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Symmetries in Quantum Mechanics

Fl. Stancu

Published Nov 21, 1996• 0 citations
Publisher

Abstract

Abstract Group theory is a branch of mathematics appropriate for studying symmetries of physical systems. A symmetry is a natural attribute of the physical world and therefore is the starting point of any physical law. The foundation of dynamics is in Lagrangian theory or equivalently in Hamiltonian theory. A symmetry of a physical system is expressed by the invariance of its Lagrangian or Hamiltonian, or ultimately of its equations of motion, under certain transformations. When these transformations form groups it is convenient and useful to study symmetries through group theory. Group theory can explain observed regularities and helps to simplify and unify the physics of apparently different systems. It is a valuable tool that helps in predicting the behaviour of systems for which a symmetry has been found.

DOI
10.1093/oso/9780198517429.003.0001

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Abstract Group theory is a branch of mathematics appropriate for studying symmetries of physical systems. A symmetry is a natural attribute of the physical world and therefore is the starting point of any physical law. The foundation of dynamics is in Lagrangian theory or equivalently in Hamiltonian theory. A symmetry of a physical system is expressed by the invariance of its Lagrangian or Hamiltonian, or ultimately of its equations of motion, under certain transformations. When these transformations form groups it is convenient and useful to study symmetries through group theory. Group theory can explain observed regularities and helps to simplify and unify the physics of apparently different systems. It is a valuable tool that helps in predicting the behaviour of systems for which a symmetry has been found.
The structures are physical systems and/or their mathematical descriptions consisting of elements such as particles, fields, observables, operators etc and of relations between these elements: the equations of motion and the rules of quantum mechanics. Examples of symmetries are reflections, permutations of particles, time reversal. The physical system has a symmetry group means, then, that there is a group of transformations leaving the equations of motion and the rules of quantum mechanics invariant. The discrete symmetries lead to conservation laws frequently expressible in terms of quantum numbers, but sometimes requiring a more elaborate description. The observables corresponding to the super-selection quantum numbers can be measured without disturbing any other measurement; their values are always sharp. The chapter shows that the invariant subspace may be labelled by continuous quantum numbers (for instance momentum) when the direct sum becomes a direct integral.
A symmetry is an equivalence of different physical situations, and is therefore strictly associated with the concept of invariance . One of the main aims of physics is the search in nature for symmetries and, therefore, for observables that are invariant under certain classes of transformation. In this context, it becomes particularly interesting to look for the conditions under which a certain symmetry is eventually broken. We have already discussed some symmetries of quantum mechanics: time translations (Ch. 3), space translations (Ch. 2) and rotations (Ch. 6). Another example of invariance is represented by the indistinguishability of identical particles, which we discussed in the previous chapter. Symmetries are induced by physical transformations that generate some invariant properties (see Sec. 8.1). In Sec. 8.2, the continuous transformations induced by rotations and space translations are analyzed, whereas in Sec. 8.3, space reflection and time reversal ( discrete symmetries) are discussed. As we shall see in the next chapter, time reversibility is lost in the measurement process. The rigorous mathematical framework of a theory of transformations and of their invariance is called group theory (the subject of Sec. 8.4). Quantum transformations and symmetries Active and passive transformations We have seen that time evolution may be represented either in the Schrödinger picture (state vectors evolve and observables are kept constant) or in the Heisenberg picture (states vectors remain constant and observables evolve) (see Subsec. 3.6.1 and Sec. 5.3).
What is the common thing between some integers and symmetries of an equilateral triangle? How studying rotations on a circle helps us understand quantum mechanics? Groups and their representations provide an amazing framework for many physics and chemistry theories. Understanding how certain groups act on physical systems, both classical and quantum, helps us to build models and make predictions. In this talk, we discover how abstract mathematical notions such as groups and representation theory and counterintuitive nature of quantum mechanics come together to guide us in our journey to explore the world we live in. This talk is designed to be accessible to any person with some understanding of calculus and a little bit of linear algebra.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.
Concepts of quantum theory are considered from the constructive “finite” point of view. The introduction of a continuum or other actual infinities in physics destroys constructiveness without any need for them in describing empirical observations. It is shown that quantum behavior is a natural consequence of symmetries of dynamical systems. The underlying reason is that it is impossible in principle to trace the identity of indistinguishable objects in their evolution—only information about invariant statements and values concerning such objects is available. General mathematical arguments indicate that any quantum dynamics is reducible to a sequence of permutations. Quantum phenomena, such as interference, arise in invariant subspaces of permutation representations of the symmetry group of a dynamical system. Observable quantities can be expressed in terms of permutation invariants. It is shown that nonconstructive number systems, such as complex numbers, are not needed for describing quantum phenomena. It is sufficient to employ cyclotomic numbers—a minimal extension of natural numbers that is appropriate for quantum mechanics. The use of finite groups in physics, which underlies the present approach, has an additional motivation. Numerous experiments and observations in the particle physics suggest the importance of finite groups of relatively small orders in some fundamental processes. The origin of these groups is unclear within the currently accepted theories—in particular, within the Standard Model.
The meaning of symmetries is studied in some detail, and a study is performed of transformations which preserve the description, of transformations of frames and the corresponding quantum symmetries. The second part of the chapter outlines Galilei transformations, time translations, spatial reflection and time reversal Meaning of symmetries Symmetries and constants of motion have already appeared here and there in this book, most notably in Appendix 3.A. Recall that, therein, we have defined symmetries as those transformations that generate new solutions out of known solutions; more generally, that permute solutions among themselves. Constants of motion are functions on the carrier space which, when restricted to solutions, acquire a constant value depending on the solution considered. This point of view may be viewed as a dynamical point of view, i.e. depending on the specific system under consideration. There is, however, another meaning of symmetry, which deals with the symmetry of the description that ensures the covariance of the equations of motion, e.g. transformations that map equations of motion in Hamiltonian form into other equations still in Hamiltonian form, or transformations that map second-order differential equations into second-order ones, i.e. equations admitting a Lagrangian description into new ones also admitting a Lagrangian description. Transformations of the dynamical type emerge out of the previous ones when we further require that the Hamiltonian is preserved or the Lagrangian is preserved up to a total time derivative.