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Physical review. E

Work statistics and thermal phase transitions

Kwai-Kong Ng, Min-Fong Yang

Published Jun 18, 2025• 0 citations
Publisher

Abstract

The investigation of nonequilibrium thermodynamics in quantum many-body systems underscores the importance of quantum work, which differs from its classical counterpart due to its statistical nature. Recent studies have shown that quantum work can serve as an effective indicator of quantum phase transitions in systems subjected to sudden quenches. However, the potential of quantum work to identify thermal phase transitions remains largely unexplored. In this paper, we examine several types of thermal phase transitions in a sudden-quench hard-core boson model, including Ising, three-state Potts, and Berezinskii-Kosterlitz-Thouless transitions. Through finite-size scaling analysis, we conclude that work statistics can also characterize the critical behaviors of thermal phase transitions in generic many-body systems. This study lays the groundwork for broader applications of work statistics in analyzing critical phenomena across diverse settings.

DOI
10.1103/77fj-z867

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The investigation of nonequilibrium thermodynamics in quantum many-body systems underscores the importance of quantum work, which differs from its classical counterpart due to its statistical nature. Recent studies have shown that quantum work can serve as an effective indicator of quantum phase transitions in systems subjected to sudden quenches. However, the potential of quantum work to identify thermal phase transitions remains largely unexplored. In this paper, we examine several types of thermal phase transitions in a sudden-quench hard-core boson model, including Ising, three-state Potts, and Berezinskii-Kosterlitz-Thouless transitions. Through finite-size scaling analysis, we conclude that work statistics can also characterize the critical behaviors of thermal phase transitions in generic many-body systems. This study lays the groundwork for broader applications of work statistics in analyzing critical phenomena across diverse settings.
Many previous studies have demonstrated that work statistics can exhibit certain singular behaviors in the quantum critical regimes of many-body systems at zero or very low temperatures. However, as the temperature increases, it is commonly believed that such singularities will vanish. Contrary to this common recognition, we report a nonanalytic behavior of the averaged work done, which occurs at finite temperature, in the Dicke model as well as the Lipkin-Meshkov-Glick model subjected to the sudden quenches of their work parameters. It is revealed that work statistics can be viewed as a signature of the thermal phase transition when the quenched parameters are tuned across the critical line that separates two different thermal phases.
The emerging field of quantum thermodynamics is contributing important results and insights into archetypal many-body problems, including quantum phase transitions. Still, the question whether out-of-equilibrium quantities, such as fluctuations of work, exhibit critical scaling after a sudden quench in a closed system has remained elusive. Here, we take a novel approach to the problem by studying a quench across an impurity quantum critical point. By performing density matrix renormalization group computations on the two-impurity Kondo model, we are able to establish that the irreversible work produced in a quench exhibits finite-size scaling at quantum criticality. This scaling faithfully predicts the equilibrium critical exponents for the crossover length and the order parameter of the model, and, moreover, implies an exponent for the rescaled irreversible work. By connecting the irreversible work to the two-impurity spin correlation function, our findings can be tested experimentally.
This thesis reports the results obtained during my PhD research in the field of out of equilibrium quantum many-body systems. Chapter 1 consists in a brief introduction of the field and the introduction of concept that are useful for the following chapters. In Chapter 2 the statistics of the work as a tool for characterizing the dynamics of many-body quantum systems is introduced its general features discussed. Then, such a statistics is computed for generic time-dependent protocols (both global and local) in the quantum Ising chain and in the Gaussian field theory, showing, in particular, that in its low-energy part there are features that are independent of the details of the specific chosen protocol. Chapter 3 is devoted to the study of the dynamical phase transition in the O(N)O(N)O(N) quantum vector model in the N→∞N \rightarrow \inftyN→∞ limit, whose critical properties in generic dimensions are characterized. Moreover, a strong connection between such a transition and the statistics of excitations produced in a double quench as a function of the waiting time is showed. The chapter ends by studying the fate of the dynamical transition and the its critical properties when a ramp of finite duration τ\tauτ is applied to the system instead of a sudden quench. In particular, we will show that when τ→∞\tau \rightarrow \inftyτ→∞ the critical point tends to the equilibrium critical point (at zero temperature) in a power-law fashion and that for every finite τ\tauτ the critical properties are always the same (and different from the equilibrium critical properties). Finally in Chapter 4 we will discuss the emergence of a non adiabatic behavior in the dynamics of the order parameter for a low dimensional quantum system driven within a gapped phase by considering in detail the case of a quantum Ising chain subject to a linear variation in time of the transverse field, showing that, no matter how slowly the ramp is performed, such a change leads eventually to the disruption of the order.
We develop a Monte Carlo framework to analyze the statistics of quantum work in correlated electron systems. Using the Ising-Kondo model in heavy fermions as a paradigmatic platform, we thoroughly illustrate the process of determining the moment generating function of quantum work under nonequilibrium conditions in detail. Based on this function, we systematically investigate essential statistical quantities, including the mean irreversible work density, the mean work density, variance, and the third central moment of quantum work across different quench processes. Our findings highlight distinct singularities in these quantities at the metal-insulator phase transition point at low temperatures. However, these singularities disappear, and the transition becomes a smooth crossover at high temperatures. This stark contrast underscores quantum work as an effective thermodynamic tool for identifying metal-insulator phase transitions. Our approach provides a promising new framework for investigating nonequilibrium quantum thermodynamics in strongly correlated electron systems.
We study three aspects of work statistics in the context of the fluctuation theorem for quantum spin chains up to 1024 sites by numerical methods based on matrix-product states (MPSs). First, we use our numerical method to evaluate the moments/cumulants of work done by the sudden quench process on the Ising or Haldane spin chains, and we study their behaviors across the quantum phase transitions. Our results show that, up to the fourth cumulant, the work statistics can indicate the quantum phase transition characterized by the local order parameters but barely for purely topological phase transitions. Second, we propose to use the fluctuation theorem, such as Jarzynski's equality, which relates the real-time correlator to the ratio of the thermal partition functions, as a benchmark indicator for the numerical real-time evolving methods. Third, we study the passivity of ground and thermal states of quantum spin chains under some cyclic impulse processes. We show that the passivity of thermal states and ground states under the Hermitian actions is ensured by the second laws and variational principles, respectively, and we also verify this by numerical calculations. In addition, we also consider the passivity of ground states under non-Hermitian actions, for which the variational principle cannot be applied. Despite that, we find no violation of passivity from our numerical results for all the cases considered in the Ising and Haldane chains. Overall, we demonstrate that the work statistics for the sudden quench and impulse processes can be evaluated precisely by the numerical MPS method to characterize quantum phase transitions and examine the passivity of quantum states. We also propose to exploit the universality of the fluctuation theorem to benchmark the numerical real-time evolutions in an algorithmic and model-independent way. Published by the American Physical Society 2024
We examine how the presence of an excited-state quantum phase transition manifests in the dynamics of a many-body system subject to a sudden quench. Focusing on the Lipkin-Meshkov-Glick model initialized in the ground state of the ferromagnetic phase, we demonstrate that the work probability distribution displays non-Gaussian behavior for quenches in the vicinity of the excited-state critical point. Furthermore, we show that the entropy of the diagonal ensemble is highly susceptible to critical regions, making it a robust and practical indicator of the associated spectral characteristics. We assess the role that symmetry breaking has on the ensuing dynamics, highlighting that its effect is only present for quenches beyond the critical point. Finally, we show that similar features persist when the system is initialized in an excited state and briefly explore the behavior for initial states in the paramagnetic phase.