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CRC Press eBooks

Quantum Mechanics (Conception)

Giuseppe Pileio

Published Jan 10, 2024• 0 citations
Publisher

Abstract

This chapter attempts to reconnect quantum mechanics to classical mechanics by comparing the role of the Poisson bracket used in classical mechanics to the commutator used in quantum mechanics. After introducing Planck’s quantization method, the operators for position and linear momentum are defined, their eigenvalues and eigenvectors are derived, and their mutual commutator is taken and compared to the analogous result in classical mechanics. Finally, the Heisenberg’s uncertainty principle is introduced, and its implications briefly discussed.

DOI
10.1201/9781003459781-10

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This chapter attempts to reconnect quantum mechanics to classical mechanics by comparing the role of the Poisson bracket used in classical mechanics to the commutator used in quantum mechanics. After introducing Planck’s quantization method, the operators for position and linear momentum are defined, their eigenvalues and eigenvectors are derived, and their mutual commutator is taken and compared to the analogous result in classical mechanics. Finally, the Heisenberg’s uncertainty principle is introduced, and its implications briefly discussed.
Abstract A short review of methods in classical mechanics is given, as a basis both for presenting transport processes and quantum mechanics, based upon theorems of Louisville and Noether. Examples are given to demonstrate that in spectroscopy, aspects of classical physics are useful even beyond Bohr’s correspondence principle. Augmenting classical physics with just Planck’s quantum of action ℏ along with Heisenberg’s uncertainty principle, properties of molecular spectra are inferred. The central role of Poisson brackets in moving towards quantum mechanics is highlighted.
This chapter begins by developing the relation between the quantum theory and the linear algebra. It discusses the most fundamental postulates of the theory and provides a phenomenological development of the Schrödinger wave equation (SWE) although the results might be gleaned from the classical Lagrangian and Hamiltonian with the Poisson bracket relations. Afterward some simple examples for the infinitely and finitely deep wells help clarify the basic postulates. The simple harmonic oscillator has perhaps the most sweeping implications and applications for the quantum theory. For this reason, we present the most applicable formalism for the Harmonic oscillator that uses the operator approach rather than the classical method of partial differential equations. The angular momentum and spin are presented for the study of the atom and for applications for nanodevices, and quantum computing. Next the representation formalism clarifies the distinction between the dynamical operators and the wave functions and their interrelations. The chapter discusses both timeindependent and time-dependent perturbation theories. The density operator combines the quantum theory with the classical theory for finding the behavior of a system. The density operator represents one of the basic concepts in the quantum theory. The remainder of the chapter introduces the more advanced material meant to introduce the quantum field theory starting with the second quantization and the propagator.
Several quantum gravity and string theory thought experiments indicate that the Heisenberg uncertainty relations get modified at the Planck scale so that a minimal length do arises. This modification may imply a modification of the canonical commutation relations and hence quantum mechanics at the Planck scale. The corresponding modification of classical mechanics is usually considered by replacing modified quantum commutators by Poisson brackets suitably modified in such a way that they retain their main properties (antisymmetry, linearity, Leibniz rule and Jacobi identity). We indicate that there exists an alternative interesting possibility. Koopman–von Neumann’s Hilbert space formulation of classical mechanics allows, as Sudarshan remarked, to consider the classical mechanics as a hidden variable quantum system. Then, the Planck scale modification of this quantum system naturally induces the corresponding modification of dynamics in the classical substrate. Interestingly, it seems this induced modification in fact destroys the classicality: classical position and momentum operators cease to be commuting and hidden variables do appear in their evolution equations.
The position operator in the Heisenberg representation obeys the usual classical equation of motion. The similarity between the Heisenberg equations of motion and the classical Hamiltonian equations of motion arises from the fact that the commutator of the operators for the physical quantities plays a similar role in quantum mechanics, to that of the Poisson bracket of the classical quantities A and B, in classical mechanics. Generally, the Heisenberg equations of motion are more difficult to solve than the corresponding classical equations because of the lack of commutation of quantum mechanical operators. The chapter explains the notion of a time-ordered product of operators, and then can be written much more compactly.
In the first part of this series we have shown how the Schrodinger equation for a single particle and the corresponding non relativistic quantum observables can be obtained from a purely classical phonon model through the Newtonian equations of motion. In this work we focus instead on how the classical Hamiltonian formalism applied to the same phonon system allows to recover the feature of relativistic quantum mechanics for a single spinless particle. Using the classical nature of the phonon model, we naturally define continuous Poisson brackets between classical observables, which allows to recover the dynamics of such observables, i.e. the Ehrenfest relations associated to real-valued Klein-Gordon fields. The Poisson brackets also permits to obtain the generic form of constants of motions, thus generalizing the concept of inner products and momentum on Klein-Gordon fields. We then connect the formalism of real-valued classical functionals with that of hermitian operators and complex-valued wave functions. This is done through the introduction of a non-local complex-valued change of variables which allows to rewrite the real-valued Klein-Gordon equation in a form akin to the Schrodinger equation, and the classical observables as quantum expectation values. Then, we show how this change of variables allows to rewrite the classical Poisson brackets as commutators of hermitian operators. This points out the strict equivalence between the Heisenberg formalism and the formalism of classical Poisson bracket. Eventually, we illustrate how the Poisson brackets allows to recover the transformations of Poincare group in 1+1 dimension together with its algebra. The latter makes the link between the Lorentz invariant inner product of Mostafazadeh and the Casimir invariant associated to the mass of particle.
Quantum mechanics takes various forms. For atomic and nuclear physics, the Schrödinger picture is convenient. For quantum field theory and for correspondence with classical mechanics through Poisson brackets, the Heisenberg picture is useful. The interaction picture is useful in calculations. The Wigner phase-space is convenient for studying the uncertainty relations and their symmetries. The density matrix and probability distribution are necessary for extracting measurable dynamic quantities and are essential for ensemble averages. Mathematical instruments, such as the Lie algebra of the rotation group, the creation and annihilation operators of the Fock space and the Lie algebra governing Dirac’s two oscillators are shown to be derivable from Heisenberg’s commutation relations.