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International Journal of Geometric Methods in Modern Physics

The velocity of a quantum particle in the case of real solutions of the time independent Schrödinger equation

A. Feoli

Published May 8, 2024• 3 citations
Publisher

Abstract

In the de Broglie–Bohm interpretation of quantum mechanics, the momentum of a particle in a box of perfectly reflecting walls is vanishing. On the contrary, the classical physics predicts an oscillatory motion between the walls. The resulting difference between the behavior of a body in classical and quantum regime is unsatisfactory for Einstein and many other scientists. In order to solve the problem, we show that it is possible to obtain a motion of the body using the rules of quantum mechanics. The result holds for the quantum systems described by solutions of the time independent Schrödinger equation that are real functions.

DOI
10.1142/s0219887824502190

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In the de Broglie–Bohm interpretation of quantum mechanics, the momentum of a particle in a box of perfectly reflecting walls is vanishing. On the contrary, the classical physics predicts an oscillatory motion between the walls. The resulting difference between the behavior of a body in classical and quantum regime is unsatisfactory for Einstein and many other scientists. In order to solve the problem, we show that it is possible to obtain a motion of the body using the rules of quantum mechanics. The result holds for the quantum systems described by solutions of the time independent Schrödinger equation that are real functions.
When the solution of the time independent Schrödinger equation is a real function, the velocity of the associated quantum particle is vanishing in Bohmian Mechanics. We can obtain a moving particle if we consider that its velocity can be related not to the phase of the wave function but to its amplitude. By using the rules of standard quantum mechanics, we have constructed a model generalizing the momentum operator and modifying the corresponding Schrödinger equation. We obtain a new nonlinear equation of the form studied by Ermakov and Pinney and we apply the model to the cases of the particle in a box and of a bouncing ball. The new formula of quantum velocity and the corresponding motion of quantum particles have an immediate correspondence with the behavior of the bodies in classical mechanics.
In this chapter, the Schrödinger equation is “derived” for particles that can be described by de Broglie waves. The Schrödinger equation is very different from the corresponding equation of motion in classical mechanics. In order to illustrate the fundamental differences between the two theories, one of the simplest problems of particle dynamics is solved in both Newtonian and quantum mechanics. This simple example also helps to show that quantum mechanics is the fundamental theory and classical mechanics is an approximation, a remarkably good approximation, when considering macroscopic objects. The solution of the Schrödinger equation is presented for a particle inside a box and the quantization condition is derived. The amazing possibility of quantum tunneling when a particle is incident on a barrier of height larger than the energy of the incident particle is also discussed. Finally the three-dimensional Schrödinger equation is solved for the hydrogen atom.
Following de Broglie, Bohm, and others, it is assumed that quantum mechanics may be interpreted causally and that the $\ensuremath{\psi}$ function plays the role of a generating function for particle trajectories. By arguing that the $\ensuremath{\psi}$ function should not be interpreted as a probability amplitude, a new method for generating particle trajectories is postulated. The four-momentum of a scalar particle is assumed to be given as the gradient of an unspecified function $F(\ensuremath{\psi})$, where $\ensuremath{\psi}$ is a pure real solution of the Klein-Gordon equation. Since the location of a particle is determined solely by its trajectory, the probability distribution differs from $\ensuremath{\psi}{\ensuremath{\psi}}^{*}$; and therefore, ordinary experimental results differing from the traditional theory may, in principle, be predicted. Particle motion and trajectories are discussed for three examples: a free particle, a particle in a box, and the double slit.
Classical mechanics traces a particle’s movement through space and time through x(t). For example, one may consider the case of a particle moving at constant speed (momentum p) in one direction or a particle bouncing back and forth at constant speed in a box. These problems are described in time and have direction and position associated with time etc. It is possible to define a probability P(x,t) in the classical picture based on delta time, the amount of time a particle spends in a little region of space dx. P(x,t), by itself, loses much relevant information present in the x(t) scenario because a particle moving to the right, or to the left, or bouncing back and forth all have the same probability, 1/L, where L is length. Furthermore, this probability is the same for all p (momentum) values. Thus a probability description, without extra information, is a subset of the relevant information in the problem. As a result, to describe the classical picture fully, one might say that a particle has a probability of 1/L, but also a mass mo and velocity +v (i.e. momentum mov nonrelativistically). For the particle bouncing back and forth in a box with constant p, one needs to give the initial position at time=0 and then a subsequent time (as well as the initial velocity and mo) in order to fully describe the problem, even though probability = 1/L. In the literature (see (1)), there have been many attempts to derive the quantum Schrodinger equation from a classical Fockker-Planck equation or a continuity equation (which follows from the Fokker-Planck equation as shown in (1)). The continuity equation contains a probability P(x,t) and a velocity(x,t) and is generally argued to represent classical physics. It does, if one retains appropriate classical conditions such as the discontinuity of density for a particle in a box (i.e. density=0 outside the box, but 1/L inside) and the notion of differing directions within the box. In fact, one may write density=W*(x,t)W(x,t) where W(x,t) is an ad hoc complex function and still retain compatibility with classical physics. If one does not, however, retain the classical conditions completely, nonclassical physics is introduced, even if density(x,t)=1/L. For example, in quantum mechanics density(x) is considered to be continuous in all x. Thus for a particle moving in a box, density outside the box is 0 so at the box wall it must also be 0. In the classical case, the density is 1 inside the box and 0 outside. There is a discontinuity classically and this cannot be changed and this contradicts the quantum mechanical picture. Thus quantum mechanics does not follow form classical Fokker-Planck or continuity equations which retain classical conditions.. Furthermore, because time is completely removed in the FP-continuity approach as applied to quantum mechanics, one cannot distinguish between forwards and backwards motion. As seen by the velocity field given in (1), v is zero for a bound particle which completely removes the sense of time and violates the classical physics conditions. It is, however, not zero for a particle moving in one direction. Thus there seems to be no issue in describing a Fokker-Planck-continuity equation as describing classical physics. One may even introduce density(x,t)= W*(x,t)W(x,t) provided one retains classical conditions allowing for discontinuity in density and different W(x,t) values at different times i.e. a discontinuity in W(x,t) at a box wall. If these conditions, however, are not met, then one no longer describes classical physics, but a new kind of physics (quantum physics). Thus one cannot argue that quantum mechanics follows from classical statistical Fokker-Planck-continuity equations. It may follow from these if one adds a set of extra conditions. Given these extra conditions, however, one could derive quantum mechanics without starting with classical density.
A formulation is proposed for the behavior of a particle in a box based on two assumptions: (1) particles have an associated phase which changes periodically with time as defined by de Broglie, and (2) the transmission of phase information follows optical principles, including reflection at potential boundaries and relativistic Doppler effects. This approach defines optimal trajectories by matching the phase of a source and its reflections. The momentum of the particle is guided by a de Broglie wave which follows the equation R exp {i[w0 (1-v^2/c^2)^-1/2][(t - vz)/c^2]} cos {[w0(1-v^2/c^2)^-1/2/c](vt-z)} This wave is generated by reflections occurring an even number of times, the phase and amplitude of which correspond to Lorentz transforms relative to the time and position, respectively. Nodes are produced by reflections occurring an odd number of times, which can be conceived to generate a wave traveling in the opposite direction and shifted by a phase constant π. Application to an individual particle in an infinite potential well affords the same results for energies and nodes as derived by the Schrödinger equation.