This chapter discusses how solving the Schrödinger equation leads to the conclusion that orbital angular momentum is quantized and how the same conclusion can also be reached from the angular momentum operators without solving the Schrödinger equation explicitly. It analyses the commutation properties of the angular momentum operators, noting that the same conclusions apply to observables that are described by operators with the same commutation properties. Angular momentum has many more mundane applications, including being central to the discussion of the structures of atoms and the rotation of molecules, as well as to virtually all forms of spectroscopy. The chapter mentions classical mechanics that puts no constraints on the magnitude of the angular momentum, which is consistent with the kinetic energy of rotation being continuously variable. The property of hermiticity can be demonstrated explicitly in the position representation.
This chapter discusses how solving the Schrödinger equation leads to the conclusion that orbital angular momentum is quantized and how the same conclusion can also be reached from the angular momentum operators without solving the Schrödinger equation explicitly. It analyses the commutation properties of the angular momentum operators, noting that the same conclusions apply to observables that are described by operators with the same commutation properties. Angular momentum has many more mundane applications, including being central to the discussion of the structures of atoms and the rotation of molecules, as well as to virtually all forms of spectroscopy. The chapter mentions classical mechanics that puts no constraints on the magnitude of the angular momentum, which is consistent with the kinetic energy of rotation being continuously variable. The property of hermiticity can be demonstrated explicitly in the position representation.
The orbital angular momentum of a particle in quantum mechanics is defined exactly as in classical mechanics. Before developing any properties of the angular momentum operators, students must know the commutation relations they satisfy with themselves, with the momentum operator, and with the position operator. The angular momentum operator is very closely related to rotations of the system. Students should compare the ability of the angular momentum operator to generate infinitesimal rotations, with the corresponding property of the linear momentum p. The chapter provides the theory of the orbital angular momentum sufficiently to study the problem of a particle in a central potential.
The theory of angular momentum performance a significant position in the classical and quantum mechanical study of physical properties, such as studies into nuclear, atomic, and molecular processes, as well as other quantum problems, including spherical symmetry. In this analysis, angular momentum operators are described in multiple ways, based on the angular momentum operator's commutator, matrix, and geometric representation, The eigenvalue and eigenvector were also known for operatorsJ ̂_±,J ⃑ ̂^2, J ̂_x,J ̂_y and J ̂_zwithin the |j,┤ ├ m⟩ basis. Furthermore, in quantum mechanics, angular momentum is called quantized variable, meaning that it comes in discrete quantities. In contrast to the macroscopic system case where a continuous variable is angular momentum.
Angular momentum is a very important and revealing property of many physical systems. In classical mechanics the principle of conservation of angular momentum is a powerful aid to the solution of such problems as the orbits of planets and satellites and the behaviour of gyroscopes and tops. The role of angular momentum in quantum mechanics is probably even more important and this will be the subject of the present chapter and the next. We shall find that the operators representing the components of angular momentum do not commute with each other, although they all commute with the operator representing the total angular momentum. It follows that no pair of these components can be measured compatibly and we shall therefore look for a set of eigenfunctions that are common to the operators representing the total angular momentum and one of its components. We shall find that the angular momentum eigenvalues always form a discrete set and that, in the case of a central field, the operators commute with the Hamiltonian, implying that the total angular momentum and one component can be measured compatibly with the energy in this case, so that their values, once measured, remain constant in time. Consideration of angular momentum will also enable us to make predictions about the behaviour of atoms in magnetic fields, and we shall find that these are in agreement with experiment only if we assume that the electron (in common with many other fundamental particles) has an intrinsic “spin” angular momentum in addition to the “orbital” angular momentum associated with its motion. The interaction between spin and orbital angular momenta leads to detailed features of the atomic spectra which are known as “fine structure.” We shall also use the measurement of angular momentum to illustrate the quantum theory of measurement discussed in the previous chapter.
This chapter focuses on the concept of rotational motion. It explains that energy and angular momentum for a particle rotating in two- or three-dimensions are quantized and satisfied cyclic boundary conditions, which imply the quantization of angular momentum's magnitude and z-component. The electronic structure of atoms showcases rotational motion because electrons orbit around nuclei and spin on their axis. The chapter details the solutions for the Schrödinger equation and the vector model of angular momentum. It also discusses the concept of space quantization revolving around the quantum mechanical result of a rotating body that may not take up an arbitrary orientation concerning some specified axis.
Angular momentum theory provides a mathematical foundation for the rotation of the eigenvectors of the angular momentum operator, the spherical harmonics functions. A useful property of spherical harmonics is that their rotation in 3D space corresponds to rotation in the virtual space of their azimuthal degrees of freedom. In addition to that, spherical harmonics functions that have different orbital indices do not mix. Given that spherical harmonics functions have known rotation properties, and that any arbitrary function can be expanded in a series of spherical harmonics, this property allows the rotation of an electrostatic potential when it is expanded in the series of spherical harmonics. In this chapter, the exponential form of the rotation operator, the rotation matrix for a 3D rotation of the coordinate system, and the principles of rotation of vectors and functions are described. The chapter provides a detailed self-contained introduction to the theory of angular momentum, derives the commutative properties of the angular momentum operator, and explains shift operators, while minimizing references to quantum mechanics and entirely avoiding group theory.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.