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Physical review. E

Comparative study of quantum Otto and Carnot engines powered by a spin working substance

Mahmoud Youssef Abd‐Rabbou, Atta Ur Rahman, Mikhail A. Yurischev, Saeed Haddadi

Published Sep 7, 2023• 30 citations
Publisher

Abstract

Quantum Otto and Carnot engines have recently been receiving attention due to their ability to achieve high efficiencies and powers based on the laws of quantum mechanics. This paper discusses the theory, progress, and possible applications of quantum Otto and Carnot engines, such as energy production, cooling, and nanoscale technologies. In particular, we investigate a two-spin Heisenberg system that works as a substance in quantum Otto and Carnot cycles while exposed to an external magnetic field with both Dzyaloshinsky-Moriya and dipole-dipole interactions. The four stages of engine cycles are subject to analysis with respect to the heat exchanges that occur between the hot and cold reservoirs, alongside the work done during each stage. The operating conditions of the heat engine, refrigerator, thermal accelerator, and heater are all achieved. Moreover, our results demonstrate that the laws of thermodynamics are strictly upheld and the Carnot cycle produces more useful work than that of the Otto cycle.

DOI
10.1103/physreve.108.034106

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Quantum Otto and Carnot engines have recently been receiving attention due to their ability to achieve high efficiencies and powers based on the laws of quantum mechanics. This paper discusses the theory, progress, and possible applications of quantum Otto and Carnot engines, such as energy production, cooling, and nanoscale technologies. In particular, we investigate a two-spin Heisenberg system that works as a substance in quantum Otto and Carnot cycles while exposed to an external magnetic field with both Dzyaloshinsky-Moriya and dipole-dipole interactions. The four stages of engine cycles are subject to analysis with respect to the heat exchanges that occur between the hot and cold reservoirs, alongside the work done during each stage. The operating conditions of the heat engine, refrigerator, thermal accelerator, and heater are all achieved. Moreover, our results demonstrate that the laws of thermodynamics are strictly upheld and the Carnot cycle produces more useful work than that of the Otto cycle.
Abstract This paper proposes a theoretical model for a heat engine operating on the Otto cycle, employing a two-qubit Heisenberg chain as its working substance. This system is subjected to an external, time-dependent homogeneous magnetic field and a symmetric cross-spin interaction. The interaction is configured to occur along two distinct orientations, contingent upon the direction of Zeeman energy and symmetric interaction: either exclusively along the X -direction or exclusively along the Z -direction. Furthermore, the thermal reservoirs integral to the Otto engine are considered to engage with the working substance via two discrete modes: a localized interaction or a collective interaction. The two qubits exhibit weak coupling to a non-equilibrium thermal environment during the isochoric heating and cooling strokes, thereby validating the application of a Markovian model as a suitable approximation for describing the time evolution of the working substance. This study investigates the influence of various system parameters on the thermodynamic quantities and the resultant power output. A principal finding is that refrigeration functionality is the predominant operational characteristic when the system engages in collective interaction with the reservoirs. Conversely, localized interactions facilitate dual operational modes, with the sign of the Zeeman energy determining the function as either a refrigerator or a heat engine. Significantly, positive power output is achieved in the engine regime, and we find that the choice of interaction axis acts as a powerful amplification mechanism for the thermodynamic output, while the system-environment coupling scheme proves to be the most decisive factor in determining the machine’s fundamental purpose.
Abstract We investigate the thermodynamic performance of quantum heat engines and refrigerators based on a two-spin system subject to a skew magnetic field. The working substance is described by an interacting spin model that incorporates both spin--spin coupling and anisotropy induced by a tilted magnetic field. We analyze and compare quantum Carnot and Otto cycles, showing that the Carnot cycle exhibits a universal, entropy-driven behavior with smooth phase boundaries, while the Otto cycle displays a much richer structure governed by the interplay between the energy spectrum and nonequilibrium population differences. In particular, we identify a crossover in both efficiency and coefficient of performance as a function of the interaction strength, which arises from the competition between the interaction energy scale and the magnetic field. We further demonstrate that the skew angle induces state hybridization, modifying both the energy levels and occupation probabilities. Our results highlight that interactions and anisotropy, when properly tuned, can enhance thermodynamic performance, and emphasize the importance of multi-level effects in the design of quantum thermal machines.
Recently, the influences of the Dzyaloshinski-Moriya (DM) interaction on the performances of the basic thermo-dynamical quantities have attracted a lot of attention. A large number of investigations on the quantum coupling systems with DM interaction have been carried out. However, the specific effects of spin-orbit coupling with the performance on the quantum heat engine have not been taken into account in previous studies. DM interaction is a special kind spin-orbit coupling. To enrich the research of the quantum heat engines, the investigation about the effect of DM interaction on its thermodynamic characteristics should be included. In this study, we construct two entangled quantum engines based on spin-1/2 systems with different DM interactions, with the spin exchange constant and magnetic field fixed. The quantum Otto engine and the quantum Stirling engine are discussed in this article. By numerical calculation, we obtain the expressions for several thermodynamic quantities and plot the isoline maps of the variation of the basic thermodynamic quantities such as heat transfer, work with D1 and D2 and their efficiency in the two engines. The results indicate that the DM interaction plays an important role in the thermodynamic quantities for the quantum Otto engine and the quantum Stirling engine. In addition, the positive work condition is discussed with different DM interactions, with the spin exchange constant and magnetic field. Furthermore fixed, it is found that the efficiency of quantum Otto engine cycle is smaller than the Carnot efficiency while the quantum Stirling cycle can exceed the Carnot efficiency by using the regenerator. Finally, the second law of thermodynamics is shown to be valid in the two entangled quantum systems.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.