Generalization of Adding Angular Momenta and Circular Potential in Quaternionic Quantum Mechanics

Andrey G. Grozin

Alessio Zaccone

F. S. Levin

R. Deepika, Krishnan Muthunagai

Complex numbers were created by introducing the imaginary unit i to represent the square root of -1, allowing solutions to equations that involved square roots of negative numbers. Complex numbers were further extended to quaternionic numbers by introducing additional imaginary units, namely " j " and " k ". Quaternions are non-commutative and involve four components, with each component being a real number or a multiple of an imaginary unit. Usually complex numbers are used to represent wave functions in quantum mechanics. Solutions using quaternions to square well, spin and angular momentum, Dirac equations have been obtained by many researchers. In this article, we have made use of quaternions to study the generalization of adding angular momenta, the digital signal processing of a quaternionic function and circular potential of a particle in real Hilbert space and have obtained quaternionic solutions in terms of Bessel functions.

František Jenč

Walter Wilcox

Synopsis: General operator properties of angular momenta are recalled, and a physical motivation for adding them is given. The product and total angular momentum bases are defined. It is shown how to express one basis in terms of the other, and an explicit example of adding two spin 1/2 angular momenta is given. A further example consists of adding a general orbital angular momentum value to spin 1/2. These considerations are applied to perturbations in the hydrogen atom energy spectrum, where the correct choice for calculations is the total angular momentum basis.