Contents The rectangular potential energy barrier 80 Brief illustration 10.1: Transmission probabilities for a rectangular barrier 83 The Eckart potential energy barrier 83 Brief illustration 10.2: Transmission probabilities for an Eckart barrier 84 The double-well potential 85 Brief illustration 10.3: The inversion...
This work is a contribution to the theory of the quantum tunneling effect. In the literature at least two barriers are studied, for which the third-order contribution to the phase - integral asymptotic approximation of the transmission coefficient do not contribute. These are the parabolic barrier and the inverse Morse barrier. In the present work we will show that with a proper choice of the so called base function there is at least one more barrier in this category namely the Eckart-Epstein potential. The fact that the third - order contribution vanishes is a good indication that we have found an optimal choice of the base function, and the treatment to find an optimal base function may be possible to generalize to other classes of potential barriers. For particles of a low energy compared to the energy near the top of the barrier we obtain a vary low transmission coefficient, which means that the probability for tunneling to occur is very low. There exist some cases, for example that with a double barrier which is transparent, even for certain relatively low energies but no evidence for this kind of transparency for a single barrier has been found. The present work does not give any such evidence. At the same time there are still speculations on cold fusion like effects, which would demand a higher probability for tunneling through for a single barrier.
Proton transfer plays a key role in the applications of advanced energy materials as well as in the functionalities of biological systems. In this work, based on the transfer matrix method, we study the quantum effects of proton transfer in a series of one-dimensional (1D) model potentials and numerically calculate the quantum probability of transferring across single and double barriers (wells). In the case of single barriers, when the incident energies of protons are above the barrier height, the quantum oscillations in the transmission coefficients depend on the geometric shape of the barriers. It is found that atomic resonant tunneling (ART) not only presents in the rectangular single well and rectangular double barriers as expected, but also exists in the other types of potential wells and double barriers. For hetero-structured double barriers, there is no resonant tunneling in the classical forbidden zone, i.e., in the case when the incident energy (E i) is lower than the barrier height (E b). Furthermore, we have provided generalized analysis on the characteristics of transmission coefficients of hetero-structured rectangular double barriers.