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Annals of Physics

Effective description of a quantum particle constrained to a catenoid

Guillermo Chacón‐Acosta, Héctor H. Hernández, J. Ruvalcaba-Rascón

Published May 23, 2024• 3 citations
Publisher
DOI
10.1016/j.aop.2024.169695

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Since electrons in a ballistic regime perceive a carbon nanotube or a graphene layer structure as a continuous medium, we can use the study of the quantum dynamics of one electron constrained to a curve or surface to obtain a qualitative description of the conduction electrons' behavior. The confinement process of a quantum particle to a curve or surface leads us, in the so-called da Costa's approach, to a geometry-induced potential (GIP) in the effective Schr\odinger equation. With these considerations, this work aims to study in detail the consequences of constraining a quantum particle to a helix, catenary, helicoid, or catenoid, exploring the relations between these curves and surfaces using differential geometry. Initially, we use the variational method to estimate the energy of the particle in its ground state, and then, we obtain better approximations with the use of the confluent Heun function through numerical calculations. Thus, we conclude that a quantum particle constrained to an infinite helix has its angular momentum quantized due to the geometry of the curve, while in the cases of the catenary, helicoid, and catenoid the particle can be found either in a single bound state or in excited states which constitute a continuous energy band.
We develop a semiclassical framework for studying quantum particles constrained to curved surfaces using the momentous quantum mechanics formalism, which extends classical phase-space to include quantum fluctuation variables (moments). In a spherical geometry, we derive quantum-corrected Hamiltonians and trajectories that incorporate quantum back-reaction effects absent in classical descriptions. For the free particle, quantum fluctuations induce measurable phase shifts in azimuthal precession of approximately 8-12%, with uncertainty growth rates proportional to initial moment correlations. When a non-central Makarov potential is introduced, quantum corrections dramatically amplify its asymmetry. For strong coupling (γγγ = -1.9), the quantum-corrected force drives trajectories preferentially toward the southern hemisphere on timescales 40% shorter than classical predictions, with trajectory densities exhibiting up to 3-fold enhancement in the preferred region. Throughout evolution, the solutions rigorously satisfy Heisenberg uncertainty relations, validating the truncation scheme. These results demonstrate that quantum effects fundamentally alter semiclassical dynamics in curved constrained systems, with direct implications for charge transport in carbon nanostructures, exciton dynamics in curved quantum wells, and reaction pathways in cyclic molecules.