Entropy

The Group-Algebraic Formalism of Quantum Probability and Its Applications in Quantum Statistical Mechanics

Yan Gu, Jiao Wang

Published Jan 10, 2025• 0 citations

Abstract

We show that the theory of quantum statistical mechanics is a special model in the framework of the quantum probability theory developed by mathematicians, by extending the characteristic function in the classical probability theory to the quantum probability theory. As dynamical variables of a quantum system must respect certain commutation relations, we take the group generated by a Lie algebra constructed with these commutation relations as the bridge, so that the classical characteristic function defined in a Euclidean space is transformed to a normalized, non-negative definite function defined in this group. Indeed, on the quantum side, this group-theoretical characteristic function is equivalent to the density matrix; hence, it can be adopted to represent the state of a quantum ensemble. It is also found that this new representation may have significant advantages in applications. As two examples, we show its effectiveness and convenience in solving the quantum-optical master equation for a harmonic oscillator coupled with its thermal environment, and in simulating the quantum cat map, a paradigmatic model for quantum chaos. Other related issues are reviewed and discussed as well.

DOI: 10.3390/e27010059

Related papers

Quantum statistical mechanics, quantum probability and quantum characteristic function

Yan Gu

The theory of quantum statistical mechanics is reviewed in the light of the quantum probability theory developed in recent years by mathematicians. We show that—which is our main motivation here—the former is a special model in the framework of the latter, by extending the characteristic function in the classical probability theory to the quantum probability theory based on the requirements of quantum statistical mechanics. We find that due to the fact that fundamental dynamical variables of a quantum system must respect certain commutation relations, one has to reform the classical characteristic function defined on a Euclidean space to a normalized, nonnegative definite function defined on a group which is generated by a Lie algebra formed from these commutation relations. Our key finding is that the group-theoretical characteristic function could be adopted to replace the density matrix commonly used in quantum statistical mechanics for representing a state of the quantum ensemble, and more than that, the new representation has some significant advantages in applications. To show its advantages compared with the conventional density matrix scenario, we illustrate its applications in: solving the master equation that describes the irreversible evolution of a quantum open system; determining the pointer states of a quantum open system; and expanding the density matrix with the pointer states. In particular, thanks to the quantum characteristic function, we are able to write down the solutions of the quantum-optical master equation explicitly, obtain its steady solutions and verify that the pointer states are exactly coherent states. Besides, the Caldeira-Leggett master equation for the quantum Brownian motion and its extension to the Lindblad type are also studied.

Zhongguo kexue. Wulixue Lixue TianwenxueApr 20, 20203 citations

Probability Representation of Quantum States

Olga V. Man’ko, Vladimir I. Man’ko

The review of new formulation of conventional quantum mechanics where the quantum states are identified with probability distributions is presented. The invertible map of density operators and wave functions onto the probability distributions describing the quantum states in quantum mechanics is constructed both for systems with continuous variables and systems with discrete variables by using the Born's rule and recently suggested method of dequantizer-quantizer operators. Examples of discussed probability representations of qubits (spin-1/2, two-level atoms), harmonic oscillator and free particle are studied in detail. Schrödinger and von Neumann equations, as well as equations for the evolution of open systems, are written in the form of linear classical-like equations for the probability distributions determining the quantum system states. Relations to phase-space representation of quantum states (Wigner functions) with quantum tomography and classical mechanics are elucidated.

EntropyApr 29, 202143 citations

Phase Space Methods

Alessio Serafini

The language of statistical moments and covariance matrices we introduced in the previous chapter offers a compact and efficient formalism to deal with Gaussian states. A much more general approach may be taken to describe any quantum state in a setting which is reminiscent of classical phase space. This is the framework of quantum characteristic functions and quasi-probability distributions, which goes back to seminal work by Wigner on quantum corrections to classical statistical mechanics, and bloomed in the sixties with the rise of theoretical quantum optics and the emergence of a general unifying picture. Conceptually, the phase space description of quantum states hinges on the completeness of the set of displacement operators, which we shall prove in the form of the Fourier–Weyl relation between density matrices and characteristic functions. This relationship will constitute the bridge between phase space and Hilbert space descriptions, which will be useful in several applications in the context of quantum information. It will be convenient to handle most of the proofs and mathematical arguments concerning characteristic functions and quasi-probability distributions on a single mode of the system. Because displacement operators of multimode systems are just tensor products of local displacement operators, the extension of the formalism to systems with many degrees of freedom will be straightforward. Nevertheless, we shall always take care of explicitly linking the single-mode formulae which will appear in this chapter to the general multimode description adopted in the previous one.

CRC Press eBooksJun 1, 20230 citations

From probabilistic mechanics to quantum theory

U. Klein

We show that quantum theory (QT) is a substructure of classical probabilistic physics. The central quantity of the classical theory is Hamilton’s function, which determines canonical equations, a corresponding flow, and a Liouville equation for a probability density. We extend this theory in two respects: (1) The same structure is defined for arbitrary observables. Thus, we have all of the above entities generated not only by Hamilton’s function but also by every observable. (2) We introduce for each observable a phase space function representing the classical action. This is a redundant quantity in a classical context but indispensable for the transition to QT. The basic equations of the resulting theory take a “quantum-like” form, which allows for a simple derivation of QT by means of a projection to configuration space reported previously [Quantum Stud Math Found 5:219–227, 2018]. We obtain the most important relations of QT, namely the form of operators, Schrödinger’s equation, eigenvalue equations, commutation relations, expectation values, and Born’s rule. Implications for the interpretation of QT are discussed, as well as an alternative projection method allowing for a derivation of spin.

arXiv:1907.08513Quantum Studies Mathematics and FoundationsAug 29, 20199 citations

Probability Representation of Quantum Mechanics Where System States Are Identified with Probability Distributions

Vladimir N. Chernega, Olga V. Man’ko, Vladimir I. Man’ko

The probability representation of quantum mechanics where the system states are identified with fair probability distributions is reviewed for systems with continuous variables (the example of the oscillator) and discrete variables (the example of the qubit). The relation for the evolution of the probability distributions which determine quantum states with the Feynman path integral is found. The time-dependent phase of the wave function is related to the time-dependent probability distribution which determines the density matrix. The formal classical-like random variables associated with quantum observables for qubit systems are considered, and the connection of the statistics of the quantum observables with the classical statistics of the random variables is discussed.

Quantum ReportsJan 21, 20205 citations

Algebraic Quantum Statistical Mechanics and Bose-Einstein Condensation

Kalle Matias Koskinen

This thesis can be regarded as a light, but thorough, introduction to the algebraic approach to quantum statistical mechanics and a subsequent test of this framework in the form of an application to Bose-Einstein condensates. The success of the algebraic approach to quantum statistical mechanics hinges upon the remarkable properties of special operator algebras known as C^*-algebras. These algebras have unique characterization properties which allows one to readily identify the mathematical counterparts of concepts in physics while at the same time maintaining mathematical rigour and clarity. In the first half of this thesis, we focus on abstract C^*-algebras known as the canonical commutation relation algebras (CCR algebras) which are generated by elements satisfying specific commutation relations. The main result in this section is the proof of a certain kind of algebraic uniqueness of these algebras. The main idea of the proof is to utilise the underlying common structure of any of the CCR algebras and explicitly construct an isomorphism between the generators of these algebras. The construction of this isomorphism involves the use of abstract Fourier analysis on groups and various arguments concerning bounded operators. The second half of the thesis concerns the rigorous set-up of the formation of Bose-Einstein condensation. First, one defines the Gibbs grand canonical equilibrium states, and then we specialize to studying the taking of the thermodynamic limit of these systems in various contexts. The main result of this section involves two main elements. The first is that by fixing the temperature and density of the system while varying its activity and volume, there exists a limiting state corresponding to the taking of the thermodynamic limit. The second element concerns the existence of a critical density after which the limiting state begins to show the physical characteristics of Bose-Einstein condensation. The mathematical issues one faces with Bose-Einstein condensation are mainly related to the unboundedness of the creation and annihilation operators and the definition of the algebra that we are working on. The first issue is relevant to all areas of mathematical physics, and one deals with it in the standard ways. The second issue is more nuanced and is a direct result of the first issue we mentioned. In particular, we would like to define the states on an algebra which contains the operators that we are interested in. The problem is that these operators are unbounded, and, as a result, one must instead use the CCR algebra and show by extension that we can, in fact, also use the unbounded operators in this state.

Työväentutkimus VuosikirjaJan 1, 20180 citations