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Classical and Quantum Boltzmann Equations in the Presence of Bath Noise With Quantum Filtering Applied to Scattered Field Analysis

Harish Parthasarathy

Published Oct 16, 2024• 0 citations
Publisher

Abstract

We formulate the classical and quantum Boltzmann equations for the one particle distribution function and density operator corresponding to the motion of several indistinguisable point charges in motion with mutual electromagnetic interaction attached to central potentials and also interacting with an external electromagnetic field. These equations are used to derive formulas for the scattered electromagnetic field and analyze their properties like frequency content. Using the Wigner distribution to draw an analogy between classical probability distribution functions in phase space and corresponding quantum analogues, we compare the classical and quantum Boltzmann equations showing explicitly how the quantum Boltzmann equation for the Wigner distribution is the same as the classical Boltzmann equation but with extra quantum corrections expressible as a power series in Planck’c constant. We then proceed to formulate the quantum Boltzmann equation for open quantum systems, ie, systems connected to a noisy bath and explain how to estimate the Lindblad noisy coupling parameters from the nonlinear quantum Boltzmann state evolution between successive POV measurements. We then proceed to formulate the quantum Boltzmann equation for the one particle density operator derived from the quantum Belavkin filter for N-particles taking into account non-demolition measurement noise. Partial tracing of the Belavkin filter with the molecular chaos hypothesis for the N-particle state yields this nonlinear one particle filtered quantum Boltzmann equation. We then apply Lec-Bouten’s method of control unitaries based on the measurement process to cancel out part of Lindblad noise from the filtered quantum Boltzmann equation. Finally, we explain how to perform a second order perturbative analysis of the classical Boltzmann equation in order to arrive at the frequency spectrum of the scattered field from the frequency spectrum of the incident field. The last section is devoted to the derivation of the two particle quantum Boltzmann equation for the Belavkin quantum filter. During the process of derivation, we explain how to derive the general \(r^{th}\) order quantum Boltzmann equation for the Belavkin quantum filter on \(N\) particles when the bath acts symmetrically, ie, in a permutation invariant way on all the particles.

DOI
10.32388/4qmm4s

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We formulate the classical and quantum Boltzmann equations for the one particle distribution function and density operator corresponding to the motion of several indistinguisable point charges in motion with mutual electromagnetic interaction attached to central potentials and also interacting with an external electromagnetic field. These equations are used to derive formulas for the scattered electromagnetic field and analyze their properties like frequency content. Using the Wigner distribution to draw an analogy between classical probability distribution functions in phase space and corresponding quantum analogues, we compare the classical and quantum Boltzmann equations showing explicitly how the quantum Boltzmann equation for the Wigner distribution is the same as the classical Boltzmann equation but with extra quantum corrections expressible as a power series in Planck’c constant. We then proceed to formulate the quantum Boltzmann equation for open quantum systems, ie, systems connected to a noisy bath and explain how to estimate the Lindblad noisy coupling parameters from the nonlinear quantum Boltzmann state evolution between successive POV measurements. We then proceed to formulate the quantum Boltzmann equation for the one particle density operator derived from the quantum Belavkin filter for N-particles taking into account non-demolition measurement noise. Partial tracing of the Belavkin filter with the molecular chaos hypothesis for the N-particle state yields this nonlinear one particle filtered quantum Boltzmann equation. We then apply Lec-Bouten’s method of control unitaries based on the measurement process to cancel out part of Lindblad noise from the filtered quantum Boltzmann equation. Finally, we explain how to perform a second order perturbative analysis of the classical Boltzmann equation in order to arrive at the frequency spectrum of the scattered field from the frequency spectrum of the incident field. The last section is devoted to the derivation of the two particle quantum Boltzmann equation for the Belavkin quantum filter. During the process of derivation, we explain how to derive the general (r^{th}) order quantum Boltzmann equation for the Belavkin quantum filter on (N) particles when the bath acts symmetrically, ie, in a permutation invariant way on all the particles.
This paper explores some of the applications of quantum stochastic calculus (qsc) as founded by R.L.Hudson and K.R.Parthasarathy and the theory of the quantum filter established by V.P.Belavkin based on qsc which was simplified considerably by John Gough, Claude Kostler and others to quantum field theory. Specifically, we first derive some general versions of the Belavkin quantum filter for the case when the Hamiltonian and Lindblad operators in the Hudson-Parthasarathy noisy Schrodinger equation (HPSDE) are functions of a classical Markovian time varying parameter process whose statistics is determined by an infinitesimal generator. Using this generalized Belavkin filter, we show how we can estimate on real time basis not only the evolving mixed state of the system but also the probability density of the Markovian parameter. Our generalized filter enables us to obtain a function ρ(t,θ)\rho{(t,\theta)}ρ(t,θ) that represents an estimate of the state of the quantum system at time ttt as well as the probability density of the parameter θ\thetaθ at time ttt. Specifically, when X(θ)=∑k=1nfk(θ)Xk{X{(\theta)}} = {\sum_{k = 1}^{n}{f_{k}{(\theta)}X_{k}}}X(θ)=∑k=1n​fk​(θ)Xk​ is a system observable dependent upon the Markovian θ\thetaθ, then, ∫Tr(ρ(t,θ)X(θ))dθ\int{Tr{({\rho{(t,\theta)}X{(\theta)}})}{d\theta}}∫Tr(ρ(t,θ)X(θ))dθ would represent the conditional expectation of X(t,θ(t))=U(t)∗X(θ(t))U(t){X{(t,{\theta{(t)}})}} = {U{(t)}^{\ast}X{({\theta{(t)}})}U{(t)}}X(t,θ(t))=U(t)∗X(θ(t))U(t) given non-demolition measurements at time tttThis paper explores some of the applications of quantum stochastic calculus (qsc) as founded by R.L.Hudson and K.R.Parthasarathy and the theory of the quantum filter established by V.P.Belavkin based on qsc which was simplified considerably by John Gough, Claude Kostler and others to quantum field theory. Specifically, we first derive some general versions of the Belavkin quantum filter for the case when the Hamiltonian and Lindblad operators in the Hudson-Parthasarathy noisy Schrodinger equation (HPSDE) are functions of a classical Markovian time varying parameter process whose statistics is determined by an infinitesimal generator. Using this generalized Belavkin filter, we show how we can estimate on real time basis not only the evolving mixed state of the system but also the probability density of the Markovian parameter. Our generalized filter enables us to obtain a function ρ(t,θ)\rho{(t,\theta)}ρ(t,θ) that represents an estimate of the state of the quantum system at time ttt as well as the probability density of the parameter θ\thetaθ at time ttt. Specifically, when X(θ)=∑k=1nfk(θ)Xk{X{(\theta)}} = {\sum_{k = 1}^{n}{f_{k}{(\theta)}X_{k}}}X(θ)=∑k=1n​fk​(θ)Xk​ is a system observable dependent upon the Markovian θ\thetaθ, then, ∫Tr(ρ(t,θ)X(θ))dθ\int{Tr{({\rho{(t,\theta)}X{(\theta)}})}{d\theta}}∫Tr(ρ(t,θ)X(θ))dθ would represent the conditional expectation of X(t,θ(t))=U(t)∗X(θ(t))U(t){X{(t,{\theta{(t)}})}} = {U{(t)}^{\ast}X{({\theta{(t)}})}U{(t)}}X(t,θ(t))=U(t)∗X(θ(t))U(t) given non-demolition measurements at time ttt. After that, we show how the Weyl-Moyal-Wigner transform can be used to formulate noisy quantum evolutions as well as Belavkin filter equations in a classical language wherein intepretations of quantum observables and states are given in terms of classical complex functions of positions and momenta. Marginals of the Wigner distribution of the state for example represent probabiity densities of positions and momenta but the Wigner distribution of the state does not represent any joint probability density of the positions and momenta, indeed the Heisenberg uncertainty does not allow any such interpretation. We then illustrate how a quantum mechanical theory taking into account quantum noise can be constructed in a natural way by perturbing the electromagnetic field with quantum super-symmetric noise introducing even and odd system operators. We explain how the interaction between the matter supercurrent and the metric superfield in supergravity theories can be perturbed by quantum noise by adding supersymmetric quantum noise to the matter supercurrent. Further, with the hope that Feynman path integrals can be used in quantum noisy field theories to evaluate transition amplitudes of scattering, we propose a Feynnman path integral approach to the solution of the HPQSDE when the system can be described by canonical position and momentum operators. We then describe quantum scattering in the presence of quantum noise in the HPQSDE framework. Here either one or both of the Hamiltonians contains noise and the corresponding joint unitary evolution of system and bath is described by a HPQSDE and we illustrate some methods for computing the scattering wave operators and analyzing their existence using standard quantum scattering inequalities. Finally, we develop some formulae for computing the rate of change of Von-Neumann entropy of the Belavkin filtered quantum state based on combining Lie algebraic methods for evaluating the differential of the matrix exponential map with Ito’s formula for Brownian motion, Poisson and Levy processes and even for Martingales. These formulae that describe rate of entropy increase have potential applications to quantum information and quantum commmunication when we require to measure how much information has been transmitted as a function of time across a quantum channel after filtering out the noise on a real time basis. In the context of quantum communication theory, we illustrate the situation of an optical fibre wherein the information carrying quantum electromagnetic field interacts with a classical electromagnetic field that has been scattered by the phonon lattice and hence contains unknown Markovian parameters. By estimating the Markovian paremeters using our generalized Belvakin filter on a real time basis, we are therefore able to generate a counter Hamiltonian via causing a simulated counter classical field using this estimated parameter to interact with the propagating quantum field and hence mitigate the effect of the interaction of the classical field with the quantum field. One of the novel results of this paper is the exact representation of the Weyl-Moyal-Wigner transform of products of quantum operators that includes Lie brackets between operators to all orders in Planck’s constant. We use this idea to obtain a classical representation of the quantum Boltzmann equation in terms of Wigner densities that are complex valued functions of position and momenta representing the system state. Future work on Wigner transforming the quantum Boltzmann equation for all r-particle marginal states of an N-particle system is in progress. Work on interpreting the Belavkin filter and quantum Boltzmann equation in the Wigner domain in terms of corrections to the classical Fujisaki-Kushner-Kallianpur stochastic filter and the classical Boltzmann equation is also in progress.
We develop a Bayesian formulation of diffusive quantum-classical dynamics by treating the wave function and classical variables as components of an ordinary stochastic process. The joint probability density P(psi,x,t) obeys a classical Fokker-Planck equation, while the quantum state appears as its second moment. Requiring autonomous second-moment evolution and trace preservation, together with a full-column-rank quantum-classical noise correlation matrix, forces the ensemble dynamics into hybrid Lindblad form. The same result also determines the general class of diffusive stochastic unravelings compatible with this hybrid evolution. Notably, this construction makes positivity immediate and does not take complete positivity or an underlying unitary quantum dilation as assumptions, but instead relies on the presence of a sufficiently coupled classical sector. We formulate quantum measurement, filtering and smoothing of hybrid quantum-classical dynamics as standard Bayesian inference and show how to correlation between the quantum and classical noise fully explains the differences between quantum smoothing and smoothing in classical time series models. We recover the stochastic master equation from the Kushner-Stratonovich equation with correlated noise and show how the quantum effect operator is related to the Bayesian backward message through the adjoint dynamics of the linear unraveling. The Bayesian posterior also defines a smoothed density matrix and, more generally, a posterior distribution over latent quantum-classical trajectories. These quantities can be approximated with standard particle filtering and smoothing methods. Numerical examples show that smoothing improves reconstruction of a hidden quantum-classical trajectory and that the full trajectory posterior can retain structure, such as multimodality, that is absent from its density-matrix second moment.
The quantum Boltzmann equation (QBE), originally formulated as the quantum extension of Boltzmann’s classical transport theory by Uehling and Uhlenbeck and subsequently developed within the nonequilibrium Green-function formalisms of Kadanoff–Baym and Keldysh, provides the central kinetic framework for describing relaxation and transport in weakly interacting quantum many-body systems. Although its formal structure is well established, conventional derivations often obscure the microscopic equivalence between operator and nonequilibrium Green-function approaches. Wick factorization is typically applied without explicitly enumerating real-time contractions, while Green-function treatments encode the same physics in Born-level self-energies that conceal their operator origin. In this paper, we present a pedagogical microscopic derivation of the quantum Boltzmann equation that makes this equivalence fully explicit. Starting from the ladder-operator formulation, we enumerate all fifteen Wick pairings of the second-order six-field correlator, identifying three Hartree–Fock contributions and twelve real-time Born scattering channels generated by a quartic, number-conserving interaction Hamiltonian. We then establish a one-to-one correspondence between these twelve operator contractions and the Keldysh components of the second-order Born self-energy, demonstrating explicitly how the Uehling–Uhlenbeck collision integral emerges after Wigner transformation and quasiparticle projection. Under controlled Born–Markov and quasiparticle approximations, this work offers a transparent synthesis of operator and Green-function formulations, and clarifies how kinetic fluctuations can be understood as emergent under coarse-graining.
Open quantum systems play a central role in contemporary nanoscale technologies, including molecular electronics, quantum heat engines, quantum computation and information processing. A major theoretical challenge is to construct dynamical models that are simultaneously consistent with classical thermodynamics and complete positivity. In this work, we develop a framework that addresses this issue by extending classical stochastic dynamics to the quantum domain. We begin by formulating a generalized Langevin equation in which both friction and noise act symmetrically on the two Hamiltonian equations. From this, we derive a generalized Klein-Kramers equation expressed in terms of Poisson brackets, and we show that it admits the Boltzmann distribution as its stationary solution while satisfying the first and second laws of thermodynamics along individual trajectories. Applying canonical quantization to this classical framework yields two distinct quantum master equations, depending on whether the friction operators are taken to be Hermitian or non-Hermitian. By analyzing the dynamics of a harmonic oscillator, we determine the conditions under which these equations reduce to a Lindblad-type generator. Our results demonstrate that complete positivity is ensured only when friction and noise are included in both Hamiltonian equations, thus fully justifying the classical construction. Moreover, we find that the friction coefficients must satisfy the same positivity condition in both the Hermitian and non-Hermitian formulations, revealing a form of universality that transcends the specific operator representation. The formalism offers a versatile tool for deriving quantum versions of the thermodynamic laws and is directly applicable to a wide class of nonequilibrium nanoscale systems.
In this paper, we first derive the discrete time recursive stochastic filtering equations for a classical Markov process when noisy measurements of the process are made with the measurement noise at each discrete sample forms an iid Gaussian or non-Gaussian process. The filter involves deriving general formulae for the conditional mean process given measurements up to that time and also simultaneously recursive formulae for the conditional moments of the estimation error process. In the next section, we build upon the method of John Gough et al., to construct a supersymmetric quantum stochastic filter, i.e. the supersymmetric Belavkin filter. The construction of supersymmetric noise in the Hudson–Parthasarathy noisy Schrödinger equation is based on constructing Fermionic noise by applying a twist to Bosonic noise, i.e. [Formula: see text]. Such a Fermionic noise has memory unlike the Bosonic noise and satisfies the Canonical Anti-commutation Relations (CAR). We prove that when a superposition of Bosonic quantum Brownian motion and Bosonic counting process along with Fermionic counting process is measured through the Hudson–Parthasarathy noisy Schrödinger system with both Bosonic and supersymmetric noise, then it satisfies the non-demolition property and hence conditional expectations can be defined. The construction of the quantum filter here involves taking into consideration all the positive integer powers of the output measurement noise differential and we give an algorithm for computing these powers based on the quantum Ito’s formula. The method for deriving a countably infinite number of linear equations for the filter coefficients is based on the reference probability method of Gough et al. The method of constructing supersymmetric noise for driving the HPS equation is based on the work of Timothy Eyre. The main result of this paper is to derive an infinite system of linear equations for the quantum filter coefficients thereby yielding a real-time implementable filter for estimating system observables or equivalently, the system mixed state from the most general form of non-demolition measurements comprising Bosonic continuous and counting noise plus Fermionic counting noise.
Abstract Open quantum systems play a central role in current nanoscale technologies, such as molecular electronics, quantum heat engines, quantum computation and information processing. A major theoretical challenge is to construct dynamical models that are simultaneously consistent with classical thermodynamics and with the requirement of complete positivity of quantum evolution. In this work we develop a framework that addresses this issue by systematically extending classical stochastic dynamics to the quantum domain. We begin by formulating a generalized Langevin equation in which both friction and noise act symmetrically on the two Hamiltonian equations. From this, we derive a generalized Klein–Kramers equation expressed in terms of Poisson brackets, and we show that it admits the Boltzmann distribution as its stationary solution while fulfilling the first and second laws of thermodynamics along individual trajectories. Applying canonical quantization to this classical framework yields two distinct quantum master equations, depending on whether the friction operators are taken to be Hermitian or non-Hermitian. By analyzing the dynamics of a harmonic oscillator, we determine the conditions under which these equations reduce to a Lindblad-type generator. Our results demonstrate that complete positivity is ensured only when friction and noise are included in both Hamiltonian equations, fully justifying the classical construction. Moreover, we find that the friction coefficients must adhere to the same positivity condition in both the Hermitian and non-Hermitian formulations, revealing a form of universality that transcends the specific operator representation. The formalism developed here presents a thermodynamically consistent and completely positive quantum extension of classical stochastic mechanics. It offers a versatile tool for deriving quantum versions of thermodynamic laws and is directly applicable to a broad class of non-equilibrium nanoscale systems of current theoretical and technological interest.