∣2) will decrease the kinetic energy. This principle can be regarded as a simple generalization of a well-known convexity inequality for gradients. We will show how this principle can give a rather unified approach toward our problems.