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Annals of the New York Academy of Sciences

On the photon–classical electromagnetic field relationship

Daniela Dragoman

Published Jun 18, 2025• 3 citations
Publisher

Abstract

This paper discusses how the two ways in which the wavefunction of a free-propagating photon can be introduced-starting from the relativistic energy-momentum relationship or based on the electromagnetic field, in particular on Riemann-Silberstein vectors-are not entirely equivalent since they can lead to different consequences regarding photon localization. In the first case, a phase space localization in regions of the order of Planck's constant, in agreement with the quantum uncertainty principle, could be unambiguously obtained. In the second case, the choice of canonically conjugate variables and Fourier transforms determines if the state is treated quantumly or classically. Both formalisms are, however, compatible.

DOI
10.1111/nyas.15378

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This paper discusses how the two ways in which the wavefunction of a free-propagating photon can be introduced-starting from the relativistic energy-momentum relationship or based on the electromagnetic field, in particular on Riemann-Silberstein vectors-are not entirely equivalent since they can lead to different consequences regarding photon localization. In the first case, a phase space localization in regions of the order of Planck's constant, in agreement with the quantum uncertainty principle, could be unambiguously obtained. In the second case, the choice of canonically conjugate variables and Fourier transforms determines if the state is treated quantumly or classically. Both formalisms are, however, compatible.
In Chapt. 10, photon wave mechanics was based on the transverse part of the vector potential. As we shall realize soon, it is quite possible to claim rightfully that other quantities constructed from electromagnetic field vectors may be considered as the photon wave function in free space. The crucial point is that whatever choice one makes for the photon wave function the subsequent photon-matter interactions must all result in the same observable consequences. In this chapter an important and interesting choice based on the Riemann-Silberstein vectors, which were introduced in Sec. 2.8, will be described.
A first-quantized free photon is a complex massless vector field A=(Aμ) whose field strength satisfies Maxwell’s equations in vacuum. We construct the Hilbert space H of the photon by endowing the vector space of the fields A in the temporal-Coulomb gauge with a positive-definite and relativistically invariant inner product. We give an explicit expression for this inner product, identify the Hamiltonian for the photon with the generator of time translations in H, determine the operators representing the momentum and the helicity of the photon, and introduce a chirality operator whose eigenfunctions correspond to fields having a definite sign of energy. We also construct a position operator for the photon whose components commute with each other and with the chirality and helicity operators. This allows for the construction of the localized states of the photon with a definite sign of energy and helicity. We derive an explicit formula for the latter and compute the corresponding electric and magnetic fields. These turn out to diverge not just at the point where the photon is localized but on a plane containing this point. We identify the axis normal to this plane with an associated symmetry axis and show that each choice of this axis specifies a particular position operator, a corresponding position basis, and a position representation of the quantum mechanics of a photon. In particular, we examine the position wave functions determined by such a position basis, elucidate their relationship with the Riemann-Silberstein and Landau-Peierls wave functions, and give an explicit formula for the probability density of the spatial localization of the photon.
Some connections between quantum mechanics and classical physics are explored. The Planck–Einstein and De Broglie relations, the wavefunction and its probabilistic interpretation, the canonical commutation relations and the Maxwell–Lorentz equation may be understood in a simple way by comparing classical electromagnetism and the photonic description of light provided by classical relativistic kinematics. The method used may be described as 'inverse correspondence' since quantum phenomena become apparent on considering the low photon number density limit of classical electromagnetism. Generalization to massive particles leads to the Klein–Gordon and Schrödinger equations. The difference between the quantum wavefunction of the photon and a classical electromagnetic wave is discussed in some detail.
Classical equations of motion that are first-order in time and conserve energy can only be quantized after their variables have been transformed to canonical ones, i.e., variables in which the energy is the system's Hamiltonian. The source-free version of Maxwell's equations is purely dynamical, first-order in time and has well-defined nonnegative conserved field energy but is decidedly noncanonical. That should long ago have made source-free Maxwell equation canonical Hamiltonization a research priority, and afterward, standard textbook fare, but textbooks seem unaware of the issue. The opposite parities of the electric and magnetic fields and consequent curl operations that typify Maxwell's equations are especially at odds with their being canonical fields. Transformation of the magnetic field into the transverse part of the vector potential helps but is not sufficient; further simple nonnegative symmetric integral transforms, which commute with all differential operators, are needed for both fields; such transforms also supplant the curls in the equations of motion. The canonical replacements of the source-free electromagnetic fields remain transverse-vector fields, but are more diffuse than their predecessors, albeit less diffuse than the transverse vector potential. Combined as the real and imaginary parts of a complex field, the canonical fields prove to be the transverse-vector wave function of a time-dependent Schrodinger equation whose Hamiltonian operator is the quantization of the free photon's square-root relativistic energy. Thus proper quantization of the source-free Maxwell equations is identical to second quantization of free photons that have normal square-root energy. There is no physical reason why first and second quantization of any relativistic free particle ought not to proceed in precise parallel, utilizing the square-root Hamiltonian operator. This natural procedure leaves no role for the completely artificial Klein-Gordon and Dirac equations, as accords with their grossly unphysical properties.
This tutorial begins with the relationship of source-free classical electromagnetism to ultra-relativistic free-photon quantum mechanics. The linear transformation of the source-free classical-electromagnetic real-valued transverse vector potential to its corresponding free-photon Schroedinger-equation complex-valued transverse vector wave function is obtained. It is then pointed out that despite the free-photon Klein-Gordon equation's being formally identical to the source-free classical-electromagnetic vector-potential wave equation, it yields not only free-photon Schroedinger-equation wave functions but also their complex conjugates, which don't satisfy the free-photon Schroedinger equation. This is a consequence of admitting complex-valued solutions of the Klein-Gordon equation -- of course only its real-valued solutions apply to the classical vector potential. It is pointed out that solutions of the free-particle Dirac equation likewise occur in conjugate pairs, and that its Hamiltonian operator implies a variety of unphysical consequences, e.g., any Dirac free particle's speed is that of light times the square root of three.
It has recently been shown that the classical electric and magnetic fields which satisfy the source-free Maxwell equations can be linearly mapped into the real and imaginary parts of a transverse-vector wave function which in consequence satisfies the time-dependent Schroedinger equation whose Hamiltonian operator is physically appropriate to the free photon. The free-particle Klein-Gordon equation for scalar fields modestly extends the classical wave equation via a mass term. It is physically untenable for complex-valued wave functions, but has a sound nonnegative conserved-energy functional when it is restricted to real-valued classical fields. Canonical Hamiltonization and a further canonical transformation maps the real-valued classical Klein-Gordon field and its canonical conjugate into the real and imaginary parts of a scalar wave function (within a constant factor) which in consequence satisfies the time-dependent Schroedinger equation whose Hamiltonian operator has the natural correspondence-principle relativistic square-root form for a free particle, with a mass that matches the Klein-Gordon field theory's mass term. Quantization of the real-valued classical Klein-Gordon field is thus second quantization of this natural correspondence-principle first-quantized relativistic Schroedinger equation. Source-free electromagnetism is treated in a parallel manner, but with the classical scalar Klein-Gordon field replaced by a transverse vector potential that satisfies the classical wave equation. This reproduces the previous first-quantized results that were based on Maxwell's source-free electric and magnetic field equations.