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Journal of Low Temperature Physics

Effect of the Screening Parameter on Shannon Entropy and Thermal Properties for Exponential Kratzer–Feus Potential

P. O. Amadi, A. R. P. Moreira, A. N. Ikot, Norshamsuri Ali, Syed Alwee Aljunid, R. Horchani

Published Apr 24, 2024• 9 citations
Publisher
DOI
10.1007/s10909-024-03098-x

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This study rigorously investigates the improved exponential Kratzer–Feus potential (IEKFP) model combined with exponential Kratzer–Feus potential (EKFP) and other terms produced by the effect of phase–space deformation [Formula: see text]. The new energy equation in three-dimensional non-relativistic non-commutative phase–space (3D(NR-NCPS)) symmetries is obtained using the parametric generalized Bopp’s shifts method and standard independent time perturbation theory of hydrogen-related molecules (CH, H2, NO, HCL, and LiH) diatomic molecules. This is achieved by applying a Green–Aldrich approximation scheme to the centrifugal terms. The new non-relativistic energy equation for the IEKFP in the presence of deformation phase–space is dependent on the discrete atomic quantum numbers ([Formula: see text] and [Formula: see text], the dissociation energy [Formula: see text], the equilibrium bond length [Formula: see text], the screening parameter [Formula: see text], and the deformation phase–space parameters ([Formula: see text]. The new resulting energy equation is utilized to calculate the partition function, from which thermodynamic properties such as mean energy, specific heat capacity, entropy, and free energy are derived in both three-dimensional non-relativistic quantum mechanics 3D(NR-QM) and (3D(NR-NCPS)) symmetries. This study has multiple applications in various domains, including atomic and molecular physics. We have indicated that our work deals with the study of the possibility of the effect of various phase–space deformations on various physical values such as energy and various thermodynamic properties under the influence of exponential Kratzer–Feus potential. So we completed the study of Amadi et al.
In this research, the radial Schrödinger equation for a newly proposed screened Kratzer–Hellmann potential model was studied via the conventional Nikiforov–Uvarov method. The approximate bound state solution of the Schrödinger equation was obtained using the Greene–Aldrich approximation in addition to the normalized eigenfunction for the new potential model, both analytically and numerically. These results were employed to evaluate the rotational–vibrational partition function and other thermodynamic properties for the screened Kratzer–Hellmann potential. The results obtained have been graphically discussed. Also, the normalized eigenfunction has been used to calculate some information-theoretic measures including Shannon entropy and Fisher information for low-lying states in both position and momentum spaces numerically. The Shannon entropy results obtained agreed with the Bialynicki-Birula and Mycielski inequality, while the Fisher information results obtained agreed with the Stam, Cramér–Rao inequality. Also, alternating increasing and decreasing localization across the screening parameter for both eigenstates was observed.