This chapter presents some basic calculations that show counterintuitive or unexpected results. First, it is shown that the Planck spectrum of light, which played an important role in the history of quantum mechanics, doesn’t say anything about the existence of indivisible particles. Second, a brief discussion of “chaos theory” shows that jumpy and unpredictable behavior can occur in classical systems. Last, the concept of “entanglement” is introduced as a basic property of quantum systems.
This chapter presents some basic calculations that show counterintuitive or unexpected results. First, it is shown that the Planck spectrum of light, which played an important role in the history of quantum mechanics, doesn’t say anything about the existence of indivisible particles. Second, a brief discussion of “chaos theory” shows that jumpy and unpredictable behavior can occur in classical systems. Last, the concept of “entanglement” is introduced as a basic property of quantum systems.
This chapter begins with a survey of early experimental results — the Planck spectrum, the photoelectric effect, and Compton scattering — that are usually presented as evidence for the existence of photons. The photon concept is indeed sufficient to explain these results, but it is not necessary. There are semi-classical models that explain the same data without introducing photons. The crucial experiment, in which light consisting of a single photon reflects from a beam splitter, depends on the essential indivisibility of photons, and it excludes all semi-classical descriptions of light. This discussion is followed by a preview of modern methods of production and detection of individual photons, e.g., spontaneous down conversion and Silicon avalanche-photodiode counters, together with an introduction to the quantum theory of light based on the correspondence principle.
Classical mechanics and quantum mechanics are two of the most successful scientific theories ever discovered, and yet how they can describe the same world is far from clear: one theory is deterministic, the other indeterministic; one theory describes a world in which chaos is pervasive, the other a world in which chaos is absent. Focusing on the exciting field of 'quantum chaos', this book reveals that there is a subtle and complex relation between classical and quantum mechanics. It challenges the received view that classical and quantum mechanics are incommensurable, and revives another, largely forgotten tradition due to Niels Bohr and Paul Dirac. By artfully weaving together considerations from the history of science, philosophy of science, and contemporary physics, this book offers a new way of thinking about intertheory relations and scientific explanation. It will be of particular interest to historians and philosophers of science, philosophically-inclined physicists, and interested non-specialists.
The first objective of this chapter is to briefly review some of the basic ideas about the structure of matter, in particular the concepts of microscopic physics, in order to recall the knowledge gained in previous physics (and chemistry) courses and make it more precise. Our review will be very concise, and most statements will be made without any proof or detailed discussion. A second objective is to give a brief description of some of the crucial stages in the early development of quantum physics. We shall not follow the strict historical order of this development or present the arguments used at the beginning of the last century by the founding fathers of quantum mechanics; rather, we shall stress the concepts which we shall find useful later on. Our last objective is to give an elementary introduction to some of the basic ideas, like those of a quantum particle or energy level, that will reappear throughout this text. We shall base our review on the Bohr theory, which provides a simple, though far from convincing, explanation of how energy levels are quantized and how the spectrum of the hydrogen atom arises. This chapter should be reread later on, once the basic ideas of quantum mechanics have been made explicit and illustrated by examples. From the practical point of view, it is possible to skip the general considerations of Sections 1.1 and 1.2 at the first reading and begin with Section 1.3, returning to those two sections later on as needed.
This chapter introduces quantum mechanics through the experimental discoveries that revealed the limits of classical physics. Beginning with the historical debate over whether light is a wave or a particle, it examines Young’s double-slit experiment and its modern single-particle versions, which demonstrate that quantum objects can exist in superpositions of mutually exclusive states. The chapter explains how interference arises when alternative possibilities are not measured and how interaction with the environment suppresses these effects through decoherence, giving rise to classical behavior at macroscopic scales. A sequence of thought experiments involving interferometers and Stern–Gerlach devices highlights the counterintuitive structure of quantum measurement and the incompatibility of certain physical properties, as captured by the uncertainty principle. The chapter emphasizes that quantum mechanics does not describe particles taking multiple paths simultaneously in a classical sense but rather requires a new framework for probability based on amplitudes and interference. Finally, the discussion connects these foundational ideas to emerging technologies such as quantum computing, showing how superposition and entanglement can be harnessed to perform computations that have no classical analogue.
The behavior of light and its interaction with matter is certainly one of the most interesting phenomena of physics. It has puzzled thinkers and scientists in ancient Greece (Archimedes) and through the Middle Ages, at least since the times of Robert Grosseteste (1168–1235), right up to the theories of Galileo Galilei and Isaac Newton. The classical electromagnetic theory of light (see Tab. 13.1) was beautifully established in the second half of the nineteenth century with the Maxwell equations. Quantum optics is nothing other than the quantum theory of light. It finds its roots in Planck's discovery (1900) that the assumption of energy quantization for a harmonic oscillator allowed us to solve the black-body problem (see Subsec. 1.5.1). The successive early steps that led to the quantization of the electromagnetic field include Einstein's explanation of the photoelectric effect with the introduction of the quantum of light (see Subsec. 1.2.1) and the interpretation of atomic spectra (see Subsec. 1.5.4). Quantum optics is usually not covered by conventional textbooks on quantum mechanics. We include its discussion here for two main reasons: first, because it is a fundamental and advanced application of the basic framework of quantum mechanics, and, second, because in the last 30 years quantum optics has played (and is still playing) a major role in the advancement and understanding of quantum mechanics.
The relationship between chaos and quantum mechanics has been somewhat uneasy--even stormy, in the minds of some people. However, much of the confusion may stem from inappropriate comparisons using formal analyses. In contrast, our starting point here is that a complete dynamical description requires a full understanding of the evolution of measured systems, necessary to explain actual experimental results. This is of course true, both classically and quantum mechanically. Because the evolution of the physical state is now conditioned on measurement results, the dynamics of such systems is intrinsically nonlinear even at the level of distribution functions. Due to this feature, the physically more complete treatment reveals the existence of dynamical regimes--such as chaos--that have no direct counterpart in the linear (unobserved) case. Moreover, this treatment allows for understanding how an effective classical behavior can result from the dynamics of an observed quantum system, both at the level of trajectories as well as distribution functions. Finally, we have the striking prediction that time-series from measured quantum systems can be chaotic far from the classical regime, with Lyapunov exponents differing from their classical values. These predictions can be tested in next-generation experiments.