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CRC Press eBooks

Quantum Mechanics (Inception)

Giuseppe Pileio

Published Jan 10, 2024• 0 citations
Publisher

Abstract

This chapter discusses the basis of quantum mechanics in terms of a series of postulates. In doing so it introduces the concepts of wavefunction, operator, and expectation values. The notions of eigenequations, eigenvalues, eigenvectors, adjoint, and commutators are also encountered and explained. Finally, the time-dependent Schrödinger equation is written down and used to derive the time evolution of expectation values in quantum mechanics.

DOI
10.1201/9781003459781-2

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This chapter discusses the basis of quantum mechanics in terms of a series of postulates. In doing so it introduces the concepts of wavefunction, operator, and expectation values. The notions of eigenequations, eigenvalues, eigenvectors, adjoint, and commutators are also encountered and explained. Finally, the time-dependent Schrödinger equation is written down and used to derive the time evolution of expectation values in quantum mechanics.
Abstract Chapter 9 begins laying a foundation for quantum statistical mechanics with a discussion of relevant topics in quantum mechanics. The fundamental postulates of quantum mechanics are reviewed, beginning with the definition of a quantum state and the introduction of the concept of a state vector in a Hilbert space. The representation of observables as Hermitian operators on Hilbert space vectors is described; it is shown that the eigenvalues of Hermitian operators are real and, therefore, constitute possible outcomes of measurements made on these observables. The notions compatible and non-compatible observables and implication for the measurement problem are presented. The time-dependent Schrödinger equation is introduced as generating the time-evolution of the state vector, and it is shown how to cast the Schrödinger equation into a coordinate basis to yield the wave equation of quantum mechanics. Coordinate and momentum bases and their properties are desribed. Several analytically solvable quantum systems are presented as illustrative examples. The chapter concludes with a discussion of spin and the treatment identical particles
Abstract In this chapter, we present the theoretical foundations of quantum mechanics. Our presentation follows the von Neumann postulates. We discuss them stepping through the parts of a typical quantum experiment: the preparation of the system, the subsequent time evolution, and the final measurement. Specifically, we present normalized vectors in a Hilbert space, that describe preparations; projection-valued measures and Hermitian operators, that describe measurable observables; and the Schrodinger equation governing time evolution. In the last part of the chapter, we present two examples of quantum systems: the qubit and the quantum harmonic oscillator. We study the interaction between them in two different regimes
Abstract The second chapter introduces the notion of wave functions and their equation of motion proposed by Erwin Schrödinger. The interpretation and normalization of the wave function are discussed, leading to the continuity equation. The chapter also introduces basic mathematical operations that can be carried out for wave functions and operators, describing e.g., how to calculate scalar products and commutators, as well as expectation values and variances of observables. With these tools at hand, Heisenberg’s uncertainty principle is re-examined, focusing on the example of a Gaussian wave packet, which is studied both in position space and momentum space. We also discuss the time evolution of general states and of the exemplary wave packet. Finally, we will see how classical physics is recovered as a limiting case of the quantum-mechanical description
This chapter reviews the fundamental assumptions underlying quantum mechanics, while simultaneously seeing how they can be realized in the language of MATLAB, which we will be using to express and explore bonding concepts. For every measurable quantity there is an operator in quantum mechanics. The only possible values that can be measured for a property are given by the eigenvalues of its corresponding operator. Such oscillations represent the usual difficulty of representing a sharp discontinuous function with harmonic functions, such as sine and cosine functions. The time-dependent Schrodinger equation is what gives the eigenfunctions of the Hamiltonian operator such an important place in quantum mechanics. The postulate is fundamental to defining the relationship between a quantum mechanical system and the person observing it. Observations cannot be made on a system without disturbing it, with the sole exception being the case when a system is already in an eigenstate of the property being measured.
This chapter starts with the definition of postulates. Here, in quantum mechanics, the postulates concern the atomic and molecular properties, which are quite far removed from everyday experience. The postulates described here make no claim to those happy mathematical adjectives such as ‘rigorous’, ‘complete’, or irreducible. The ‘proof’ of the postulates is their ability to explain the adequate experimental observations. Here, we have incorporated six postulates. The first postulate opines that ‘the state of quantum mechanical objects is described by a wavefunction’, whereas the second postulate says that ‘every physical observable is expressed by a linear operator’. It also describes how a quantum mechanical operator is constructed. The third postulate gives an idea that the measurement of a physical observable will yield a result, which is one of the Eigen values of the corresponding operator for that observable. The fourth postulate gives how the average of a sequence of measurement is connected with an operator. The fifth postulate is called the time-dependent postulate. Here, it gives a relationship between the time-dependent wave function and an operator, whereas the sixth postulate says that the wave function must be antisymmetric (or symmetric) for the exchange of identical fermions. It must be noted that each and every postulate has been explained clearly. The references, solved problems, and questions on concepts have been given at the end of the chapter.
The postulates of quantum mechanics associate the time-evolution of a system with its time-dependent Schrödinger equation. We start by examining different solutions to this equation for a particle, represented in terms of a Gaussian wave packet, in different scenarios: free, scattered from a potential energy barrier, or trapped in a potential energy well. In some cases, we encounter stationary solutions, in which the probability density does not change in time (a standing wave). These solutions are identified as eigenfunctions of a system Hamiltonian. The properties of the Hamiltonian as a Hermitian operator are introduced, and particularly, the fact that its proper eigenfunctions can compose an orthonormal set, and that the corresponding eigenvalues are real-valued. Learning that all operators that relate to measurables are Hermitian, and that their eigenvalues relate to the measured values, we conclude that the eigenvalues of the energy operator (Hamiltonian) are the energy levels of the quantum system.