Abstract Quantum mechanics was created mainly to account for microscopic phenomena that occur on a scale of order IO−10 m. It has turned out to be an astonishingly successful theory which applies on a scale down to at least 10−18 m. Quantum theory has become established as part of the essential core of physics. The purpose of this introductory chapter is twofold. Firstly, in Sections 1.1–1.7 we review the formalism of elementary nonrelativistic quantum mechanics. In this review we attempt to give enough of the terminology and basics of the subject so that a reader who is not already familiar with quantum mechanics will be able to follow the applications considered later in the book. For the reader who finds our discussion too brief, the literature on quantum mechanics is vast and we recommend in particular Refs 1–5. The second purpose of this chapter is to present the basic tools of operator methods as they are used in this book: thus in Sections 1.8–1.11 we discuss commutation relations, shift operators, and the virial, hypervirial, and Hellmann Feynman theorems.
Abstract Quantum mechanics was created mainly to account for microscopic phenomena that occur on a scale of order IO−10 m. It has turned out to be an astonishingly successful theory which applies on a scale down to at least 10−18 m. Quantum theory has become established as part of the essential core of physics. The purpose of this introductory chapter is twofold. Firstly, in Sections 1.1–1.7 we review the formalism of elementary nonrelativistic quantum mechanics. In this review we attempt to give enough of the terminology and basics of the subject so that a reader who is not already familiar with quantum mechanics will be able to follow the applications considered later in the book. For the reader who finds our discussion too brief, the literature on quantum mechanics is vast and we recommend in particular Refs 1–5. The second purpose of this chapter is to present the basic tools of operator methods as they are used in this book: thus in Sections 1.8–1.11 we discuss commutation relations, shift operators, and the virial, hypervirial, and Hellmann Feynman theorems.
In this second chapter we will review the basic mathematical and physical facts about quantum mechanics and establish physical units and notation. Those readers already familiar with the subject can safely jump to the next chapter. An attempt has been made to make the presentation in this chapter as elementary as possible, and yet present the basic facts that will be needed later. There are many beautiful and important topics which will not be touched upon such as self-adjointness of Schrödinger operators, the general mathematical structure of quantum mechanics and the like. These topics are well described in other works, e.g.. Much of the following can be done in a Euclidean space of arbitrary dimension, but in this chapter the dimension of the Euclidean space is taken to be three-which is the physical case-unless otherwise stated. We do this to avoid confusion and, occasionally, complications that arise in the computation of mathematical constants. The interested reader can easily generalize what is done here to the R d , d > 3 case. Likewise, in the next chapters we mostly consider N particles, with spatial coordinates in R 3 , so that the total spatial dimension is 3 N . A Brief Review of the Connection Between Classical and Quantum Mechanics Considering the range of validity of quantum mechanics, it is not surprising that its formulation is more complicated and abstract than classical mechanics. Nevertheless, classical mechanics is a basic ingredient for quantum mechanics. One still talks about position, momentum and energy which are notions from Newtonian mechanics.
Mathematical formalism of quantum mechanics: brief introduction In this chapter, we present basic notions of quantum mechanics, and we emphasize “quantum mathematics.” To posit that the mathematical formalism of quantum mechanics can be used outside of quantum physics (as in sociology, economics, or finance) may be of interest. If one can steer away from merely positing and veer instead into convincing the reader that such a position is tenable, then some achievement has been booked. But the price to pay is that the formalism of quantum mechanics needs to be uncovered: how else can one judge whether what we posit is senseful? Thus, a reader can either (i) formally accept our viewpoint about the quantum-like paradigm (see Khrennikov [1]), or (ii) ask for a detailed analysis of the quantum foundations which would justify this paradigm. In the first case, it may well be sufficient to skip this chapter (but we should suggest to attempt to include Chapter 3). In the second case, we invite especially those readers who are concerned about the fact that the formal usage of the mathematical formalism of quantum mechanics may transfer major problems of quantum foundations to social science, economics, and finance, to read the present chapter carefully.
Abstract This book provides the reader with a contemporary and comprehensive introduction to Quantum Mechanics. It is suitable for beginners as well as for more advanced university students. Quantum mechanics is presented in a pedagogical fashion, with a clear logical organization. The various concepts and methods are introduced first in elementary terms, and later developed into more precise formulations. Systematic studies of approximation methods and the discussion of a wide class of physical applications follow. Part I of the book, together with the opening sections of Part II, provide adequate material for an introductory course of one semester at most universities. The rest of the book might be used in an advanced course on Quantum Mechanics. The basic material is fairly standard, even though some discussions such as those on general systems with time-dependent Hamiltonians, on metastable systems, as well as the discussions in some of the Complement sections, may not be found in other textbooks. The book also contains many original observations or new ways of illustrating even well-known subjects. In fact, the authors wish to convey in this book the sense of wonder in the logical simplicity and at the same time the beauty of subtle and far-reaching consequences of Quantum Mechanics, to young physics students in particular. Problem sets are provided at the end of each chapter, to be solved either analytically or by numerical methods. The solutions to both types of problems are given as separate pdf files or as Mathematica notebooks (there are 88 of them), all together on a CD accompanying the textbook. The presence of such a collection of numerical analyses enriches the main text and is one of the characteristic features of the book. With the many interesting systems discussed, the book will also be a useful reference for researchers and teachers. It provides the reader with a unique, enjoyable and rather complete textbook of Quantum Mechanics, destined to set a new standard for many years to come.
The mathematical formalism of quantum theory in terms of vectors and operators in infinite-dimensional complex vector spaces is very abstract. The definitions of many mathematical quantities used do not seem to have an intuitive meaning, which makes it difficult to appreciate the mathematical formalism and understand quantum mechanics. This book provides intuition and motivation to the mathematics of quantum theory, introducing the mathematics in its simplest and familiar form, for instance, with three-dimensional vectors and operators, which can be readily understood. Feeling confident about and comfortable with the mathematics used helps readers appreciate and understand the concepts and formalism of quantum mechanics. This book is divided into four parts. Part I is a brief review of the general properties of classical and quantum systems. A general discussion of probability theory is also included which aims to help in understanding the probability theories relevant to quantum mechanics. Part II is a detailed study of the mathematics for quantum mechanics. Part III presents quantum mechanics in a series of postulates. Six groups of postulates are presented to describe orthodox quantum systems. Each statement of a postulate is supplemented with a detailed discussion. To make them easier to understand, the postulates for discrete observables are presented before those for continuous observables. Part IV presents several illustrative applications, which include harmonic and isotropic oscillators, charged particle in external magnetic fields and the Aharonov–Bohm effect. For easy reference, definitions, theorems, examples, comments, properties and results are labelled with section numbers. Various symbols and notations are adopted to distinguish different quantities explicitly and to avoid misrepresentation. Self-contained both mathematically and physically, the book is accessible to a wide readership, including astrophysicists, mathematicians and philosophers of science who are interested in the foundations of quantum mechanics.
The chief aim of this chapter is to give brief accounts of topics in nonrelativistic quantum mechanics that are not always treated in elementary texts. We begin with the Hilbert space formulation of quantum mechanics as set down by von Neumann in his book Mathematical Foundations of Quantum Mechanics (von Neumann, 1955), which will henceforth be referred to as von Neumann's book. Much of our concern will be with continuous spectra, which cannot be discussed adequately in the Dirac formalism. The density matrix, which will play a key role in Chapters 8 and 10, will be treated in some detail. The section on formalism is followed by one on the probability interpretation; the latter is included because Sewell's theory of measurement suggests a subtle reformulation of a part of it. These are followed by sections on superselection rules and the Galilei group, which is the relativity group of quantum mechanics. They are based on the pioneering works of Wigner and Bargmann. The last section is devoted to the fundamental theorems of von Neumann and Stone, and to Reeh's observation on the physical significance of the failure of the Stone–von Neumann uniqueness theorem at the Lie algebra level. The formalism of quantum mechanics By quantum mechanics we shall mean the nonrelativistic quantum theory of a system with a finite number, N, of particles. The number N is assumed fixed. It will be convenient, for later recall, to divide the material into subsections.