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Non-Integer order calculation applied in Quantum Mechanics: Particle in a one-dimensional finite well

Joel Elías Escudero-Gómez, Ernesto Alejandro Mendoza Álvarez, Guillermo Fernández‐Anaya, J.J. Flores-Godoy, Leo Diago Cisneros

Published Nov 28, 2024• 0 citations
Publisher

Abstract

Fractional calculus is becoming increasingly important nowadays in studying and understanding fundamental physical phenomena, both simple and complex, through the formulation of generalized models. In the present work, a treatment of non-integer order is developed for the study of the wave function that describes the accessible states of a one-dimensional particle confined in a finite well with finite and constant walls, using a conformable derivative in describing the temporal evolution of the states of the system and Caputo-Fabrizio fractional derivative in describing its spatial evolution. By plotting the complete fractional solution ψ(x,t) for given values ​​of the Kernel indices α, β, γ, we recover the flat-wave front oscillations predicted by the integer-order calculation, whose superposition represents the particle state with uniform probability in all space. However, for another range of values ​​of the indices of the integral transformation, damping effects are observed, which do not seem to have a quantum mechanical physical meaning in themselves, but they do have a special physical-mathematical interest since such effects are related to the nature of the Caputo-Fabrizio operator, which as a non-local operator saves memory, that is, non-local spatial effects entail long-range interactions in a physical region, so the generalized wave function obtained does not depend exclusively on a point in space but on a region of space. When calculating the probability density, the fractional wave function shows a definite parity when γ is unitary, just as expected for a symmetric potential well. The generalized model obtained by incorporating a greater number of free parameters can represent an appropriate alternative formulation in the description of the probabilistic behavior of simple and complex quantum mechanical systems. Palabras clave: Ecuación de Schrödinger fraccional; Derivada fraccionaria de Caputo, derivada fraccionaria de Caputo-Fabrizio, derivada general conformable de Khalil.

DOI
10.21640/ns.v16i33.3448

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Fractional calculus is becoming increasingly important nowadays in studying and understanding fundamental physical phenomena, both simple and complex, through the formulation of generalized models. In the present work, a treatment of non-integer order is developed for the study of the wave function that describes the accessible states of a one-dimensional particle confined in a finite well with finite and constant walls, using a conformable derivative in describing the temporal evolution of the states of the system and Caputo-Fabrizio fractional derivative in describing its spatial evolution. By plotting the complete fractional solution ψ(x,t) for given values ​​of the Kernel indices α, β, γ, we recover the flat-wave front oscillations predicted by the integer-order calculation, whose superposition represents the particle state with uniform probability in all space. However, for another range of values ​​of the indices of the integral transformation, damping effects are observed, which do not seem to have a quantum mechanical physical meaning in themselves, but they do have a special physical-mathematical interest since such effects are related to the nature of the Caputo-Fabrizio operator, which as a non-local operator saves memory, that is, non-local spatial effects entail long-range interactions in a physical region, so the generalized wave function obtained does not depend exclusively on a point in space but on a region of space. When calculating the probability density, the fractional wave function shows a definite parity when γ is unitary, just as expected for a symmetric potential well. The generalized model obtained by incorporating a greater number of free parameters can represent an appropriate alternative formulation in the description of the probabilistic behavior of simple and complex quantum mechanical systems. Palabras clave: Ecuación de Schrödinger fraccional; Derivada fraccionaria de Caputo, derivada fraccionaria de Caputo-Fabrizio, derivada general conformable de Khalil.
This study investigates the time-fractional Schrödinger equation (TFSE) for a free particle using the Caputo fractional derivative. The model extends the classical Schrödinger equation by incorporating memory effects through a non-integer order time derivative. By applying the Fourier transform method, an explicit solution is derived in terms of the Mittag–Leffler function, which generalizes the classical exponential evolution. The analysis reveals that the resulting dynamics are non-unitary, leading to a time-dependent total probability that deviates from the conservation property of standard quantum mechanics. Numerical illustrations demonstrate the influence of the fractional order ν on wave packet evolution and probability behavior. The results highlight the role of fractional calculus in modeling non-Markovian quantum systems and provide insight into the transition from fractional to classical dynamics as v→1. .
Background and Objective: In the context of the novel definition of the fractional derivative, we solve the Fractional Schrödinger equation based on the non-singular Caputo-Fabrizio derivative definition.The quantum particle is submitted to a step potential.We focus our study to find the reflection and transmission coefficients.Materials and Methods: To reach this goal, we first work out the fractional differential equation defined in terms of the Caputo-Fabrizio derivative.Results: Hence, according to the obtained wave functions of fractional Schrödinger equations, the reflection and transmission coefficient are calculated.Conclusion: Interestingly, our findings collapse to the standard results when the fractional order of derivative become integer numbers.
Abstract In this work, we examine the quantum information characteristics of a hydrogen-like system under a Coulomb potential by using previously derived exact solutions of the generalized Schrödinger equation formulated within the conformable fractional framework. The approach introduces a fractional parameter (0<α≤1)(0 < \alpha \le 1)(0<α≤1) ( 0 < α ≤ 1 ) , which permits a continuous transition between standard quantum mechanics and a fractional description. Utilizing these available analytical solutions, we determine the associated energy spectrum and wavefunctions and employ them to quantify the informational structure of the system. In particular, we calculate the Shannon entropy in both position and momentum spaces, along with the Fisher information, as fundamental indicators of uncertainty, spatial spreading, and sensitivity to local variations of the probability density. The results show that the fractional parameter (α)(\alpha )(α) ( α ) produces nontrivial corrections to these quantum information measures, indicating modifications in localization properties and momentum profiles. Also, the formalism recovers the conventional hydrogenic limit when (α→1)(\alpha \rightarrow 1)(α→1) ( α → 1 ) , which validates the consistency of the formulation. In this context, these results show that the conformable fractional framework constitutes a consistent extension for analyzing quantum systems via information-theoretic quantities without modifying the exact solutions, providing a systematic approach to investigate deviations from integer-order dynamics.
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The wave function is a fundamental concept in quantum mechanics, but its abstract nature makes it difficult for students to understand its behavior. Furthermore, it is the probabilistic nature of particles that makes direct observation of quantum wave dynamics impossible. Therefore, this research investigates the eigenstates, superposition, and the time-dependent probability density of a particle within an infinite potential well through theoretical analysis and computational visualization based on Streamlit. The research method combines analysis with mathematical calculations to obtain the eigenstates, calculate |Ψ|², the expected position value, and the phase evolution of the superposition state. The visualizations illustrate the relationship between the wave function and quantum numbers, as well as interference patterns and time-dependent behavior. The visualization results show how the method represents theoretical concepts related to the probabilistic nature of particles. This research shows that theoretical analysis combined with interactive visualization provides an interactive representation that may facilitate students’ understanding of quantum mechanics concepts, a potential that still requires empirical validation through classroom-based studies. Unlike existing closed-source quantum applets, the Quantum Probability Explorer is fully open-source and directly couples the analytical solution of the Schrödinger equation with real-time interactive visualization of eigenstates and superposition, which constitutes the novelty of this study.
We propose and investigate a generalized Schrödinger equation by introducing a fractional Riesz derivative to account for anomalous transport and a memory kernel to describe temporal nonlocal effects. Additionally, we include a long-range interactions term, modeled by an integral operator, which captures spatially extended interactions. Using the Green function approach, we derive analytical solutions and explore their implications in the time-space domain. Our findings reveal novel quantum phenomena arising from the interplay of fractional dynamics, nonlocal potentials, and memory effects, including the emergence of new local maxima in the evolution of Green's functions and distinct localization behaviors.