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Institute of Physics eBooks

Elements of quantum theory

Giuseppe Di Molfetta

Published Sep 1, 2024• 1 citation
Publisher

Abstract

In this chapter we will expose the fundamental principles of quantum mechanics alongside the mathematical formalism on which they are grounded, which is that of Hilbert spaces. In particular we will briefly present the necessary fundamentals of linear algebra, including the definitions of vector spaces, of scalar and tensorial products, and the definition of linear operators.

DOI
10.1088/978-0-7503-5744-9ch2

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In this chapter we will expose the fundamental principles of quantum mechanics alongside the mathematical formalism on which they are grounded, which is that of Hilbert spaces. In particular we will briefly present the necessary fundamentals of linear algebra, including the definitions of vector spaces, of scalar and tensorial products, and the definition of linear operators.
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This chapter provides a simple general introduction to some basic mathematics necessary for a subsequent discussion of Lie algebras, operator methods, and their applications to theoretical physics and chemistry. It also provides some useful mathematical tools to derive important theoretical results and expressions in a simple and elegant way. In quantum mechanics the state of a system is represented by an element of a particular vector space, in which one defines an appropriate scalar or inner product, known in mathematics as Hilbert space. Hermitian operators with a complete set of eigenvectors belonging to that state space represent physical observables. Moreover, in certain cases it proves useful to work with vector spaces formed by linear operators. Hermitian operators are particular cases of linear operators and physical observables are particular cases of Hermitian operators. In many physical applications of operator methods one needs to reorder products of exponential operators or to rewrite one such operator as a product of simpler ones.
Abstract Mathematical formalism of quantum mechanics is closely connected with the theory of linear operators. A key quantum-mechanical principle is that physical quantities (observables) are represented by Hermitian linear operators that act on state vectors that belong to a Hilbert vector space. This chapter analyzes problems that deal with the basic concepts of the theory of linear operators; eigenfunctions, eigenvalues, mean values; the projection operators; quantum-mechanical representations of operators and wave-functions; and unitary operators.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
Abstract Quantum mechanics is written in the language of linear algebra. On the Schrodinger picture the theory represents quantum-mechanical states using the elements of a Hilbert space and represents observable physical properties and the standard dynamics using the linear operators on the state space. We consider the mathematical notions for understanding and working with the standard formulation of quantum mechanics. Each mathematical notion is characterized geometrically, algebraically, and physically. The mathematical representation of quantum-mechanical superpositions is discussed.
This chapter, based on the background information of the previous chapter, will review the formalism of quantum mechanics – its fundamental mathematical structure (the basic contents of Hilbert space representation and operator algebra representation) and physical assumptions (kinematics, dynamics, and measurement theory). These are the premise and foundation for discussing the quantum histories interpretation. Then, in combination with the viewpoints of some literature in recent years, we will explore what is the interpretation of quantum mechanics, analyze the relationship between the theory of quantum mechanics and its interpretation, and declare the author’s basic stance on these two issues. These two are the primary issues that all interpretive work in the philosophy of physics will face (not limited to the interpretation of quantum mechanics), and the necessary clarification here is also conducive to the subsequent discussion. Three common terms – theory, formalism, and interpretation – are explicated and differentiated by offering the necessary definitions of their meanings, based on the works of Acuña and Ruetsche. The clarification will help to make the subsequent related discussions more precise.