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WORLD SCIENTIFIC eBooks

Multiparticle Schrödinger equation

Published Mar 26, 2024• 0 citations
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DOI
10.1142/9789811286735_0013

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The center-of-mass principle is the key to the rapid computation of the interaction of a large number of classical particles. Electrons governed by the multiparticle Schrödinger equation have a much more complicated interaction mainly due to their spatial extent and the antisymmetry constraint on the total wave function of the combined electron system. We present a center-of-mass principle for quantum particles that accounts for this spatial extent, the antisymmetry constraint, and the potential operators. We use it to construct an algorithm for computing a size-consistent approximate wave function for large systems with simple geometries.
The one-particle Schrödinger and Dirac equations are derived, without making any quantization hypothesis, from the postulate that an elementary particle is a physical wave packet of dynamically varying form and size, rather than a pointlike object located somewhere within the support of a wavefunction that serves only as a mathematical probability amplitude. An isolated multiparticle system can, similarly, be described in principle as a set of interacting wave packets governed by coupled one-particle equations, a picture from which, in the nonrelativistic limit, the multiparticle Schrödinger equation can be obtained as a sufficiency condition for the system to have a conserved total energy equal to a particular value E .
We investigate hierarchies of nonlinear Schrödinger equations for multiparticle systems satisfying the separation property, i.e., where product wave functions evolve by the separate evolution of each factor.Such a hierarchy defines a nonlinear derivation on tensor products of the single-particle wave-function space, and satisfies a certain homogeneity property characterized by two new universal physical constants.A canonical construction of hierarchies is derived that allows the introduction, at any particular "threshold" number of particles, of truly new physical effects absent in systems having fewer particles.In particular, if single quantum particles satisfy the usual (linear) Schrödinger equation, a system of two particles can evolve by means of a fairly simple nonlinear Schrödinger equation without violating the separation property.Examples of Galileian-invariant hierarchies are given.