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Proceedings of the National Academy of Sciences

Instantons and the quantum bound to chaos

Vijay Ganesh Sadhasivam, Lars Meuser, David R. Reichman, Stuart C. Althorpe

Published Nov 30, 2023• 8 citations
Publisher

Abstract

The rate at which information scrambles in a quantum system can be quantified using out-of-time-ordered correlators. A remarkable prediction is that the associated Lyapunov exponent [Formula: see text] that quantifies the scrambling rate in chaotic systems obeys a universal bound [Formula: see text]. Previous numerical and analytical studies have indicated that this bound has a quantum-statistical origin. Here, we use path-integral techniques to show that a minimal theory to reproduce this bound involves adding contributions from quantum thermal fluctuations (describing quantum tunneling and zero-point energy) to classical dynamics. By propagating a model quantum-Boltzmann-conserving classical dynamics for a system with a barrier, we show that the bound is controlled by the stability of thermal fluctuations around the barrier instanton (a delocalized structure which dominates the tunneling statistics). This stability requirement appears to be general, implying that there is a close relation between the formation of instantons, or related delocalized structures, and the imposition of the quantum-chaos bound.

DOI
10.1073/pnas.2312378120

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The rate at which information scrambles in a quantum system can be quantified using out-of-time-ordered correlators. A remarkable prediction is that the associated Lyapunov exponent [Formula: see text] that quantifies the scrambling rate in chaotic systems obeys a universal bound [Formula: see text]. Previous numerical and analytical studies have indicated that this bound has a quantum-statistical origin. Here, we use path-integral techniques to show that a minimal theory to reproduce this bound involves adding contributions from quantum thermal fluctuations (describing quantum tunneling and zero-point energy) to classical dynamics. By propagating a model quantum-Boltzmann-conserving classical dynamics for a system with a barrier, we show that the bound is controlled by the stability of thermal fluctuations around the barrier instanton (a delocalized structure which dominates the tunneling statistics). This stability requirement appears to be general, implying that there is a close relation between the formation of instantons, or related delocalized structures, and the imposition of the quantum-chaos bound.
The rate at which information scrambles in a quantum system can be quantified using out-of-time-ordered correlators. A remarkable prediction is that the associated Lyapunov exponent λ that quantifies the scrambling rate in chaotic systems obeys a universal bound λ < 2πkBT/h. Previous numerical and analytical studies have indicated that this bound has a quantum-statistical origin. Here, we use path-integral techniques to show that a minimal theory to reproduce this bound involves adding contributions from quantum thermal fluctuations (describing quantum tunneling and zero-point energy) to classical dynamics. By propagating a model quantum-Boltzmannconserving classical dynamics for a system with a barrier, we show that the bound is controlled by the stability of thermal fluctuations around the barrier instanton (a delocalized structure which dominates the tunneling statistics). This stability requirement appears to be general, implying that there is a close relation between the formation of instantons, or related delocalized structures, and the imposition of the quantum-chaos bound.
Out-of-Time-Ordered Commutators (OTOCs), representing a key diagnostic for scrambling as a facet of short-time quantum chaos, have attracted wide-ranging interest, from many-body physics to quantum gravity. By means of a suitable form of the Wigner-Moyal expansion, and invoking ensemble equivalence in statistical physics, we provide a consistent approach to the growth rate of the OTOC for many-body systems with chaotic classical limit where both the classical Lyapunov exponent and the quantum nature of the density of states enter. Applying this construction to quantized high-dimensional hyperbolic motion, i.e., a quantum chaotic system that exhibits gravity-like correlation functions in the late-time regime, we compute the OTOC growth rate ΛΛΛ as a function of the number of degrees of freedom, fff, and inverse temperature, βββ. We show that the scaled growth rate, Λ/fΛ/fΛ/f, can be described by a universal function of fβf βfβ and displays a cross-over from classical to quantum behavior as we increase fff and/or lower the temperature. In the deep quantum regime of infinite fff, we find maximally fast scrambling in the sense of the Maldacena-Shenker-Stanford bound on chaos. This elucidates the non-perturbative mechanism underlying the saturation of the bound via quantum contributions to the mean density of states, and it provides further support for this dynamical system as a dual to two-dimensional quantum gravity. In this way, we present first evidence of maximally fast scrambling in a quantum chaotic system with a well-defined classical Hamiltonian limit, without invoking any external mechanism such as (disorder) averaging.
The ultimate regularity of quantum mechanics creates a tension with the assumption of classical chaos used in many of our pictures of chemical reaction dynamics. Out-of-time-order correlators (OTOCs) provide a quantum analog to the Lyapunov exponents that characterize classical chaotic motion. Maldacena, Shenker, and Stanford have suggested a fundamental quantum bound for the rate of information scrambling, which resembles a limit suggested by Herzfeld for chemical reaction rates. Here, we use OTOCs to study model reactions based on a double-well reaction coordinate coupled to anharmonic oscillators or to a continuum oscillator bath. Upon cooling, as one enters the tunneling regime where the reaction rate does not strongly depend on temperature, the quantum Lyapunov exponent can approach the scrambling bound and the effective reaction rate obtained from a population correlation function can approach the Herzfeld limit on reaction rates: Tunneling increases scrambling by expanding the state space available to the system. The coupling of a dissipative continuum bath to the reaction coordinate reduces the scrambling rate obtained from the early-time OTOC, thus making the scrambling bound harder to reach, in the same way that friction is known to lower the temperature at which thermally activated barrier crossing goes over to the low-temperature activationless tunneling regime. Thus, chemical reactions entering the tunneling regime can be information scramblers as powerful as the black holes to which the quantum Lyapunov exponent bound has usually been applied.
In this work, we develop a quantum metrological framework for quantum chaos by showing that local subsystems of information scrambling systems naturally function as quantum stopwatches. The reduced quantum state of a subsystem encodes the passage of time through its growing distinguishability from the initial preparation. Treating time as the estimation parameter, we then derive a generalized quantum Cramer-Rao bound that directly relates the precision of time estimation to the decay of out-of-time ordered correlators (OTOCs) and subsystem quantum Fisher information (QFI). As a main result, we obtain continuity bounds for quantum Lyapunov exponent in terms of the subsystem QFI in quantumly chaotic dynamics. Furthermore, using a scaling analysis based on imaginary-time correlators, we show that the subsystem QFI exhibits universal critical amplification near quantum phase transitions. Our results are demonstrated and verified by a numerical analysis of the dynamics of a chaotic Ising chain.
Out-of-Time-Ordered Commutators (OTOCs), representing a key diagnostic for scrambling as a facet of short-time quantum chaos, have attracted wide-ranging interest, from many-body physics to quantum gravity. By means of a suitable form of the Wigner-Moyal expansion, and invoking ensemble equivalence in statistical physics, we provide a consistent approach to the growth rate of the OTOC for many-body systems with chaotic classical limit where both the classical Lyapunov exponent and the quantum nature of the density of states enter. Applying this construction to quantized high-dimensional hyperbolic motion, i.e., a quantum chaotic system that exhibits gravity-like correlation functions in the late-time regime, we compute the OTOC growth rate Λ as a function of the number of degrees of freedom, f, and inverse temperature, β. We show that the scaled growth rate, Λ/f, can be described by a universal function of fβ and displays a cross-over from classical to quantum behavior as we increase f and/or lower the temperature. In the deep quantum regime of infinite f, we find maximally fast scrambling in the sense of the Maldacena-Shenker-Stanford bound on chaos. This elucidates the non-perturbative mechanism underlying the saturation of the bound via quantum contributions to the mean density of states, and it provides further support for this dynamical system as a dual to two-dimensional quantum gravity. In this way, we present first evidence of maximally fast scrambling in a quantum chaotic system with a well-defined classical Hamiltonian limit, without invoking any external mechanism such as (disorder) averaging.
In this work, we develop a quantum metrological framework for quantum chaos by showing that local subsystems of information scrambling systems naturally function as quantum stopwatches. The reduced quantum state of a subsystem encodes the passage of time through its growing distinguishability from the initial preparation. Treating time as the estimation parameter, we then derive a generalized quantum Cramer-Rao bound that directly relates the precision of time estimation to the decay of out-of-time ordered correlators (OTOCs) and subsystem quantum Fisher information (QFI). As a main result, we obtain continuity bounds for quantum Lyapunov exponent in terms of the subsystem QFI in quantumly chaotic dynamics. Furthermore, using a scaling analysis based on imaginary-time correlators, we show that the subsystem QFI exhibits universal critical amplification near quantum phase transitions. Our results are demonstrated and verified by a numerical analysis of the dynamics of a chaotic Ising chain.