Abstract Rydberg atoms and excitons are composed so that they have a hydrogenic energy level structure governed by the Rydberg formula. They are relevant per se and for their numerous applications, e.g. facilitating the creation of novel quantum devices in quantum technologies which are inherently robust, miniature, and scalable (basically because they exist in solid-state platforms) and the realization of synthetic dimensions in numerous quantum-mechanical systems, giving rise to quantum matter which can behave as if it were in dimensions other than three. However the quantification of their internal disorder is scarcely known. Here we show and review the knowledge of dispersion, entanglement, physical entropies (Rényi, Shannon) and complexity-like measures of D-dimensional Rydberg systems with D ⩾ 2 in both position and momentum spaces. These uncertainty quantifiers are expressed in terms of D, the potential strength and the hyperquantum numbers of the Rydberg states. This has been possible because of the fine asymptotics of algebraic functionals the Laguerre and Gegenbauer polynomials which, together with the hyperspherical harmonics, control the Rydberg wavefunctions.
Abstract Rydberg atoms and excitons are composed so that they have a hydrogenic energy level structure governed by the Rydberg formula. They are relevant per se and for their numerous applications, e.g. facilitating the creation of novel quantum devices in quantum technologies which are inherently robust, miniature, and scalable (basically because they exist in solid-state platforms) and the realization of synthetic dimensions in numerous quantum-mechanical systems, giving rise to quantum matter which can behave as if it were in dimensions other than three. However the quantification of their internal disorder is scarcely known. Here we show and review the knowledge of dispersion, entanglement, physical entropies (Rényi, Shannon) and complexity-like measures of D-dimensional Rydberg systems with D ⩾ 2 in both position and momentum spaces. These uncertainty quantifiers are expressed in terms of D, the potential strength and the hyperquantum numbers of the Rydberg states. This has been possible because of the fine asymptotics of algebraic functionals the Laguerre and Gegenbauer polynomials which, together with the hyperspherical harmonics, control the Rydberg wavefunctions.
The internal disorder of hydrogenic Rydberg atoms as contained in their position and momentum probability densities is examined by means of the following information-theoretic spreading quantities: the radial and logarithmic expectation values, the Shannon entropy, and the Fisher information. As well, the complexity measures of Crámer-Rao, Fisher-Shannon, and López Ruiz-Mancini-Calvet types are investigated in both reciprocal spaces. The leading term of these quantities is rigorously calculated by use of the asymptotic properties of the concomitant entropic functionals of the Laguerre and Gegenbauer orthogonal polynomials which control the wavefunctions of the Rydberg states in both position and momentum spaces. The associated generalized Heisenberg-like, logarithmic and entropic uncertainty relations are also given. Finally, application to linear (l = 0), circular (l = n − 1), and quasicircular (l = n − 2) states is explicitly done.
The various facets of the internal disorder of quantum systems can be described by means of the Rényi entropies of their single-particle probability density according to modern density functional theory and quantum information techniques. In this work, we first show the lower and upper bounds for the Rényi entropies of general and central-potential quantum systems, as well as the associated entropic uncertainty relations. Then, the Rényi entropies of multidimensional oscillator and hydrogenic-like systems are reviewed and explicitly determined for all bound stationary position and momentum states from first principles (i.e., in terms of the potential strength, the space dimensionality and the states's hyperquantum numbers). This is possible because the associated wavefunctions can be expressed by means of hypergeometric orthogonal polynomials. Emphasis is placed on the most extreme, non-trivial cases corresponding to the highly excited Rydberg states, where the Rényi entropies can be amazingly obtained in a simple, compact, and transparent form. Powerful asymptotic approaches of approximation theory have been used when the polynomial's degree or the weight-function parameter(s) of the Hermite, Laguerre, and Gegenbauer polynomials have large values. At present, these special states are being shown of increasing potential interest in quantum information and the associated quantum technologies, such as e.g., quantum key distribution, quantum computation, and quantum metrology.
Abstract The position and momentum probability densities of a multidimensional quantum system are fully characterized by means of the radial expectation values ⟨ r α ⟩ and p α , respectively. These quantities, which describe and/or are closely related to various fundamental properties of realistic systems, have not been calculated in an analytical and effective manner up until now except for a number of three-dimensional hydrogenic states. In this work we explicitly show these expectation values for all discrete stationary D -dimensional hydrogenic states in terms of the dimensionality D , the strength of the Coulomb potential (i.e. the nuclear charge) and the D state’s hyperquantum numbers. Emphasis is placed on the momentum expectation values (mostly unknown, specially the ones with odd order) which are obtained in a closed compact form. Applications are made to circular, S -wave, high-energy (Rydberg) and high-dimensional (pseudo-classical) states of three- and multidimensional hydrogenic atoms. This has been possible because of the analytical algebraic and asymptotical properties of the special functions (orthogonal polynomials, hyperspherical harmonics) which control the states’ wavefunctions. Finally, some Heisenberg-like uncertainty inequalities satisfied by these dispersion quantities are also given and discussed.
The internal disorder of a D-dimensional hydrogenic system, which is strongly associated to the non-uniformity of the quantum-mechanical density of its physical states, is investigated by means of the shape complexity in the two reciprocal spaces. This quantity, which is the product of the disequilibrium and the Shannon entropic power, is mathematically expressed for both ground and excited stationary states in terms of certain entropic functionals of Laguerre and Gegenbauer (or ultraspherical) polynomials. Emphasis is made in the ground and circular states.
High dimensional atomic states play a relevant role in a broad range of quantum fields, ranging from atomic and molecular physics to quantum technologies. The D-dimensional hydrogenic system (i.e., a negatively-charged particle moving around a positively charged core under a Coulomb-like potential) is the main prototype of the physics of multidimensional quantum systems. In this work, we review the leading terms of the Heisenberg-like (radial expectation values) and entropy-like (Rényi, Shannon) uncertainty measures of this system at the limit of high D. They are given in a simple compact way in terms of the space dimensionality, the Coulomb strength and the state’s hyperquantum numbers. The associated multidimensional position–momentum uncertainty relations are also revised and compared with those of other relevant systems.